公开(公告)号：US5898023A

公开(公告)日：1999-04-27

申请号：US47055

申请日：1998-03-24

Applicant: Manuel A. Francisco ,  Jason Z. Gao ,  Kim E. Fyfe

Inventor： Manuel A. Francisco ,  Jason Z. Gao ,  Kim E. Fyfe

IPC: C10M133/04 ,  C10M135/08 ,  C10M141/08 ,  C10M163/00 ,  C10M129/68

CPC classification number: C10M163/00 ,  C10M141/08 ,  C10M2215/04 ,  C10M2215/064 ,  C10M2215/065 ,  C10M2215/086 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/085

Abstract: A lube oil composition that inhibits lubricant viscosity increase and dispersancy decrease is described. The composition includes an oil of lubricating viscosity and a mixture of specified functionalized derivatives of pentaerythritol tetrakis 3-mercaptopropionate and amine antioxidants.

Abstract translation: 描述了抑制润滑剂粘度增加和分散降低的润滑油组合物。 该组合物包括润滑粘度的油和季戊四醇四硫代三巯基丙酸酯的特定官能化衍生物和胺抗氧化剂的混合物。

公开(公告)号：US5750478A

公开(公告)日：1998-05-12

申请号：US808101

申请日：1997-02-28

Applicant: Jeenok T. Kim ,  Paul Joseph Berlowitz ,  Manuel A. Francisco ,  Morton Beltzer

Inventor： Jeenok T. Kim ,  Paul Joseph Berlowitz ,  Manuel A. Francisco ,  Morton Beltzer

IPC: C10M169/04 ,  C10M141/06 ,  C10M141/08

CPC classification number: C10M169/04 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/2835 ,  C10M2207/286 ,  C10M2215/064 ,  C10M2215/065 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/223 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/30 ,  C10M2219/02 ,  C10M2219/108 ,  C10M2223/02 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2223/042 ,  C10M2223/043 ,  C10M2223/049 ,  C10M2223/10 ,  C10N2240/14

Abstract: This invention relates to synthetic based turbo oils, preferably polyol ester-based turbo oils which exhibit exceptional load-carrying capacity by use of a synergistic combination of sulfur (S)-based and phosphorous (P)-based load additives. The S-containing additive of the present invention is sulfurized fatty acid (SFA), preferably the sulfurized oleic acid (SOA) and the P-containing additive is one or more amine phosphate(s). The turbo oil composition consisting of the dual P/S additives of the present invention achieves an excellent load-carrying capacity, which is better than or equivalent to that obtained when each additive was used alone at a treat rate higher than the total additive combination treat rate, and this lower additive concentration requirement allows the turbo oil composition to meet or exceed U.S. Navy MIL-L-23699 requirements including Oxidation and Corrosion Stability and Si seal compatibility.

Abstract translation: 本发明涉及合成基涡轮油，优选多醇酯基涡轮油，其通过使用基于硫（S）和基于磷（P）的负载添加剂的协同组合而表现出优异的负载能力。 本发明的含S添加剂是硫化脂肪酸（SFA），优选硫化油酸（SOA），含P的添加剂是一种或多种磷酸胺。 由本发明的双重P / S添加剂组成的涡轮油组合物实现了优异的承载能力，其优于或等同于当单独使用每种添加剂时的处理速率高于总添加剂组合处理 速率，并且这种较低的添加剂浓度要求允许涡轮油组合物满足或超过美国海军MIL-L-23699要求，包括氧化和腐蚀稳定性和Si密封相容性。

公开(公告)号：US5569404A

公开(公告)日：1996-10-29

申请号：US390728

申请日：1995-02-17

Applicant: Manuel A. Francisco ,  Kenneth D. Rose

Inventor： Manuel A. Francisco ,  Kenneth D. Rose

IPC: C10M131/08 ,  C10M125/18 ,  C10M133/06 ,  C10N30/10

CPC classification number: C10M125/18 ,  C10M133/06 ,  C10M2201/08 ,  C10M2201/081 ,  C10M2201/082 ,  C10M2201/084 ,  C10M2215/04 ,  C10M2215/26 ,  C10M2219/044 ,  C10M2219/046

Abstract: The present invention provides for the use of certain oil soluble iodides to enhance the oxidation resistance of lubricating oils and fuels, and for the novel formulated compositions containing these iodides. Oil soluble iodides such as C.sub.16 to C.sub.78 alkyl ammonium as well as oil solubilizable or dispersible iodides such as CoI.sub.2, CuI, KI and NaI in combination with a suitable dispersing agent may be used. Typically a minor amount of additive, from about 40 to about 1000 ppm is used. The additive is effective as an antioxidant in a variety of different types of base and formulated oils.

