公开(公告)号：US07575847B2

公开(公告)日：2009-08-18

申请号：US11427665

申请日：2006-06-29

Applicant: Naiyong Jing ,  Thomas P. Klun ,  Chuntao Cao ,  William D. Coggio ,  Zai-Ming Qiu

Inventor： Naiyong Jing ,  Thomas P. Klun ,  Chuntao Cao ,  William D. Coggio ,  Zai-Ming Qiu

IPC: G03F7/00 ,  G03F7/004 ,  B32B7/02

CPC classification number: G03F7/091 ,  G03F7/0046 ,  G03F7/027 ,  G03F7/038 ,  G03F7/0388 ,  Y10T428/24942 ,  Y10T428/3154 ,  Y10T428/31971

Abstract: Antireflective films and low refractive index compositions are described. The low refractive index layer comprises the reaction product of a composition comprising at least one free-radically polymerizable material having a high fluorine content, and at least one free-radically polymerizable fluoropolyether urethane material.

Abstract translation: 描述了抗反射膜和低折射率组合物。 低折射率层包括含有至少一种具有高氟含量的至少一种可自由基聚合的材料和至少一种可自由基聚合的氟聚醚聚氨酯材料的组合物的反应产物。

公开(公告)号：US07485371B2

公开(公告)日：2009-02-03

申请号：US10903832

申请日：2004-07-30

Applicant: Naiyong Jing ,  George Van Dyke Tiers ,  Mark W. Muggli ,  Kathryn M. Spurgeon

Inventor： Naiyong Jing ,  George Van Dyke Tiers ,  Mark W. Muggli ,  Kathryn M. Spurgeon

IPC: B32B9/04

CPC classification number: B32B27/08 ,  B32B7/12 ,  B32B27/283 ,  B32B27/304 ,  B32B27/322 ,  B32B27/36 ,  B32B2250/24 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/204 ,  B32B2307/308 ,  B32B2307/546 ,  B32B2307/714 ,  B32B2307/7265 ,  B32B2439/00 ,  B32B2439/40 ,  B32B2597/00 ,  C08F8/42 ,  C08G18/837 ,  C08G63/6854 ,  C08G63/6954 ,  C08G63/914 ,  C08G64/085 ,  C08G64/12 ,  C08G64/42 ,  C08G69/48 ,  C08K5/544 ,  C09J175/04 ,  C09J177/00 ,  Y10T428/3154 ,  Y10T428/31663 ,  C08F210/02

Abstract: Polymer bonding compositions having greater than about 1 milliequivalent primary amine/100 grams of the polymer, more preferably greater than about 3 milliequivalent non-tertiary amine/100 grams of the polymer. Preferably the polymer is not significantly crosslinked. These bonding compositions may be especially useful for bonding fluoropolymers. Processes for making the novel polymers and the resulting multilayer bonded articles are described. The polymers include polymer-bonded ZNHLSi(OP)a(X)3−a−b(Y)b units. The bonding composition may be used for making multi-layer polymer laminates such as tubes and films and containers.

Abstract translation: 具有大于约1毫当量伯胺/ 100克聚合物，更优选大于约3毫当量非叔胺/ 100克聚合物的聚合物粘合组合物。 优选地，聚合物不是显着交联的。 这些粘合组合物可特别用于粘结含氟聚合物。 描述了制备新型聚合物和所得多层粘合制品的方法。 聚合物包括聚合物键合的ZNHLSi（OP）a（X）3-a-b（Y）b单元。 粘合组合物可以用于制造多层聚合物层压材料，例如管，薄膜和容器。

公开(公告)号：US07449266B2

公开(公告)日：2008-11-11

申请号：US11553853

申请日：2006-10-27

Applicant: Richard M. Flynn ,  Naiyong Jing ,  Mark J. Pellerite

Inventor： Richard M. Flynn ,  Naiyong Jing ,  Mark J. Pellerite

IPC: G03G13/00 ,  C07D249/12

CPC classification number: B82Y30/00 ,  C07D249/18 ,  C09D5/00 ,  C09D5/12

Abstract: Perfluoropolyether benzotriazole compounds and compositions containing perfluoropolyether benzotriazole compounds are provided. The perfluoropolyether benzotriazole compounds can be attached to a substrate having a metal or metal oxide-containing surface to provide at least one of the following characteristics: anti-soiling, anti-staining, ease of cleaning, repellency, hydrophobicity, or oleophobicity.

