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    Amorphous hydrocarbon conversion catalysts and process for preparing same
    168.
    发明授权
    Amorphous hydrocarbon conversion catalysts and process for preparing same 失效
    无定形烃转化催化剂及其制备方法

    公开(公告)号：US3915893A

    公开(公告)日：1975-10-28

    申请号：US38215273

    申请日：1973-07-24

    Applicant: UNION CARBIDE CORP

    Inventor： FLANIGEN EDITH MARIE ,  GROSE ROBERT WILLIAM

    IPC: B01J21/16 ,  B01J11/82

    CPC classification number: B01J21/16 ,  Y10S585/906

    Abstract: Novel amorphous compositions possessing catalytic properties may be prepared by controlled calcination of synthetic crystalline precursor material structurally related to the mineral alunite, said precursor material being prepared and crystallized from an aqueous reaction mixture having a composition expressed in terms of mole ratios of oxides as Q G2O : a Al2O3 : b M2O3 : c SO4 : d XO4 : e H2O wherein ''''G'''' represents NH4 , H , Ag or any mixture thereof, wherein M2O3 represents at least one oxide selected from the group consisting of Fe2O3, Cr2O3, V2O3, La2O3, and Ce2O3; XO4 represents at least one oxide selected from the group consisting of PO4, MoO4, VO4. SiO4 and TlO4; ''''q'''' has a value of from 0.5 to 6.0; ''''a'''' has a value of from 1.5 to 4.0: ''''b'''' has a value of from zero to 2.0; ''''c'''' has a value of from 8.0 to 10.0; ''''d'''' has a value of from zero to 2.0; ''''e'''' has a value of from 100 to 1,000; the sum of ''''a'''' + ''''b'''' has a value not exceeding 4.0.

    Abstract translation: 具有催化性质的新型无定形组合物可以通过对结构上与矿物铝酸盐相关的合成结晶前体材料的可控煅烧来制备，所述前体材料由具有以氧化物摩尔比表示的组成的水性反应混合物制备并结晶，如Q G 2 O ：Al 2 O 3 :b M 2 O 3 :c SO 4：d XO 4：e H 2 O其中“G”表示NH 4 +，H +，Ag +或其任何混合物，其中M 2 O 3表示选自以下的至少一种氧化物： 由Fe2O3，Cr2O3，V2O3，La2O3和Ce2O3组成; XO4表示选自PO4，MoO4，VO4中的至少一种氧化物。 SiO4和T104; “q”的值为0.5至6.0; “a”的值为1.5至4.0：“b”的值为零至2.0; “c”的值为8.0〜10.0; “d”的值为零到2.0; “e”的值为100到1,000; “a”+“b”的总和的值不超过4.0。

    Catalyst composition for oxidation of butenes
    169.
    发明授权
    Catalyst composition for oxidation of butenes 失效
    用于丁烯氧化的催化剂组合物

    公开(公告)号：US3893945A

    公开(公告)日：1975-07-08

    申请号：US41268073

    申请日：1973-11-05

    Applicant: MITSUBISHI RAYON CO

    Inventor： KOBAYASHI MASAO ,  IKEDA MINORU ,  YAMADA KANTARO ,  ISHII HIROMICHI

    IPC: B01J27/057 ,  B01J27/19 ,  C07C5/48 ,  C07C45/34 ,  C07C45/35 ,  B01J11/82 ,  B01J11/22

    CPC classification number: C07C5/48 ,  B01J27/0576 ,  B01J27/19 ,  C07C45/35 ,  C07C11/167 ,  C07C47/22

    Abstract: A novel catalyst composition for vapor-phase oxidation of butenes which is active at a temperature in the range from 250* to 450*C and capable of converting n-butenes and iso-butene selectively into 1,3-butadiene and methacrolein, respectively. The said catalyst composition contains tungsten, molybdenum, tellurium, antimony and oxygen, one combination selected from among (a) nickel and cobalt, (b) nickel and iron, (c) nickel, cobalt and bismuth and (d) nickel, iron and bismuth, and at least one member selected from the group consisting of potassium, rubidium and cesium. Phosphorus and/or tin may also be added to the catalyst composition.

    Abstract translation: 一种用于丁烯气相氧化的新型催化剂组合物，其在250℃至450℃的温度范围内有活性，并能够分别将正丁烯和异丁烯转化为1,3-丁二烯和异丁烯醛。 所述催化剂组合物包含钨，钼，碲，锑和氧，选自（a）镍和钴中的一种组合，（b）镍和铁，（c）镍，钴和铋以及（d）镍，铁和 铋以及选自钾，铷和铯中的至少一种。 也可以将磷和/或锡加入到催化剂组合物中。

    Aluminosilicate compositions, method of preparation
    170.
    发明授权
    Aluminosilicate compositions, method of preparation 失效
    铝酸钠组合物，制备方法

    公开(公告)号：US3844977A

    公开(公告)日：1974-10-29

    申请号：US30686072

    申请日：1972-11-15

    Applicant: UNION OIL CO

    Inventor： YOUNG D

    IPC: B01J20/12 ,  B01J20/18 ,  B01J29/06 ,  C10G11/05 ,  C10G25/03 ,  C10G49/08 ,  B01J11/82 ,  B01J11/40

    CPC classification number: B01J20/12 ,  B01J20/183 ,  B01J29/061 ,  C10G11/05 ,  C10G25/03 ,  C10G49/08

    Abstract: Intimate dispersions of particulate aluminosilicates and refractory oxides are prepared in aqueous media in the presence of an oxygen containing amine followed by separation and drying of the resultant dispersion. The original aluminosilicate or refractory oxide can contain active components, stabilizing compositions and the like, as such or in a form that can be subsequently converted to such active components by thermal or chemical treatment. Similarly the dispersion of the aluminosilicate in the refractory oxide can be combined with catalytically active, stabilizing or otherwise chemically or physically modifying compositions.

    Abstract translation: 在含氧胺的存在下，在水介质中制备颗粒状硅铝酸盐和难熔氧化物的紧密分散体，然后分离和干燥所得分散体。 原始的硅铝酸盐或耐火氧化物可以包含活性组分，稳定组合物等，或者以随后可以通过热或化学处理转化为这种活性组分的形式。 类似地，铝硅酸盐在难熔氧化物中的分散体可与催化活性，稳定化或其它化学或物理改性组合物组合。

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