Abstract translation: 本发明提供了使用某些油溶性碘化物以增强润滑油和燃料的抗氧化性，以及含有这些碘化物的新型配制组合物。 可以使用油溶性碘化物如C16至C78烷基铵以及油可溶解或可分散的碘化物如CoI 2，CuI，KI和NaI与合适的分散剂的组合。 通常使用少量的添加剂，约40至约1000ppm。 该添加剂作为各种不同类型的基础和配制的油中的抗氧化剂是有效的。

公开(公告)号：US10035959B2

公开(公告)日：2018-07-31

申请号：US14308905

申请日：2014-06-19

Applicant: Ramanathan Sundararaman ,  Thomas Francis Degnan, Jr. ,  Rustom Merwan Billimoria ,  Natalie Ann Fassbender ,  Manuel A. Francisco ,  Anjaneya Sarma Kovvali ,  Randolph J. Smiley ,  John Peter Greeley ,  William Ernest Lewis ,  Roby Bearden, Jr.

Inventor： Ramanathan Sundararaman ,  Thomas Francis Degnan, Jr. ,  Rustom Merwan Billimoria ,  Natalie Ann Fassbender ,  Manuel A. Francisco ,  Anjaneya Sarma Kovvali ,  Randolph J. Smiley ,  John Peter Greeley ,  William Ernest Lewis ,  Roby Bearden, Jr.

IPC: C10G47/26 ,  C10G49/06 ,  C10G49/12 ,  C10G69/14 ,  C10G49/04 ,  C10G69/06 ,  C10G9/00

CPC classification number: C10G49/12 ,  C10G9/005 ,  C10G49/04 ,  C10G49/06 ,  C10G69/06 ,  C10G69/14

Abstract: Systems and methods are provided for slurry hydroconversion of a heavy oil feed, such as an atmospheric or vacuum resid. The systems and methods allow for slurry hydroconversion using catalysts with enhanced activity and/or catalysts that can be recycled as a side product from a complementary refinery process.

公开(公告)号：US20160264878A1

公开(公告)日：2016-09-15

申请号：US14645977

申请日：2015-03-12

Applicant: Manuel A. FRANCISCO ,  Roberto GARCIA

Inventor： Manuel A. FRANCISCO ,  Roberto GARCIA

IPC: C10G27/12

CPC classification number: C10G27/12 ,  C10G2300/205

Abstract: Heavy oils containing metalloporphyrins principally of nickel and vanadium are demetallized using an oxidizing agent such as aqueous hydrogen peroxide and catalytic amounts of phosphoric acid, preferably with tungstic acid in combination with a phase transfer agent. Up to 99% of the Ni and V are deposited in the aqueous phase and are removed from the oil. The homogenous, water soluble reactants and catalyst have the advantage of being separated more easily from the Ni and V dissolved in the aqueous phase than the same metals deposited on solid phase heterogeneous catalysts.

Abstract translation: 主要含镍和钒的金属卟啉的重油使用氧化剂如过氧化氢水溶液和催化量的磷酸，优选与钨酸结合相转移剂脱金属脱金属。 最多99％的Ni和V沉积在水相中并从油中除去。 均匀的水溶性反应物和催化剂具有比沉积在固相多相催化剂上的相同金属更容易从溶解在水相中的Ni和V分离的优点。

公开(公告)号：US20140374314A1

公开(公告)日：2014-12-25

申请号：US14308905

申请日：2014-06-19

Applicant: Ramanathan SUNDARARAMAN ,  Thomas Francis DEGNAN, JR. ,  Rustom Merwan BILLIMORIA ,  Natalie Ann FASSBENDER ,  Manuel A. FRANCISCO ,  Anjaneya Sarma KOVVALI ,  Randolph J. SMILEY ,  John Peter GREELEY ,  William Ernest LEWIS ,  Roby BEARDEN, JR.