Abstract translation: 提供全氟聚醚苯并三唑化合物和含有全氟聚醚苯并三唑化合物的组合物。 全氟聚醚苯并三唑化合物可以连接到具有金属或含金属氧化物的表面的基材上，以提供以下特征中的至少一种：抗污染，抗污染，易于清洁，排斥性，疏水性或疏油性。

公开(公告)号：US20080107907A1

公开(公告)日：2008-05-08

申请号：US11972034

申请日：2008-01-10

Applicant: William Coggio ,  Thomas Klun ,  George Moore ,  Naiyong Jing ,  Chuntao Cao ,  Sharon Wang ,  Patricia Savu ,  Lan Liu ,  Joan Noyola

Inventor： William Coggio ,  Thomas Klun ,  George Moore ,  Naiyong Jing ,  Chuntao Cao ,  Sharon Wang ,  Patricia Savu ,  Lan Liu ,  Joan Noyola

IPC: B32B27/16

CPC classification number: C08F14/18 ,  C08F259/08 ,  C08F283/00 ,  C08L51/003 ,  C09D151/003 ,  G02B1/111 ,  Y10T428/24942 ,  Y10T428/259 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31935 ,  C08F2/00 ,  C08L2666/02

Abstract: A low refractive index composition that forms a low refractive index layer on an optical display is formed having a co-crosslinked interpenetrating polymer network of a fluoropolymer phase and an acrylate phase. The fluoropolymer phase is preferably formed from fluoropolymers based on THV or FKM and having either a degree of unsaturation and/or containing a reactive cure site monomer in its polymer backbone. The acrylate phase includes a multifunctional acrylate crosslinker, and more preferably includes a perfluoropolyether acrylate crosslinker. The formed low refractive index layer has improved interfacial adhesion to other layers or substrates contained in the optical display. Further, the mechanical strength and scratch resistance of the either of above low refractive index compositions can be further enhanced through the incorporation of surface functionalized inorganic particle into the formed layer.

Abstract translation: 形成在光学显示器上形成低折射率层的低折射率组合物，其具有含氟聚合物相和丙烯酸酯相的共交联互穿聚合物网络。 含氟聚合物相优选由基于THV或FKM的含氟聚合物形成，并且在其聚合物主链中具有不饱和度和/或含有反应性固化位点单体。 丙烯酸酯相包括多官能丙烯酸酯交联剂，更优选包括全氟聚醚丙烯酸酯交联剂。 所形成的低折射率层具有改善的与光学显示器中包含的其它层或基底的界面粘合性。 此外，通过将表面官能化的无机颗粒并入成形层，可以进一步提高上述低折射率组合物中的任一种的机械强度和耐划伤性。

公开(公告)号：US07351471B2

公开(公告)日：2008-04-01

申请号：US11026754

申请日：2004-12-30

Applicant: Naiyong Jing ,  Chuntao Cao ,  Tatsuo Fukushi ,  Timothy J. Tatge ,  Christopher B. Walker, Jr. ,  Thomas P. Klun ,  William J. Schultz ,  Zai-Ming Qiu

Inventor： Naiyong Jing ,  Chuntao Cao ,  Tatsuo Fukushi ,  Timothy J. Tatge ,  Christopher B. Walker, Jr. ,  Thomas P. Klun ,  William J. Schultz ,  Zai-Ming Qiu

IPC: B32B27/00 ,  C08F8/18

CPC classification number: G02B1/111 ,  A63B37/0004 ,  Y10T428/269

Abstract: An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer and a fluoroalkyl containing multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles.

Abstract translation: 用于抗反射膜或耦合到光学显示器的经济，光学透射，防污和防油墨，耐用的低折射率含氟聚合物组合物。 在本发明的一个方面，组合物是由含氟聚合物和含氟烷基的多烯烃交联剂的反应产物形成的。 在本发明的另一方面，组合物还包括表面改性的无机纳米颗粒。

公开(公告)号：US20070148473A1

公开(公告)日：2007-06-28

申请号：US11275355

申请日：2005-12-28

Applicant: George Moore ,  John Clark ,  Audrey Sherman ,  Mark Muggli ,  Kurt Melancon ,  Timothy Filiatrault ,  Naiyong Jing

Inventor： George Moore ,  John Clark ,  Audrey Sherman ,  Mark Muggli ,  Kurt Melancon ,  Timothy Filiatrault ,  Naiyong Jing

IPC: B32B7/12 ,  B32B27/00 ,  C08L83/04

CPC classification number: C09J183/04 ,  B32B7/06 ,  B32B27/08 ,  B32B27/283 ,  B32B27/304 ,  B32B27/322 ,  B32B27/42 ,  B32B2270/00 ,  B32B2307/748 ,  B32B2405/00 ,  C08G77/458 ,  C08L83/00 ,  C09J7/22 ,  C09J7/38 ,  C09J183/10 ,  C09J2205/114 ,  C09J2427/006 ,  C09J2475/00 ,  C09J2483/00 ,  Y10T428/2852 ,  Y10T428/31663

Abstract: An adhesive article comprising a fluorothermoplastic film having a major surface; and a pressure sensitive adhesive layer adhered to at least a portion of the first major surface, wherein the pressure sensitive adhesive comprises a silicone polyurea block copolymer and an MQ tackifying resin. Composite articles preparable from the adhesive articles, and methods of making the same are also disclosed.

