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11.发明授权
公开(公告)号：US5840986A
公开(公告)日：1998-11-24
申请号：US923557
申请日：1997-09-04
IPC分类号： C07D295/04 , B01J31/26 , C07C209/60 , C07C211/08 , C07C211/23 , C07C211/25 , C07C211/26 , C07C211/43 , C07C211/54 , C07C209/26
CPC分类号： C07C209/60
摘要： A process for preparing N-alkyl-substituted aminoalkynes by reacting an alkyne with a carbonyl compound and an amine with heterogeneous catalysis in which an unsupported copper acetylide derived from malachite is used as the catalyst. The N-alkyl-substituted aminoalkyne have a wide variety of uses including their use as precursors for pharmaceuticals, their use in electroplating processes and their use as corrosion inhibitors.
摘要翻译： 通过使炔与羰基化合物和胺与非均相催化反应制备N-烷基取代的氨基炔烃的方法，其中使用源自孔雀石的未负载的乙炔化铜作为催化剂。 N-烷基取代的氨基炔具有多种用途，包括它们作为药物前体的用途，它们在电镀方法中的应用及其作为腐蚀抑制剂的用途。
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公开(公告)号：US5733838A
公开(公告)日：1998-03-31
申请号：US767382
申请日：1996-12-16
申请人： Maximilian Vicari , Klemens Flick , Johann-Peter Melder , Werner Schnurr , Joachim Wulff-Doring
发明人： Maximilian Vicari , Klemens Flick , Johann-Peter Melder , Werner Schnurr , Joachim Wulff-Doring
IPC分类号： B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30 , B01J23/00 , B01J23/56 , B01J23/72 , B01J31/00
CPC分类号： B01J37/0009 , B01J25/00 , B01J25/02 , B01J37/0018 , C07B31/00 , C07C253/30
摘要： A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.
摘要翻译： 通过从合金和助剂制备捏合材料制备基于铝合金和过渡金属的氢化催化剂，将捏合的材料转化成模制品，煅烧模制品并用碱金属氢氧化物处理煅烧的模制品，通过 使用的助剂是（a）聚乙烯醇和水或（b）硬脂酸的方法，根据本发明制备的催化剂用于氢化和氢解，特别是将脂族α，ω-二腈部分氢化成 脂肪族α，ω-氨基腈。
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公开(公告)号：US20070179051A1
公开(公告)日：2007-08-02
申请号：US10588391
申请日：2005-02-02
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F4/025 , C08F4/24 , C08F4/65916 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/18 , C08F2500/24 , C08F4/22 , C08F4/78
摘要： The invention relates to a process for preparing a supported catalyst, in particular for the polymerization and/or copolymerization of olefins, which comprises: a) preparing a hydrogel; b) milling the hydrogel to give a finely particulate hydrogel; c) producing a slurry based on the finely particulate hydrogel; d) drying the slurry comprising the finely particulate hydrogel to give the support for catalysts; e) producing the supported catalyst by applying at least one transition metal and/or at least one transition metal compound to the support for catalysts and, if appropriate, activating the applied metal and/or compound, wherein a finely particulate hydrogel in which at least 5% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦3 μm; and/or at least 40% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦12 μm, and/or at least 75% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦35 μm, is produced in step b) and a support which can be prepared as set forth in steps a) to d) is used to produce catalysts in step e).
摘要翻译： 本发明涉及一种制备负载型催化剂的方法，特别是用于烯烃的聚合和/或共聚合，其包括：a）制备水凝胶; b）研磨水凝胶以得到细颗粒水凝胶; c）基于细颗粒水凝胶生产浆料; d）干燥包含细颗粒状水凝胶的浆料，得到催化剂载体; e）通过将至少一种过渡金属和/或至少一种过渡金属化合物施加到催化剂的载体上，并且如果合适地活化所施加的金属和/或化合物，制备负载型催化剂，其中至少 基于颗粒的总体积，5体积％的颗粒具有在>0μm至<3μm的范围内的粒度; 和/或至少40体积％的颗粒，基于颗粒的总体积，其粒度范围为>0μm至≤12μm，和/或至少75体积％ 基于颗粒的总体积的颗粒具有在>0μm至<=35μm的范围内的粒度，在步骤b）中制备，并且可以如步骤a）至d所述制备的载体 ）用于在步骤e）中制备催化剂。
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14.发明申请Supported, titanized chromium catalyst and its use for preparing homopolymers and copolymers of ethylene 有权负载型，钛酸化铬催化剂及其制备乙烯均聚物和共聚物的用途公开(公告)号：US20060172884A1
公开(公告)日：2006-08-03
申请号：US11330071
申请日：2006-01-12
申请人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Doring , Gunther Schweier , Martin Lux , Peter Bauer
发明人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Doring , Gunther Schweier , Martin Lux , Peter Bauer
IPC分类号： C08F4/02
CPC分类号： C08F210/16 , C08F2410/04 , C08F4/24 , C08F4/69 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/04 , C08F2500/26
摘要： Novel supported, titanized chromium catalysts for the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins, a process for preparing them and to their use for the polymerization of olefins.