Inventor： Ramanathan SUNDARARAMAN ,  Thomas Francis DEGNAN, JR. ,  Rustom Merwan BILLIMORIA ,  Natalie Ann FASSBENDER ,  Manuel A. FRANCISCO ,  Anjaneya Sarma KOVVALI ,  Randolph J. SMILEY ,  John Peter GREELEY ,  William Ernest LEWIS ,  Roby BEARDEN, JR.

IPC: C10G49/12 ,  C10G49/06 ,  C10G69/14

CPC classification number: C10G49/12 ,  C10G9/005 ,  C10G49/04 ,  C10G49/06 ,  C10G69/06 ,  C10G69/14

Abstract: Systems and methods are provided for slurry hydroconversion of a heavy oil feed, such as an atmospheric or vacuum resid. The systems and methods allow for slurry hydroconversion using catalysts with enhanced activity and/or catalysts that can be recycled as a side product from a complementary refinery process.

Abstract translation: 提供了用于重油进料（例如大气压或真空渣油）的浆料加氢转化的系统和方法。 这些系统和方法允许使用具有增强活性的催化剂和/或催化剂进行浆料加氢转化，所述催化剂可以作为辅助炼油方法的副产物回收。

公开(公告)号：US06232276B1

公开(公告)日：2001-05-15

申请号：US08844019

申请日：1997-04-18

Applicant: Edward Ira Stiefel ,  Jonathan M. McConnachie ,  Daniel Paul Leta ,  Manuel A. Francisco ,  Catherine Louise Coyle ,  Peter John Guzi ,  Charles F. Pictroski

Inventor： Edward Ira Stiefel ,  Jonathan M. McConnachie ,  Daniel Paul Leta ,  Manuel A. Francisco ,  Catherine Louise Coyle ,  Peter John Guzi ,  Charles F. Pictroski

IPC: C10M13900

CPC classification number: C07F11/005 ,  C10M135/18 ,  C10M137/10 ,  C10M159/18 ,  C10M2219/068 ,  C10M2223/045 ,  C10M2227/09 ,  C10N2210/06 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106

Abstract: A lubricating oil composition is provided comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one trinuclear molybdenum compound. Preferably, the trinuclear molybdenum compound is selected from those compounds having the formula Mo3SkL4Qz and mixtures thereof in which L is a ligand having organo groups with a sufficient number of carbon atoms to render the compound soluble in the oil, k varies from 4 through 7, Q is selected from the group of compounds having lone pair electrons including water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5. In general, the organo groups of the mono-anionic ligands will be the same although they may be different, and they preferably are selected from alkyl, aryl, substituted aryl, and ether groups. For example, when L is a dialkyldithiocarbamate or a dialkyldithiophosphate, the alkyl groups will have from about 1 to 30 carbon atoms.

Abstract translation: 提供润滑油组合物，其包含主要量的润滑粘度的油和少量的至少一种三核钼化合物。 优选地，三核钼化合物选自具有式Mo 3 S k L 4 Q z的那些化合物及其混合物，其中L是具有足够数目碳原子的有机基团的配体，以使化合物可溶于油，k从4至7变化， Q选自具有包括水，胺，醇，膦和醚在内的单对电子的化合物的组，z的范围为0至5.通常，单阴离子配体的有机基团将是相同的，尽管它们 可以不同，它们优选选自烷基，芳基，取代的芳基和醚基。 例如，当L是二烷基二硫代氨基甲酸酯或二烷基二硫代磷酸酯时，烷基将具有约1至30个碳原子。

公开(公告)号：US5422023A

公开(公告)日：1995-06-06

申请号：US135212

申请日：1993-10-12

Applicant: Manuel A. Francisco

Inventor： Manuel A. Francisco

IPC: C10M161/00 ,  C10M169/04 ,  C10M133/58

CPC classification number: C10M169/044 ,  C10M161/00 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/2835 ,  C10M2207/286 ,  C10M2209/086 ,  C10M2219/10 ,  C10M2219/102 ,  C10M2219/104 ,  C10M2219/106 ,  C10M2219/108 ,  C10N2230/08 ,  C10N2230/12 ,  C10N2240/00 ,  C10N2240/02 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/102 ,  C10N2240/103 ,  C10N2240/104 ,  C10N2240/105 ,  C10N2240/106 ,  C10N2240/12 ,  C10N2240/121 ,  C10N2240/14 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66

