Subsonic-velocity entrained-bed gasification of coal
    91.
    发明授权
    Subsonic-velocity entrained-bed gasification of coal 失效
    煤的亚速率夹带床气化

    公开(公告)号:US4278445A

    公开(公告)日:1981-07-14

    申请号:US44020

    申请日:1979-05-31

    Abstract: A process and apparatus for gasification of carbonaceous matter, preferably coal, is disclosed. In one embodiment, a stream of previously produced char, preferably produced from coal or other fuel, together with an oxidizer and steam is introduced into a combustion stage. The combustion gas produced by the combustion passes into a mixing zone and thence with high turbulence into a gasification zone or stage at subsonic velocity. Pulverized carbonaceous matter, preferably coal, is introduced and dispersed in the combustion gas in the mixing zone. The temperature, velocity and velocity changes principally of the gas in the gasification zone or stage are controlled to provide a heating rate for the particles of pulverized carbonaceous matter of at least about 10.sup.5 degrees Kelvin per second, and to effect rapid removal of volatile components from the immediate vicinity of the particles. Upon substantial gasification of the particles in the gasification stage, the resultant product stream may be quenched, the char removed, and preferably at least a portion thereof introduced into the combustion stage.

    Abstract translation: 公开了一种用于气化碳质物质,优选煤的方法和装置。 在一个实施方案中,将优选由煤或其它燃料产生的先前生产的焦炭与氧化剂和蒸汽一起引入燃烧阶段。 由燃烧产生的燃烧气体进入混合区,从而将高湍流进入气化区或亚音速阶段。 粉碎的碳质物质,优选煤,被引入并分散在混合区中的燃烧气体中。 控制气化区或阶段中主要气体的温度,速度和速度变化,为每秒至少约105开氏度的粉碎碳质物质颗粒提供加热速率,并实现快速去除挥发性成分 颗粒附近。 在气化阶段中颗粒实质气化之后,所得产物流可被淬火,除去焦炭,优选至少部分被引入燃烧阶段。

    Production of carbon monoxide by the gasification of carbonaceous
materials
    92.
    发明授权
    Production of carbon monoxide by the gasification of carbonaceous materials 失效
    通过碳质材料的气化生产一氧化碳

    公开(公告)号:US4265868A

    公开(公告)日:1981-05-05

    申请号:US876009

    申请日:1978-02-08

    Applicant: John F. Kamody

    Inventor: John F. Kamody

    Abstract: An increased amount of carbon monoxide is produced in a process for the gasification of carbonaceous materials by employing a reverse water gas shift reaction in the process. Raw gas produced by the gasification of carbonaceous materials contains predominantly carbon monoxide and hydrogen along with hydrogen sulfide, carbon dioxide, water and methane. Carbon dioxide is separated from the raw gas as is the hydrogen sulfide. Thereafter, the carbon monoxide is separated from the raw gas to yield one portion of the carbon monoxide product gas. After the removal of carbon monoxide the raw gas consists of a hydrogen-rich gas. The hydrogen-rich gas which may be purified is mixed with the previously separated carbon dioxide along with any imported carbon dioxide and along with a recycle gas from a catalytic reaction loop. This mixed gas is conveyed to a heat exchanger in the catalytic reaction loop and passed through a heat exchanger located immediately after the gasifier through which the raw product gas passes. In the heat exchanger the hot raw product gas indirectly contacts the mixed gas and transfers some of its sensible heat to the mixed gas to effect the catalytically promoted, endothermic reaction of carbon dioxide and hydrogen to produce a carbon monoxide-containing gas. The indirect contacting for heat exchange is conducted in a manner that limits the accumulation of elemental carbon from any of the carbon-containing components of the mixed gas. The carbon monoxide is separated from the other components of the carbon monoxide-containing gas to yield a second portion of carbon monoxide gas which is then combined with the first portion of carbon monoxide product gas to give the increased amount of carbon monoxide product gas.