Abstract translation: 一种粘合制品，其包含具有主表面的氟热塑性膜; 以及粘合到所述第一主表面的至少一部分上的压敏粘合剂层，其中所述压敏粘合剂包括硅氧烷聚脲嵌段共聚物和MQ增粘树脂。 还公开了可从粘合剂制备的复合制品及其制备方法。

公开(公告)号：US20070072975A1

公开(公告)日：2007-03-29

申请号：US11239585

申请日：2005-09-29

Applicant: Blake Chandler ,  Naiyong Jing

Inventor： Blake Chandler ,  Naiyong Jing

IPC: C09D5/08 ,  C08K3/10

CPC classification number: C09D127/18 ,  C08K3/08 ,  C08K3/22 ,  C08K3/24 ,  C08K5/50 ,  C08L27/18

Abstract: Provided are fluoropolymer blends comprising a fluoropolymer having a major amount of fluorothermoplastic, a bubble suppressing metal compound, a base and a phase transfer catalyst. Also provided are layered articles comprising a first layer having the described fluoropolymer blend and methods for making the layered articles.

Abstract translation: 提供含氟聚合物共混物，其包含具有主要量的氟热塑性的含氟聚合物，气泡抑制金属化合物，碱和相转移催化剂。 还提供了包括具有所述含氟聚合物共混物的第一层和用于制备层状物的方法的层状制品。

公开(公告)号：US07179847B2

公开(公告)日：2007-02-20

申请号：US10712361

申请日：2003-11-13

Applicant: Michael A. Yandrasits ,  Steven J. Hamrock ,  Naiyong Jing

Inventor： Michael A. Yandrasits ,  Steven J. Hamrock ,  Naiyong Jing

IPC: C08F2/46

CPC classification number: C08J5/2293 ,  C08J2327/18 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56

Abstract: A method of making a crosslinked polymer is provided as well as the polymer so made, the method comprising the steps of: providing a highly fluorinated fluoropolymer, typically a perfluorinated fluoropolymer, comprising pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH, or —O−M+, where M+ is a monovalent cation, and exposing said fluoropolymer to electron beam radiation so as to result in the formation of crosslinks. Typically, the method according to the present invention additionally comprises the step of: forming said fluoropolymer into a membrane, typically having a thickness of 90 microns or less, more typically 60 microns or less, and most typically 30 microns or less.

Abstract translation: 提供制备交联聚合物的方法以及如此制备的聚合物，该方法包括以下步骤：提供高度氟化的含氟聚合物，通常为全氟化含氟聚合物，其包含侧基，其包括根据式-SO _{2 X，其中X是F，Cl，Br，OH或-O - ，其中M + 是单价阳离子，并将所述含氟聚合物暴露于电子束辐射，从而导致交联的形成。 通常，根据本发明的方法另外包括以下步骤：将所述含氟聚合物形成膜，通常具有90微米或更小，更典型地为60微米或更小，最通常为30微米或更小的厚度。}

公开(公告)号：US20060251885A1

公开(公告)日：2006-11-09

申请号：US11458408

申请日：2006-07-19

Applicant: William Coggio ,  Thomas Klun ,  Mark Pellerite ,  George Moore ,  Cheryl Elsbernd ,  Sharon Wang ,  Richard Buckanin ,  Christopher Walker ,  Naiyong Jing ,  Zai-Ming Qiu

Inventor： William Coggio ,  Thomas Klun ,  Mark Pellerite ,  George Moore ,  Cheryl Elsbernd ,  Sharon Wang ,  Richard Buckanin ,  Christopher Walker ,  Naiyong Jing ,  Zai-Ming Qiu

IPC: B32B27/30 ,  B32B27/26 ,  C09K19/00

CPC classification number: B32B33/00 ,  B32B27/18 ,  B32B27/28 ,  B32B2307/21 ,  B32B2307/40 ,  B32B2457/20 ,  B32B2457/204 ,  C08F220/22 ,  C08F220/24 ,  Y10T428/10 ,  Y10T428/1059 ,  Y10T428/25 ,  Y10T428/263 ,  Y10T428/265 ,  Y10T428/2848 ,  Y10T428/3154 ,  Y10T428/31935

Abstract: The invention relates to display and protective articles having a fluorochemical surface layer, and methods of making such articles. The invention also relates to fluoropolyether acrylate compositions.

Abstract translation: 本发明涉及具有含氟表面层的显示和保护制品，以及制造这种制品的方法。 本发明还涉及含氟聚醚丙烯酸酯组合物。

公开(公告)号：US07074841B2

公开(公告)日：2006-07-11

申请号：US10712589

申请日：2003-11-13

Applicant: Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

Inventor： Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

IPC: C08J3/28 ,  C08J3/00 ,  C08J5/22 ,  C08J5/20

CPC classification number: C08J5/225 ,  C08J2327/12

Abstract: A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1–15 carbon atoms and 0–4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

Abstract translation: 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R