公开(公告)号：US20170362984A1

公开(公告)日：2017-12-21

申请号：US15532751

申请日：2015-12-08

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: F01N3/20 ,  B01D53/94 ,  F01N3/08 ,  B01J37/08 ,  B01J37/02 ,  B01J35/10 ,  B01J35/04 ,  B01J35/00 ,  B01J33/00 ,  B01J23/46 ,  B01J23/44 ,  B01J23/42 ,  B01J23/10 ,  F01N3/10 ,  F01N3/28

CPC classification number: F01N3/2066 ,  B01D53/9427 ,  B01D53/945 ,  B01D53/9468 ,  B01D53/9472 ,  B01D2255/1025 ,  B01D2255/2065 ,  B01D2255/9022 ,  B01D2255/9032 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01D2257/402 ,  B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/63 ,  B01J33/00 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J37/08 ,  B01J37/082 ,  B01J37/088 ,  B01J2523/00 ,  F01N3/0842 ,  F01N3/101 ,  F01N3/2839 ,  Y02C20/10 ,  Y02T10/22 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/3706 ,  B01J2523/3718 ,  B01J2523/3725 ,  B01J2523/3737 ,  B01J2523/375

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US11801491B1

公开(公告)日：2023-10-31

申请号：US17725828

申请日：2022-04-21

Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC ,  University of Central Florida Research Foundation, Inc. ,  BASF Corporation

Inventor： Yuntao Gu ,  Fudong Liu ,  Wei Li ,  Shaohua Xie ,  Yuejin Li ,  Xiaolai Zheng

IPC: B01J21/04 ,  B01J23/10 ,  B01J23/44 ,  B01J23/63 ,  B01J35/04 ,  B01J37/02 ,  F01N3/10 ,  B01J6/00

CPC classification number: B01J23/44 ,  B01J6/001 ,  B01J21/04 ,  B01J23/10 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0236 ,  F01N3/101 ,  F01N2570/10 ,  F01N2570/12 ,  F01N2570/14

Abstract: A three-way catalyst for reduced palladium loading is provided. The catalyst includes an inert substrate and a palladium catalyst material coating the substrate. The palladium catalyst material includes a support material formed from one of 10% CeO2/Al2O3, 20% CeO2—Al2O3 (20CeAlOy), 30% CeO2—Al2O3 (30CeAlOy), Al2O3, and MOx-Al2O3, wherein M is one of copper, iron, manganese, titanium, zirconium, magnesium, strontium, and barium. The palladium catalyst material includes a layer of CeO2 material disposed upon the support material, wherein the layer of CeO2 material is dispersed on a surface of the support material. The palladium catalyst material includes an active component including a layer of praseodymium oxide particles dispersed across the surface of the layer of CeO2 material and a layer of palladium particles disposed upon and dispersed across the surface of the layer of CeO2 material at locations each corresponding to a respective location of each of the praseodymium particles.

公开(公告)号：US11713705B2

公开(公告)日：2023-08-01

申请号：US17483135

申请日：2021-09-23

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: B01J23/10 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/63 ,  B01J33/00 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  F01N3/08 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28 ,  B01D53/94 ,  B01J23/42 ,  B01J35/02

CPC classification number: F01N3/2066 ,  B01D53/9427 ,  B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/63 ,  B01J33/00 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J37/08 ,  B01J37/082 ,  B01J37/088 ,  F01N3/0842 ,  F01N3/101 ,  F01N3/2839 ,  B01D53/945 ,  B01D53/9468 ,  B01D53/9472 ,  B01D2255/1025 ,  B01D2255/2065 ,  B01D2255/9022 ,  B01D2255/9032 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01D2257/402 ,  B01J35/006 ,  B01J35/023 ,  B01J2523/00 ,  Y02C20/10 ,  Y02T10/12 ,  B01J2523/00 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3737 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/375 ,  B01J2523/822