摘要翻译： 用于乙烯均聚和乙烯与α-烯烃的共聚合的新型负载的钛化铬催化剂，其制备方法及其用于烯烃聚合的方法。
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公开(公告)号：US6140545A
公开(公告)日：2000-10-31
申请号：US251462
申请日：1999-02-17
IPC分类号： C07C29/149 , C07C37/08
CPC分类号： C07C29/149 , C07C2101/14
摘要： In a process for preparing alcohols by gas phase hydrogenation of carboxylic acids or esters thereof at elevated temperature and elevated pressure in the presence of catalysts consisting of or comprising, as hydrogenating components, oxides of main group VI and/or subgroup IV, the hydrogenation is carried outa) at from 250.degree. C. to 400.degree. C. and from 5 bar to 100 bar in the presence ofb) primary or secondary alcohols, the molar hydrogen/alcohol ratio being at most 800.
摘要翻译： 在通过在升高的温度和升高的压力下，在由主要VI族和/或第IV族的氧化物组成或包含氢化组分的催化剂存在下，在羧酸或其酯的气相氢化制备醇的方法中，氢化是 在b）伯醇或仲醇的存在下，在250℃至400℃和5巴至100巴下进行a），氢/醇摩尔比为至多800。
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公开(公告)号：US6034029A
公开(公告)日：2000-03-07
申请号：US992569
申请日：1997-12-17
IPC分类号： B01J21/06 , B01J23/10 , B01J35/00 , B01J35/10 , B01J37/03 , C01G25/00 , C01G25/02 , B01J23/00 , B01J21/08 , C01B17/96
CPC分类号： B01J21/066 , B01J37/031 , C01G25/00 , C01G25/02 , B01J35/002 , B01J35/1019 , C01P2002/30 , C01P2002/72 , C01P2006/12
摘要： Zirconium dioxide which is monoclinic to at least 80% by weight and has a BET surface area of at least 100 m.sup.2 /g is prepared by admixing aqueous zirconium salt solutions with ammonia, drying and calcining the precipitation product, aging the precipitation product, prior to drying, in aqueous phase at from 0 to 300.degree. C. and carrying out the calcination at from 200 to 600.degree. C.
摘要翻译： 通过将锆盐水溶液与氨混合，干燥并煅烧沉淀产物，使沉淀产物老化，然后将沉淀产物老化，制备单斜晶至至少80重量％并具有至少100m 2 / g的BET表面积的二氧化锆 在0-300℃的水相中干燥，并在200-600℃进行煅烧。
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公开(公告)号：US6013844A
公开(公告)日：2000-01-11
申请号：US115803
申请日：1998-07-15
IPC分类号： B01J23/44 , C07B61/00 , C07C33/26 , C07C37/00 , C07C37/055 , C07C37/06 , C07C37/07 , C07C37/50 , C07C39/08 , C07C41/18 , C07C41/28 , C07C43/205 , C07C43/23 , C07C41/00
CPC分类号： B01J35/1014 , B01J21/066 , B01J23/44 , B01J27/045 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0036 , C07C37/50 , C07C41/26 , C07C41/28
摘要： A process for preparing catechol monoethers or catechols of the formula Ia or Ib ##STR1## where R.sup.1 and R.sup.2 are, independently of one another, hydrogen or C.sub.1 -C.sub.8 hydrocarbon radicals, and R.sup.3 is a C.sub.1 -C.sub.8 hydrocarbon radical, which comprises a 2-hydroxycyclohexanone dialkyl ketal of the formula II or a 2-alkoxycyclohexanone of the formula III ##STR2## a) being reacted in the gas phase in the presence of palladium on zirconium oxide as catalyst to obtain compounds Ia orb) carrying out stage a) in the presence of water to obtain compounds Ib.
