Blocking and stain resistant surface treated articles and methods for making
    97.
    发明授权
    Blocking and stain resistant surface treated articles and methods for making 有权
    防粘和防污的表面处理制品及其制造方法

    公开(公告)号:US08993111B2

    公开(公告)日:2015-03-31

    申请号:US12589587

    申请日:2009-10-26

    Abstract: The present invention provides surface treated articles comprising a recoatable surface treatment of an acrylic or vinyl polymer that does not change the appearance of the treated surface, and which imparts blocking resistance and/or stain and dirt pickup resistance to the treated surface. The one or more acrylic or vinyl polymer has a number average molecular weight of from 1,000 to 100,000, a glass transition temperature of −10° C. or higher, preferably, 30° C. or higher, and comprises the polymerization product of one or more non-ionic monomer, such as methyl methacrylate, with up to 47 wt. % of an ethylenically unsaturated acid monomer and, preferably, is non-migrating under use conditions. When dry, the surface treatments may form a layer of domains of polymer distributed all over the treated surface, rather than a film. Treated articles include coating or painted articles and elastomer films.

    Abstract translation: 本发明提供了表面处理制品,其包括丙烯酸或乙烯基聚合物的可重复表面处理,其不会改变经处理的表面的外观,并且赋予对经处理的表面的抗粘连性和/或污渍和污垢拾取抗性。 一种或多种丙烯酸或乙烯基聚合物的数均分子量为1,000至100,000,玻璃化转变温度为-10℃或更高,优选为30℃或更高,并且包含一种或多种聚合产物 更多的非离子单体,如甲基丙烯酸甲酯,高达47wt。 %的烯属不饱和酸单体,并且优选在使用条件下不迁移。 当干燥时,表面处理可以形成分布在整个处理过的表面上的聚合物的一层,而不是膜。 处理过的制品包括涂层或涂漆制品和弹性体膜。

    Polymerizable phosphazene derivatives: a process for preparing them and
their uses
    100.
    发明授权
    Polymerizable phosphazene derivatives: a process for preparing them and their uses 失效
    可聚合磷腈衍生物:其制备方法及其用途

    公开(公告)号:US6060583A

    公开(公告)日:2000-05-09

    申请号:US257250

    申请日:1999-02-25

    CPC classification number: C07F9/65815 C07F9/067 C08F30/02 C09D4/00

    Abstract: This invention relates to a polymerizable phosphazene derivative with a general structural formula[.brket open-st.NP(A).sub.a (B).sub.b).brket close-st.]xwherein the groups A and B are bonded to phosphorus atoms through --O--, --S--, --NH--, or --NR-- (with R=C.sub.1 -C.sub.6) alkyl), and wherein A stands more precisely for a vinyl ether group or a styrene ether group, and B stands more precisely for a hydrocarbon group. The invention also relates to procedures for synthesizing such phosphazene derivatives. The phosphazenes derivatives of the invention can be cured by a process that is initiated cationically, which leads to a large number of advantages. The phosphazene derivatives of the invention can, in particular, be used as curable binders for paints, coatings, fillers, mastics, adhesives, moldings, or films. Paints or coatings comprising the phosphazene derivatives of the invention show especially high mechanical resistance and scratch resistance.

    Abstract translation: 本发明涉及具有通式[+547NP(A)a(B)b)+ 548] x的聚合磷腈衍生物,其中基团A和B通过-O - , - S-, -NH-或-NR-(其中R = C1-C6)烷基),并且其中A更精确地代表乙烯基醚基团或苯乙烯醚基团,并且B更精确地代表烃基。 本发明还涉及合成这种磷腈衍生物的方法。 本发明的磷腈衍生物可以通过阳离子引发的方法固化,这导致许多优点。 本发明的磷腈衍生物特别可以用作油漆,涂料,填料,胶粘剂,粘合剂,模制品或薄膜的可固化粘合剂。 包含本发明的磷腈衍生物的涂料或涂料显示出特别高的机械性能和耐擦伤性。

Patent Agency Ranking