摘要:
Biodegradable polyesters P1 obtainable by reaction of a mixture consisting essentially of (a1) a mixture consisting essentially of from 35 to 95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof, from 5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and from 0 to 5 mol % of a sulfonate compound, the sum of the individual mole percentages being 100 mol %, and (a2) a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and C5-C10-cycloalkanediols, the molar ratio of (a1) to (a2) being chosen within the range from 0.4:1 to 1.5:1, with the proviso that the polyesters P1 have a molecular weight (Mn) within the range from 5000 to 50,000 g/mol, a viscosity number within the range from 30 to 350 g/ml (measured in 50:50 w/w o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester P1 at 25° C.) and a melting point within the range from 50 to 170° C. and with the further proviso that the polyesters P1 are prepared using from 0.01 to 5 mol %, based on the molar quantity used of component (a1), of a compound D having at least three groups capable of ester formation, and further biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, use thereof for producing biodegradable moldings, and adhesives, biodegradable moldings, foams and blends with starch obtainable from the polymers or molding compositions of the present invention.
摘要:
The present invention relates to a process for the preparation of CFC-free, flexible polyurethane (molded) foams by reactingA) liquid polyisocyanate mixtures containing bonded urethane groups having a content of NCO groups of from 22 to 30% by weight which are themselves prepared by reacting a mixture of diphenylmethane diisocyanates and polyphenyl-polymethylene polyisocyanates having a content of diphenylmethane diisocyanate isomers of from 55 to 99% by weight, based on the total weight, with at least one trifunctional polyoxypropylene-polyol having a hydroxyl number of from 20 to 60, withB) relatively high-molecular-weight polyhydroxyl compounds and, if desired,C) low-molecular-weight chain extenders and/or crosslinking agents,in the presence ofD) blowing agents,E) catalysts and, if desired,F) auxiliaries and/or additives,and to the polyisocyanate mixtures (A) modified by means of urethane groups which can be used according to the invention.
摘要:
Isocyanato compounds with capped, isocyanate-reactive groups are those of the formula I ##STR1## where R.sup.1 and R.sup.2 are hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.10 -aralkyl or together form C.sub.3 -C.sub.10 -alkanediyl,X and Y are --O--, --S-- or ##STR2## where R.sup.4 is hydrogen, C.sub.1 -C.sub.20 -alkyl which is uninterrupted or interrupted by oxygen atoms in ether function, or is C.sub.6 -C.sub.10 -aryl or C.sub.7 -C.sub.10 -aralkyl,R.sup.3 is C.sub.1 -C.sub.10 -alkanediyl which together with --X--CR.sup.1 R.sup.2 --Y-- forms a 4-7-membered ring,in which either one hydrogen in R.sup.3 or the radical R.sup.4 in ##STR3## is replaced by an allophanate group R.sup.Ia ##STR4## in which R.sup.5 is a divalent aliphatic, alicyclic, araliphatic or aromatic C.sub.2 -C.sub.20 hydrocarbon unit,R.sup.6 is a single bond or a divalent aliphatic, alicyclic, araliphatic or aromatic C.sub.1 -C.sub.20 hydrocarbon unit or a mono- or poly(C.sub.2 -C.sub.4 -alkylene oxide) unit, andR.sup.7 is a carbamoyl radical ##STR5## or a biuret group R.sup.Ib ##STR6## in which one R.sup.8 is hydrogen and the other is as defined for R.sup.7 or a biuret group R.sup.Ic ##STR7## in which one R.sup.9 is as defined for R.sup.7 and the other is as defined for R.sup.1or a thioallophanate group R.sup.Id ##STR8##
摘要:
The invention relates to highly functionalized polyurethanes which are synthesized from molecules containing the functional groups A(B).sub.n, where A is an NCO group or a group reactive with an NCO group, B is an NCO group or a group reactive with an NCO group, A is reactive with B and n is a positive number and is at least equal to 2.
摘要:
The invention relates to a process for the production of (flexible) polyurethane foams having reduced odor and reduced fogging values by reacting a) modified or unmodified organic polyisocyanates with b) relatively high-molecular-weight polyhydroxyl compounds and, if desired,c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts from the group consisting of aminoalkyl- and aminophenylimidazoles of the formula ##STR1## and, if desired, f) additives, and to the use of the aminoalkyl- and aminophenylimidazoles of the formula (I) and/or (II) as catalysts for the preparation of polyisocyanate polyaddition products.
摘要:
Polymeric, catalytically-active compounds having imidazole groups linked terminally and/or laterally to the polymer chain through reactive groups on the polymer chain are disclosed. The polymer chain is selected from the group consisting of polyether ketones; acidic, basic, or neutral ion exchange resins; polymeric isocyanates; polymers or copolymers containing maleic acid or maleic anhydride; and polymers containing benzyl halide groups.
摘要:
What is proposed is the use of hyperbranched polylysine in the development, exploitation and completion of underground mineral oil and natural gas deposits, and in deep wells, especially as a shale inhibitor in water-based drilling muds, completion fluids or stimulation fluids.
摘要:
The present invention provides a composition comprising an amphiphile and an active ingredient whose solubility in water at 20° C. is not more than 10 g/L, wherein the amphiphile comprises a dendritic polyurea which is joined to at least one linear or comb-type polymer, and the joining is effected via a difunctional linker, if the repeat units of the linear polymer are composed of polymerized alkylene oxide. The invention also relates to an amphiphile comprising a dendritic polyurea and a process for preparing the amphiphile.
摘要:
Graft polymers whose grafting base is selected from the group consisting of polymers having vinylamine units, polyamines, polyamidoamines and polymers of ethylenically unsaturated acids and which comprise exclusively oligoalkylenimine side chains as side chains, process for the preparation of graft polymers having oligoalkylenimine side chains, at least one oligoalkylenimine which comprises a terminal aziridine group being grafted onto one of said grafting bases, and the use of the graft polymers thus obtainable as process chemicals in the production of paper, as antimicrobial coating materials, as builders in detergents and for the treatment of metal surfaces.
摘要:
Hyperbranched polycarbonates having stabilizing groups, prepared by reaction of (a) at least one compound having at least three alcoholic hydroxyl groups per molecule with (b) at least one reagent of the general formula I (c) and at least one reagent of the general formula X3-(A1)m-X4, where the variables are defined as follows: X1, X2 are identical or different and are selected from among halogen, C1-C10-alkoxy, C6-C10-aryloxy and O—C(═O)-halogen, X3 is a functional group selected from among OH, SH, NH2, NH—C1-C4-alkyl, iso-cyanate, epoxy, COOH, COOR12, C(═O)—O—C(═O), C(═O)—Cl, R12 is C1-C4-alkyl or C6-C10-aryl, A1 is a spacer or a single bond, m is zero or one. X4 is a group selected from among phenol groups, benzophenones, aromatic amines and nitrogen-comprising heterocycles, in each case substituted or unsubstituted.