摘要翻译： 制备式Ia或Ib的邻苯二酚单醚或邻苯二酚的方法，其中R 1和R 2彼此独立地为氢或C 1 -C 8烃基，R 3为C 1 -C 8烃基，其包含2-羟基环己酮二烷基 式II的缩酮或式IIIa的2-烷氧基环己酮在气相中在作为催化剂的氧化锆上的钯的存在下反应，得到化合物Ia或b）在水存在下进行阶段a） 得到化合物Ib。
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18.发明授权Catalysts for the amination of alkylene oxides, alcohols, aldehydes and ketones 失效用于胺化环氧烷，醇，醛和酮的催化剂
公开(公告)号：US5958825A
公开(公告)日：1999-09-28
申请号：US955121
申请日：1997-10-21
申请人： Joachim Wulff-Doring , Johann-Peter Melder , Gerhard Schulz , Guido Voit , Frank Gutschoven , Wolfgang Harder
发明人： Joachim Wulff-Doring , Johann-Peter Melder , Gerhard Schulz , Guido Voit , Frank Gutschoven , Wolfgang Harder
IPC分类号： B01J23/89 , B01J37/18 , C07B61/00 , C07C209/16 , C07C211/00 , C07C211/10 , B01J23/00 , B01J23/42 , B01J23/58 , B01J23/72
CPC分类号： C07C209/16 , B01J23/8926 , B01J23/8933
摘要： A catalyst comprising, based on the total weight of the catalyst,more than 6-50% by weight of cobalt, nickel or a mixture thereof,0.001-25% by weight of ruthenium,0-10% by weight of copper and0-5% by weight of promoterson a porous metal oxide carrier can be prepared by(a) impregnating the carrier with the metals, promoters or compounds thereof,(b) drying and calcining the impregnated carrier and(c) reducing the calcined carrier in a stream of hydrogen,carrier not being impregnated with halogen compounds.
摘要翻译： 一种催化剂，其基于催化剂的总重量计，含有大于6-50重量％的钴，镍或其混合物，0.001-25重量％的钌，0-10重量％的铜和0- 多孔金属氧化物载体上5％（重量）的助催化剂可以通过（a）用金属，促进剂或其化合物浸渍载体来制备，（b）干燥和煅烧所浸渍的载体，和（c）将煅烧载体还原成 氢气流，载体不被卤素化合物浸渍。
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公开(公告)号：US5679869A
公开(公告)日：1997-10-21
申请号：US567749
申请日：1995-12-05
IPC分类号： B01J23/10 , B01J23/06 , C07B61/00 , C07C45/41 , C07C47/02 , C07C47/105 , C07C47/14 , C07C47/19 , C07C47/198 , C07C47/228 , C07C47/28
摘要： A process for preparing aldehydes of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.12 -alkylphenyl, C.sub.7 -C.sub.12 -phenylalkyl and R.sup.1 and R.sup.2 are joined together to form a 3-, 4-, 5-, 6- or 7-membered cycloaliphatic ring, R.sup.1 and R.sup.3 are each C.sub.1 -C.sub.4 -alkoxy, phenoxy, methylamino, dimethylamino or halogen, and R.sup.1 is additionally hydroxyl or amino comprises reacting a carboxylic acid or ester of the general formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each as defined above, and R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.12 -alkylphenyl or C.sub.7 -C.sub.12 -phenylalkyl, with hydrogen in the gas phase at temperatures from 200.degree. to 450.degree. C. and pressures from 0.1 to 20 bar in the presence of a catalyst whose catalytically active mass comprises from 60 to 99.9% by weight of zirconium oxide and from 0.1 to 40% by weight of one or more elements of the lanthanides.
摘要翻译： 制备通式I（I）的醛的方法，其中R1，R2和R3各自为氢，C1-C6烷基，C3-C8-环烷基，芳基，C7-C12-烷基苯基，C7-C12- 苯基烷基和R 1和R 2连接在一起形成3-，4-，5-，6-或7-元环脂族环，R 1和R 3各自为C 1 -C 4 - 烷氧基，苯氧基，甲基氨基，二甲基氨基或卤素，R 1 另外羟基或氨基包括使通式II（II）的羧酸或酯与其中R 1，R 2和R 3各自如上所定义，R 4是氢，C 1 -C 6烷基，C 3 -C 8 - 环烷基，芳基，C 7 -C 12 - 烷基苯基或C 7 -C 12 - 苯基烷基，在气相中的氢气在200-450℃的温度和0.1至20巴的压力下，在催化剂存在下，其催化活性质量包含 60至99.9重量％的氧化锆和0.1至40重量％的一种或多种镧系元素。
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公开(公告)号：US20090076306A1
公开(公告)日：2009-03-19
申请号：US12159099
申请日：2006-12-21
申请人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
发明人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C209/00 , C07C211/46
CPC分类号： C07C209/18 , C07C211/45
摘要： A process for continuously preparing a primary aromatic amine by reacting a corresponding cycloaliphatic alcohol with ammonia in the presence of hydrogen at a temperature in the range from 80 to 350° C. in the presence of a heterogeneous catalyst, wherein the catalytically active composition of the catalyst, before its reduction with hydrogen, comprises from 90 to 99.8% by weight of zirconium dioxide (ZrO2), from 0.1 to 5.0% by weight of oxygen compounds of palladium and from 0.1 to 5.0% by weight of oxygen compounds of platinum.
摘要翻译： 一种在多异性催化剂存在下，在80-350℃的温度下，在氢气存在下使相应的脂环族醇与氨反应连续制备伯芳香胺的方法，其中催化活性组合物 催化剂在用氢还原之前包含90-99.8重量％的二氧化锆（ZrO 2），0.1-5.0重量％的氧化合物钯和0.1-5.0重量％的氧化合物铂。
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