    Abstract translation: 通过在该方法中采用反向水煤气变换反应,在碳质材料的气化过程中产生一氧化碳的量增加。 由碳质材料气化产生的原料气主要包含一氧化碳和氢气以及硫化氢,二氧化碳,水和甲烷。 二氧化碳与原始气体分离,如硫化氢。 此后,将一氧化碳与原料气体分离,得到一部分一氧化碳产物气体。 除去一氧化碳后,原料气体由富氢气组成。 可以将纯化的富氢气体与先前分离的二氧化碳以及任何进口的二氧化碳以及来自催化反应回路的再循环气体混合。 将该混合气体输送到催化反应回路中的热交换器,并通过位于原料气体通过的气化器之后的热交换器。 在热交换器中,热原料气体间接地接触混合气体并将一些显热转移到混合气体中,以进行二氧化碳和氢气的催化促进的吸热反应,产生含一氧化碳的气体。 热交换的间接接触以限制来自混合气体的任何含碳成分的元素碳积累的方式进行。 一氧化碳与含一氧化碳的气体的其它组分分离,得到第二部分一氧化碳气体,然后与第一部分一氧化碳产物气体混合,以产生增加量的一氧化碳产物气体。

    Method of producing hydrogen and carbon-oxide-containing process gases
for use for reducing ores
    93.
    发明授权
    Method of producing hydrogen and carbon-oxide-containing process gases for use for reducing ores 失效
    生产用于还原矿石的含氢氧化物和含氧化碳的工艺气体的方法

    公开(公告)号:US4235625A

    公开(公告)日:1980-11-25

    申请号:US931256

    申请日:1978-08-04

    Applicant: Kurt Tippmer

    Inventor: Kurt Tippmer

    Abstract: A method of producing hydrogen and carbon-oxide-containing gases for use for reducing ores and synthesizing hydrocarbons and oxygen-containing organic substances, comprises, directing a suspension of finely ground coal and oxygen through a burner into a pressure reactor to convert the coal into gases and partly burning the gases, separating the gases from non-converted coal and ash, directing the separated gases into a quenching water so that their heat content is converted into pressure steam and the gases are precooled. The precooled gases are further purified and further cooled. During quenching, the gases are cooled from temperatures in the range of from 1300.degree. C. to 1500.degree. C. down to 200.degree. C. to 300.degree. C., depending on the gasification pressure. The ash-free gases then become highly loaded with steam to a steam-to-gas ratio of 2 as they are cooled down to a temperature of from between 100.degree. C. to 200.degree. C., and to also form a condensate. The condensate is separated from the gases and recycled into the quenching process and the gases are further cooled to a temperature of from 4.degree. C. to 80.degree. C. and subsequently directed to the synthetic or ore-reducing process.

    Abstract translation: 一种生产用于还原矿石和合成烃类和含氧有机物质的含氢氧化物气体的方法,包括:将精细研磨的煤和氧气的悬浮液通过燃烧器引入压力反应器中以将煤转化为 气体并且部分地燃烧气体,将气体与未转化的煤和灰分离,将分离的气体引导到淬火水中,使得它们的热含量转化为压力蒸汽并且气体被预冷却。 将预冷气体进一步纯化并进一步冷却。 在淬火期间,根据气化压力,将气体从1300℃至1500℃的温度冷却至200℃至300℃。 然后,无灰的气体变得高度负载蒸汽,蒸汽与气体的比例为2,因为它们被冷却至100℃至200℃的温度,并且还形成冷凝物。 将冷凝物与气体分离并再循环到淬火过程中,并将气体进一步冷却至4℃至80℃的温度,随后指向合成或矿石还原过程。

    Entrained flow coal gasifier
    94.
    发明授权
    Entrained flow coal gasifier 失效
    夹带气煤气化炉

    公开(公告)号:US4158552A

    公开(公告)日:1979-06-19

    申请号:US828353

    申请日:1977-08-29

    Abstract: An entrained flow coal gasifier wherein a high temperature product gas stream is essentially formed by burning char with air. Additional char, formed by partial gasification of coal, is added immediately thereafter to obtain the gasification reaction. Fresh coal is thereafter supplied in a lower temperature region thereby obtaining the volatile components driven off at a relatively low temperature.