Abstract: A lubricating oil composition for jet engines which comprises: (a) an aviation turbine oil; (b) from about 0.025 to about 5.0 wt %, based on lubricating oil composition, of a dimercaptothiadiazole of the formula: ##STR1## where R and R.sup.1 are each independently hydrogen or hydrocarbyl radical having from 1 to 20 carbon atoms; and (c) from about 1.0 to about 30.0 wt %, based on lubricating oil composition, of an alphaolefin/maleic ester copolymer of the formula ##STR2## where R.sup.3 and R.sup.4 are each independently C.sub.1 to C.sub.18 alkyl, and n is an integer such that the average molecular weight of the copolymer is from 500 to 20,000.

Abstract translation: 一种用于喷气发动机的润滑油组合物，包括：（a）航空涡轮机油; （b）基于润滑油组合物的约0.025至约5.0重量％的下式的二巯基噻二唑其中R和R 1各自独立地为氢或具有1至20个碳原子的烃基; 和（c）基于润滑油组合物的约1.0至约30.0重量％的式（Ia）的α-烯烃/马来酸酯共聚物，其中R 3和R 4各自独立地为C 1至C 18烷基，n为 是共聚物的平均分子量为500〜20,000的整数。

公开(公告)号：US09816039B2

公开(公告)日：2017-11-14

申请号：US14810130

申请日：2015-07-27

Applicant: Manuel A. Francisco ,  Thomas Francis Degnan, Jr. ,  Colin L. Beswick ,  Ramanathan Sundararaman

Inventor： Manuel A. Francisco ,  Thomas Francis Degnan, Jr. ,  Colin L. Beswick ,  Ramanathan Sundararaman

IPC: C10G67/12 ,  C10G55/06 ,  C10G55/04 ,  C10G27/04 ,  C10G27/12

CPC classification number: C10G67/12 ,  C10G27/04 ,  C10G27/12 ,  C10G55/04 ,  C10G55/06 ,  C10G2300/1033 ,  C10G2300/1077 ,  C10G2300/1096

Abstract: A heavy petroleum oil feed is upgraded by having its amenability to cracking improved by subjecting the oil to selective partial oxidation with a catalytic oxidation system to partially oxidize aromatic ring systems in the heavy oil. The partially oxidized oil can then be cracked in the conventional manner but at lower severities to lower molecular weight cracking products. The cracking following the partial oxidation step may be thermal in nature as by thermal cracking, delayed, contact or fluid coking or fluid catalytic cracking or hydrogenative as in hydrocracking.

公开(公告)号：US20160060550A1

公开(公告)日：2016-03-03

申请号：US14810130

申请日：2015-07-27

Applicant: Manuel A. Francisco ,  Thomas Francis DEGNAN, JR. ,  Colin L. BESWICK ,  Ramanathan SUNDARARAMAN

Inventor： Manuel A. Francisco ,  Thomas Francis DEGNAN, JR. ,  Colin L. BESWICK ,  Ramanathan SUNDARARAMAN

IPC: C10G67/12 ,  C10G55/04 ,  C10G55/06

CPC classification number: C10G67/12 ,  C10G27/04 ,  C10G27/12 ,  C10G55/04 ,  C10G55/06 ,  C10G2300/1033 ,  C10G2300/1077 ,  C10G2300/1096

Abstract: A heavy petroleum oil feed is upgraded by having its amenability to cracking improved by subjecting the oil to selective partial oxidation with a catalytic oxidation system to partially oxidize aromatic ring systems in the heavy oil. The partially oxidized oil can then be cracked in the conventional manner but at lower severities to lower molecular weight cracking products. The cracking following the partial oxidation step may be thermal in nature as by thermal cracking, delayed, contact or fluid coking or fluid catalytic cracking or hydrogenative as in hydrocracking.

Abstract translation: 重油石油进料通过使其通过用催化氧化体系进行选择性部分氧化以部分氧化重油中的芳香环体系来改善其改性的改性。 然后部分氧化的油可以以常规方式裂解，但是在较低的严重程度下破坏较低分子量的裂化产物。 在部分氧化步骤之后的裂化本质上可以是热裂解，延迟的，接触的或流体的焦化或流化催化裂化或加氢裂化中的氢化。