VINYL ESTER/ETHYLENE-BASED BINDERS FOR PAPER AND PAPERBOARD COATINGS
    11.
    发明申请
    VINYL ESTER/ETHYLENE-BASED BINDERS FOR PAPER AND PAPERBOARD COATINGS 审中-公开
    乙烯基酯/乙烯基纸和纸板涂料的粘合剂

    公开(公告)号:US20120021237A1

    公开(公告)日:2012-01-26

    申请号:US12839662

    申请日:2010-07-20

    Abstract: Disclosed are surfactant-stabilized latex emulsions which can be used as binders in paper coating compositions. Such latex emulsions comprise an interpolymer formed by emulsion polymerizing monomers selected from vinyl esters, e.g., vineyl acetate; ethylene; certain unsaturated mono- and di-carboxylic acid materials such as acrylic acid or maleic anhydride; and certain polyethylenically unsaturated cross-linking co-monomers such as diallyl phthalate. These latex emulsions are stabilized with surfactants which are substantially free of environmentally suspect alkyl phenol ethoxylates (APEs). The paper coating compositions containing latex emulsion binders of this type exhibit especially desirable coating strength as quantified by the Dry Pick Values (as defined herein) which such compositions provide.

    Abstract translation: 公开了可用作纸涂料组合物中的粘合剂的表面活性剂稳定的胶乳乳液。 这种胶乳乳液包含通过乳液聚合选自乙烯基酯的单体形成的互聚物,例如乙酸葡萄酯; 乙烯; 某些不饱和单羧酸和二羧酸物质如丙烯酸或马来酸酐; 和某些多烯属不饱和交联共聚单体如邻苯二甲酸二烯丙酯。 这些胶乳乳液用基本上不含环保的烷基酚乙氧基化物(APE)的表面活性剂稳定。 含有这种胶乳乳液粘合剂的纸张涂料组合物显示出特别理想的涂层强度,其通过这种组合物提供的干燥选择值(如本文所定义)而定量。

    Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same
    13.
    发明申请
    Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same 失效
    盐敏乙酸乙烯酯粘合剂组合物和掺入其的纤维制品

    公开(公告)号:US20060252876A1

    公开(公告)日:2006-11-09

    申请号:US11120372

    申请日:2005-05-03

    Abstract: A salt sensitive polymeric binder for use in fibrous webs, where the binder contains a copolymer incorporating the residue of vinyl acetate, a carboxylic acid, and a vinyl ester of a saturated aliphatic monocarboxylic acid having between 6 and 18 carbon atoms in the carboxylic acid moiety. The copolymer is neutralized at least to the extent that it is water soluble. The binders are particularly suitable for strengthening non-woven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like.

    Abstract translation: 用于纤维网的盐敏聚合物粘合剂,其中粘合剂含有在羧酸部分中含有6-18个碳原子的饱和脂族一元羧酸的残基的羧酸和羧酸残基的共聚物 。 至少将共聚物中和到水溶性的程度。 粘合剂特别适用于在一次性制品如湿巾,个人护理产品,尿布等中加强非织造纤维网。

    Carpets with surfactant-stabilized emulsion polymer carpet binders for improved processability

    公开(公告)号:US10301772B2

    公开(公告)日:2019-05-28

    申请号:US13695851

    申请日:2011-05-03

    Abstract: Disclosed are improved carpet products made using certain types of coating compositions to secure carpet fibers to a carpet backing or substrates and/or to secure one or more carpet scrims or other layers to carpet backing. The coating compositions, which can be in the form of either precoating or skip coating compositions, are made from latex binder emulsions based on interpolymers emulsion polymerized from vinyl esters, ethylene, and a multifunctional cross-linking co-monomer such as an unsaturated silane. Such emulsions are also stabilized with surfactant emulsifiers but are substantially free of protective colloid stabilizers. The multifunctional co-monomer alters interpolymer molecular weight, branching and/or flow properties such that films formed from such interpolymers exhibit relatively low elongation values. When the emulsion binder exhibits such non-elongating film-forming characteristics, the carpet coating composition made from such binders can be easily processed without build-up on carpet processing apparatus. Such binder emulsions which are stabilized substantially only with surfactant emulsifiers, and not with protective colloids, also have excellent compatibility with other coating composition components.

    FUNCTIONALIZED VINYL ACETATE ETHYLENE BINDERS FOR PAPER AND PAPERBOARD COATINGS
    17.
    发明申请
    FUNCTIONALIZED VINYL ACETATE ETHYLENE BINDERS FOR PAPER AND PAPERBOARD COATINGS 审中-公开
    功能性醋酸乙烯酯纸和纸板涂料

    公开(公告)号:US20160115649A1

    公开(公告)日:2016-04-28

    申请号:US14406893

    申请日:2012-09-10

    Abstract: A paper product comprising a planar fibrous cellulose substrate, and a coating composition disposed on a surface of said substrate comprising an interpolymer prepared by the emulsion polymerization of (i) one or more vinyl ester monomers; (ii) ethylene; (iii) an unsaturated silane co-monomer; and (iv) one or more emulsion-stabilizing ionic co-monomers comprising one or more of unsaturated, substituted sulfonic acid, one or more of an unsaturated phosphonic acid, or an ester of one of those acids, in the presence of (v) a stabilizing system which comprises one or more anionic and/or nonionic surfactants but less than about 1 pphm of any protective colloid material; and (v) water.