    Abstract translation: 一种夹带气流煤气化炉,其中高温产物气流基本上是用空气燃烧焦炭形成的。 此后立即加入由煤的部分气化形成的附加炭,以获得气化反应。 此后在较低温度区域供应新鲜的煤,从而获得在较低温度下驱除的挥发性成分。

    Apparatus and system for producing coal gas
    95.
    发明授权
    Apparatus and system for producing coal gas 失效
    用于生产煤气的设备和系统

    公开(公告)号:US4137052A

    公开(公告)日:1979-01-30

    申请号:US825271

    申请日:1977-08-17

    Abstract: Apparatus and system for producing coal gas from coal, air and water. Pulverized coal is introduced into a rising stream of air and steam in a retort to constitute a fluidized or entrained bed. The coal reacts with the steam and air to form a gas consisting of hydrogen, carbon monoxide, carbon dioxide, nitrogen, methane and higher hydrocarbons. In some cases the air may be eliminated to produce nitrogen-free gas. In other instances, the production of methane and higher hydrocarbons may be suppressed to produce a gas consisting primarily of hydrogen and carbon monoxide. The retort is constructed so that product gas and air may be burned in an annular space surrounding the central reaction column to produce hot flue gas. Steam tubes may be disposed in the annular space so that the steam and air introduced to the central reaction chamber may be super-heated by the hot flue gas. A further annular space or "wet wall" may be provided surrounding the first annular space through which the intake water is passed, so that the intake water may be brought to a boiling point and converted to steam prior to its being introduced into the steam superheating tubes. This construction causes the walls to the retort to be maintained at a higher temperature than the reaction inside the column, so that all the heat radiated from the walls of the reaction column is directed inwardly, and no heat is lost through the walls. The product gas from the retort is then cooled and passed through a water spray which cools the gas to nearly room temperature, and removes all the fly ash and other particulate matter from the gas.

    Abstract translation: 从煤,空气和水中生产煤气的设备和系统。 将粉碎的煤在蒸馏器中引入上升的空气和蒸汽流中以构成流化或夹带的床。 煤与蒸汽和空气反应形成由氢气,一氧化碳,二氧化碳,氮气,甲烷和高级烃组成的气体。 在某些情况下,可以排除空气以产生无氮气体。 在其他情况下,可以抑制甲烷和高级烃的生产以产生主要由氢气和一氧化碳组成的气体。 蒸馏器被构造成使得产物气体和空气可以在围绕中央反应塔的环形空间中燃烧以产生热的烟道气。 蒸汽管可以设置在环形空间中,使得引入中央反应室的蒸汽和空气可以被热的烟道气过度加热。 可以围绕入口水通过的第一环形空间设置另外的环形空间或“湿壁”,使得进水可以在其被引入蒸汽过热之前变成沸点并转换成蒸汽 管。 这种结构使得蒸馏器的壁保持在比柱内的反应更高的温度,使得从反应塔的壁辐射的所有热量被引向内部,并且不会通过壁损失热量。 然后将来自蒸馏器的产物气体冷却并通过将气体冷却至接近室温的喷水器,并从气体中除去所有飞灰和其它颗粒物质。

    High temperature chemical reaction processes utilizing fluid-wall
reactors
    97.
    发明授权
    High temperature chemical reaction processes utilizing fluid-wall reactors 失效
    利用流体壁反应器的高温化学反应过程

