CROSSLINKED POLYAMIDES
    11.
    发明申请
    CROSSLINKED POLYAMIDES 审中-公开
    交联聚氨酯

    公开(公告)号:US20120142887A1

    公开(公告)日:2012-06-07

    申请号:US13308707

    申请日:2011-12-01

    IPC分类号: C08G69/16

    CPC分类号: C08G69/18

    摘要: A process for crosslinking polyamides by reacting a compound of the general formula R1R2C═CR3—X in which R1, R2 and R3 are each independently hydrogen or an organic radical with a lactam A at a temperature of (−30) to 150° C., and then reacting with a lactam B, a catalyst and an activator at a temperature of 40 to 240° C.

    摘要翻译: 通过使通式为R 1 R 2 C = CR 3 -X的化合物(其中R 1,R 2和R 3各自独立地为氢或有机基团)与内酰胺A在(-30)至150℃的温度下反应来交联聚酰胺的方法。 然后在40〜240℃的温度下与内酰胺B,催化剂和活化剂反应。

    LONG-FIBER REINFORCED POLYESTERS
    12.
    发明申请
    LONG-FIBER REINFORCED POLYESTERS 审中-公开
    长纤维增强聚酯

    公开(公告)号:US20120029137A1

    公开(公告)日:2012-02-02

    申请号:US13196028

    申请日:2011-08-02

    IPC分类号: C08K3/40

    CPC分类号: C08L67/02 C08K7/14 C08L67/00

    摘要: The invention relates to thermoplastic molding compositions comprising: A) from 10 to 89% by weight of a polyethylene terephthalate or polybutylene terephthalate, B) from 10 to 60% by weight of a fibrous reinforcing material with a fiber length of from 2 to 24 mm, C) from 1 to 20% by weight of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on an aliphatic dihydroxy compound, D) from 0 to 40% by weight of further additives, where the entirety of components A) to D) is 100%. The invention further relates to the use of thermoplastic molding compositions for producing long-fiber-reinforced pellets and to the pellets thus obtainable. The invention further relates to the use of pellets of this type for producing moldings of any type with good notched impact resistance, and to the resultant moldings.

    摘要翻译: 本发明涉及热塑性模塑组合物,其包含:A)10至89重量%的聚对苯二甲酸乙二醇酯或聚对苯二甲酸丁二醇酯,B)10至60重量%的纤维增强材料,纤维长度为2至24毫米 ,C)1至20重量%的至少一种基于脂族和芳族二羧酸的聚酯和脂族二羟基化合物,D)0至40重量%的其它添加剂,其中组分A)至 D)为100%。 本发明还涉及热塑性模塑组合物用于生产长纤维增强颗粒的用途以及由此获得的颗粒。 本发明还涉及这种类型的粒料用于生产具有良好缺口耐冲击性的任何类型的模制品以及所得的模制品。

    Batch process for preparing polyamides

    公开(公告)号:US10017609B2

    公开(公告)日:2018-07-10

    申请号:US13058779

    申请日:2009-08-14

    摘要: Polyamides based on dicarboxylic acids and on diamines are produced in a batch process by 1) feeding the entire amount of monomer composed of dicarboxylic acids, of diamines, and, if appropriate, of further polyamide-forming monomers, in the desired stoichiometry, in a closed stirred-tank reactor, 2) heating the monomer mixture in the stirred-tank reactor, with stirring, and with setting of a certain pressure, to a desired reaction temperature for the production of a prepolymer, 3) if appropriate, completely or partially depressurizing the reaction mixture from stage 2), 4) if appropriate, carrying out further thermal treatment of the reaction mixture from stage 2) or 3), and 5) reacting the reaction mixture from stage 2), 3), or 4) in the melt in a vented extruder for further increase of the molecular weight, with discharge of water vapor, and without use of additional polyamide-forming monomers or of polyamides.

    Process for the anionic polymerization of lactams

    公开(公告)号:US06579965B2

    公开(公告)日:2003-06-17

    申请号:US09960730

    申请日:2001-09-24

    IPC分类号: C08G6908

    CPC分类号: C08G69/20 C08G69/18

    摘要: For the anionic polymerization of lactams: (a) (i) a catalyst capable of creating a lactamate and (ii) a regulator chosen from amides of formula R1-NH—CO-R2, in which R1 can be substituted by an R3-CO—NH— or R3-0— radical and in which R1, R2 and R3 denote an aryl, alkyl or cycloalkyl radical, are dissolved in the molten lactam, (a1) the solution from stage (a) is cooled, optionally to the solid state in a form which can be divided, (a2) the product from stage (a1) is optionally reheated to a temperature below the polymerization temperature of the lactam, (a3) optionally, the product from stage (a1) is reheated and is maintained at a temperature between the melting temperature of the lactam and 15° C. above, and (b) the produce from any one of stages (a1), (a2) or (a3) is introduced into a mixing device or mold and is then heated to a temperature sufficient to obtain the bulk polymerization of the lactam.