    Abstract translation: 一种纸制品,其包含平面纤维素纤维素基质和涂布组合物,所述涂料组合物设置在所述基材的表面上,所述涂料组合物包含通过(i)一种或多种乙烯基酯单体的乳液聚合制备的互聚物; (ii)乙烯; (iii)不饱和硅烷共聚单体; 和(iv)一种或多种乳液稳定的离子共聚单体,其包含一种或多种不饱和的,取代的磺酸,一种或多种不饱和膦酸或这些酸之一的酯,在(v) 稳定系统,其包含一种或多种阴离子和/或非离子表面活性剂,但小于约1pphm的任何保护胶体材料; 和(v)水。

    Alkali neutralizing acquisition and distribution structures for use in personal care articles
    18.
    发明授权
    Alkali neutralizing acquisition and distribution structures for use in personal care articles 有权
    用于个人护理用品的碱性中和采集和分配结构

    公开(公告)号:US08785714B2

    公开(公告)日:2014-07-22

    申请号:US13036606

    申请日:2011-02-28

    Abstract: Disclosed herein are nonwoven fibrous structures for use as body fluid acquisition/distribution elements in personal care products. Such structures comprise natural and/or synthetic fibers wherein the fibers have been consolidated by application thereto, and by cross-linking of, a certain type of cross-linkable, vinyl acetate-ethylene (VAE) emulsion copolymer latex binder. The VAE latex binder is one which also comprises an added organic acidulant such as citric acid. Consolidation of the structures with VAE-based binders to which the organic acidulant has been added imparts to the resulting structures the ability to lower the pH of body fluids such as urine passing through the structures. This effect, in turn, provides odor control and skin care benefits to the absorbent articles, e.g., diapers and adult incontinence products, using such structures as acquisition/distribution elements.

    Abstract translation: 本文公开了用作个人护理产品中的体液采集/分配元件的非织造纤维结构。 这种结构包括天然和/或合成纤维,其中纤维已通过施用而被固化,并且通过交联某种类型的可交联乙酸乙烯酯 - 乙烯(VAE)乳液共聚物胶乳粘合剂。 VAE胶乳粘合剂还包括添加的有机酸化剂如柠檬酸。 已经添加有机酸化剂的具有VAE的粘合剂的结构的固结赋予所得结构降低体液(例如穿过结构物的尿液)的pH值的能力。 这种效果又使用诸如采集/分配元件之类的结构为吸收制品例如尿布和成人失禁产品提供气味控制和护肤益处。

    Coating composition for inkjet applications
    19.
    发明授权
    Coating composition for inkjet applications 失效
    用于喷墨应用的涂料组合物

    公开(公告)号:US06734244B2

    公开(公告)日:2004-05-11

    申请号:US10241934

    申请日:2002-09-11

    Abstract: The present invention relates to a coating composition for fibrous substances containing 25 to 75 percent by weight of pigment, and 0.5 to 25 weight percent of a polymer comprising 1 to 15 percent by weight of one or more monomers having sterically hindered secondary amine groups and 10 to 40 weight percent of a carboxylic acid monomer. The coating is useful on fibrous and non-fibrous substrates on which liquid inks will be fixed. The non-ionic polymer becomes cationic when contacted by anionic inks, and the cationic nature of the coating provides the substrate with an excellent point of attachment for inks and dyes, resulting in bright, crisp printed images. The coating is especially useful for ink-jet printing on paper, paperboard, textiles, non-wovens, wood, and films.

    Abstract translation: 本发明涉及含有25〜75重量%颜料的纤维状物质用涂料组合物和0.5〜25重量%的含有1〜15重量%的一种或多种具有位阻仲胺基团的单体的聚合物和10重量% 至40重量%的羧酸单体。 涂层可用于固定液体油墨的纤维和非纤维基材上。 当与阴离子油墨接触时,非离子聚合物变为阳离子型,并且涂层的阳离子性质为基材提供了油墨和染料的优异的附着点,从而产生明亮且清晰的印刷图像。 该涂料对于在纸,纸板,纺织品,无纺布,木材和薄膜上的喷墨打印特别有用。

    Pressure sensitive adhesive compositions prepared with a sterically hindered alkoxylated silane
    20.
    发明授权
    Pressure sensitive adhesive compositions prepared with a sterically hindered alkoxylated silane 失效
    用空间位阻烷氧基化硅烷制备的压敏粘合剂组合物

    公开(公告)号:US06541566B1

    公开(公告)日:2003-04-01

    申请号:US09166050

    申请日:1998-10-05

    CPC classification number: C08F230/08

    Abstract: A pressure sensitive adhesive which is prepared by emulsion polymerizing an ethylenically unsaturated monomer and 0.01 to 2 pphm of a sterically hindered alkoxylated silane monomer. The silane crosslinks during film formation to provide the adhesive with increased shear strength without the disadvantage of decreased loop tack. The sterically hindered alkoxylated silane monomer has the structure R1—Si—(OR2)n(R3)3−n wherein R1 is selected from the group consisting of an alkylene, arylene, and aralkylene group; R2 is independently a sterically hindered alkyl group having 3 to 10 carbon atoms in a straight or branched chain configuration; R3 is a monovalent alkyl group having 1 to 10 carbon atoms; and n is an integer of from 1 to 3.

    Abstract translation: 通过将烯键式不饱和单体和0.01至2pphm的空间位阻烷氧基化硅烷单体乳液聚合制备的压敏粘合剂。 硅烷在成膜期间交联,以提供具有增加的剪切强度的粘合剂,而不会降低环粘性。 空间位阻烷氧基化硅烷单体具有R1-Si-(OR2)n(R3)3-n的结构,其中R1选自亚烷基,亚芳基和亚芳基; R2独立地为直链或支链构型的具有3-10个碳原子的空间位阻烷基; R3是具有1-10个碳原子的一价烷基; n为1〜3的整数。

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