    公开(公告)号:US4044117A

    公开(公告)日:1977-08-23

    申请号:US591949

    申请日:1975-06-30

    Applicant: Edwin Matovich

    Inventor: Edwin Matovich

    Abstract: High temperature chemical reaction processes utilizing fluid-wall reactors can be conducted in fluid-wall reactors by a process which includes the steps of (1) generating a shell of a refractory material which reflects radiation, the volume enclosed by the shell constituting a black body cavity; (2) generating within the black body cavity an annular envelope of an inert fluid which is substantially transparent to radiation, the envelope having substantial axial length and the interior of the envelope defining a reaction chamber; (3) passing at least one reactant into the black body cavity and through the reaction chamber along a predetermined path substantially coincident with the longitudinal axis of the envelope, the reactants being confined within the reaction chamber; and (4) directing high intensity radiant energy into the reaction chamber to coincide with at least a portion of the predetermined path of the reactants, sufficient radiant energy being absorbed within the reaction chamber to raise the temperature of the reactants to a level required to initiate and sustain the desired chemical reaction.

    Abstract translation: 利用流体壁反应器的高温化学反应方法可以通过包括以下步骤的方法在流体壁反应器中进行:(1)产生反射辐射的耐火材料壳体,壳体由构成黑体的壳体 腔体 (2)在黑色体腔内产生对辐射基本透明的惰性流体的环形外壳,该外壳具有相当大的轴向长度,并且该外壳的内部限定一个反应室; (3)将至少一种反应物通过基本上与壳体的纵向轴线重合的预定路径穿过反应室,反应物被限制在反应室内; 和(4)将高强度辐射能量引导到反应室中以与反应物的预定路径的至少一部分重合,在反应室内吸收足够的辐射能,以将反应物的温度升高至启动所需的水平 并维持所需的化学反应。

    Slurries of solid carboniferous fuels
    98.
    发明授权
    Slurries of solid carboniferous fuels 失效
    固体燃料燃料

    公开(公告)号:US3764547A

    公开(公告)日:1973-10-09

    申请号:US3764547D

    申请日:1971-01-28

    Applicant: TEXACO INC

    Abstract: Production of synthesis gas from a slurry of particulate solid carboniferous fuels, e.g., petroleum coke, coke from bituminous coal, coal, oil shale, tar sands, pitch, or mixtures of these materials in water or in a hydrocarbon liquid fuel. The amount of particulate solid carboniferous fuel in a pumpable slurry may be increased to 75 wt. percent and the particle size of the solid fuel may be increased to pass through a 12 mesh screen by the addition of 2 to 10 wt. percent of soot as produced, for example, by the partial oxidation of crude oil. The slurry at a relatively low velocity in the range of 5 to 50 feet per second is mixed with a stream of oxidizing gas at a relatively high velocity in the range of 200 feet per second to sonic velocity at the burner tip to form an atomized dispersion of water, hydrocarbon liquid fuel, oxidizing gas, and solid carboniferous fuel. Under synthesis gas generating conditions, the atomized dispersion is reacted to produce a gaseous mixture of hydrogen and carbon monoxide. By this process, pumpable slurry feeds of low cost solid carboniferous fuels may be gasified in a synthesis gas generator without being preheated.

    Abstract translation: 从颗粒状固体含碳燃料(例如石油焦炭,来自烟煤的煤,煤,油页岩,焦油砂,沥青或这些材料在水中或烃液体燃料中的混合物)的浆料生产合成气。 可泵送浆料中的固体含量的固体含量的燃料的量可以增加到75wt。 可以增加固体燃料的颗粒尺寸以通过加入2至10重量%的通过12目筛网。 例如,通过原油的部分氧化产生的烟灰百分比。 以5至50英尺/秒的相对较低的速度将浆料与氧气气体流以200英尺/秒的相对较高的速度与燃烧器尖端处的声速混合,以形成雾化的分散体 的水,烃液体燃料,氧化气体和固体含碳燃料。 在合成气体产生条件下,使雾化的分散体反应以产生氢气和一氧化碳的气体混合物。 通过该方法,低成本固体含碳燃料的可泵送浆料进料可以在合成气发生器中气化而不被预热。

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