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US11486288B2

公开(公告)日：2022-11-01

申请号：US16869622

申请日：2020-05-08

Applicant: BASF Corporation

Inventor： Kevin Hallstrom ,  David Youngren ,  Yuejin Li

IPC: F01N3/28 ,  B01D53/94 ,  B01J23/89 ,  B01J29/76 ,  B01J35/04 ,  B01J37/02 ,  F01N3/035 ,  F01N3/08 ,  F01N3/20

Abstract: The present disclosure is directed to a system for treating an exhaust gas stream from an engine, which includes a diesel oxidation catalyst (DOC) located downstream of the engine and adapted for oxidation of hydrocarbons and carbon monoxide, an injector adapted for the addition of a reductant to the exhaust gas stream located downstream of the DOC, a catalyzed soot filter (CSF) located downstream of the injector, and a selective catalytic reduction component adapted for the oxidation of nitrogen oxides located downstream of the CSF. The CSF is adapted for oxidizing hydrocarbons and includes a selective oxidation catalyst composition on a filter with high selectivity ratio for hydrocarbon oxidation:ammonia oxidation (e.g., at least 0.6).

公开(公告)号：US20220010714A1

公开(公告)日：2022-01-13

申请号：US17483135

申请日：2021-09-23

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: F01N3/20 ,  B01J37/02 ,  B01J35/00 ,  B01J23/10 ,  B01D53/94 ,  B01J35/10 ,  B01J23/46 ,  B01J23/52 ,  B01J23/63 ,  B01J23/42 ,  B01J23/44 ,  B01J33/00 ,  B01J35/04 ,  B01J37/08 ,  F01N3/08 ,  F01N3/10 ,  F01N3/28

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US11149610B2

公开(公告)日：2021-10-19

申请号：US16838751

申请日：2020-04-02

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: B01J23/10 ,  B01J23/46 ,  B01J23/63 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  F01N3/08 ,  F01N3/20 ,  B01D53/94 ,  B01J23/52 ,  B01J23/42 ,  B01J23/44 ,  B01J33/00 ,  F01N3/10 ,  F01N3/28 ,  B01J35/02

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US20200232366A1

公开(公告)日：2020-07-23

申请号：US16838751

申请日：2020-04-02

Applicant: BASF Corporation

Inventor： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC: F01N3/20 ,  B01J37/02 ,  B01J23/63 ,  B01J23/52 ,  B01J23/46 ,  F01N3/28 ,  F01N3/10 ,  F01N3/08 ,  B01J37/08 ,  B01J35/04 ,  B01J33/00 ,  B01J23/44 ,  B01J23/42 ,  B01J35/10 ,  B01D53/94 ,  B01J23/10 ,  B01J35/00

Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US10215073B2

公开(公告)日：2019-02-26

申请号：US15574910

申请日：2016-05-18

Applicant: BASF Corporation

Inventor： Alfred Punke ,  Gerd Grubert ,  Marcus Hilgendorff ,  Torsten Neubauer ,  Matthew Caudle ,  Yuejin Li

IPC: F01N3/28 ,  B01D53/94 ,  B01J23/44 ,  B01J23/42 ,  B01J37/02 ,  B01J29/76 ,  B01J29/78 ,  B01J35/04 ,  B01J37/04 ,  B01J37/08 ,  B01J35/00 ,  F01N3/20 ,  F01N3/035 ,  F01N13/00

Abstract: The present invention relates to catalyzed soot filter comprising a porous wall flow substrate, a catalyst for selective catalytic reduction (SCR), a palladium component, and a platinum component, the wall flow substrate comprising an inlet end, an outlet end, a substrate axial length extending between the inlet end and the outlet end, and a plurality of channels defined by internal walls of the wall flow substrate, wherein the plurality of channels comprise inlet channels having an open inlet end and a closed outlet end, and outlet channels having a closed inlet end and an open outlet end, and the SCR catalyst is provided on the entire surface of the inlet channel walls and on at least a portion of the surface of the pores within the channel walls underneath the surface of the channel walls coated with the SCR catalyst.

公开(公告)号：US20180038252A1

公开(公告)日：2018-02-08

申请号：US15555117

申请日：2016-03-24

Applicant: BASF CORPORATION

Inventor： Xiaofan Yang ,  Wen-Mei Xue ,  John K. Hochmuth ,  Matthew J. Schladt ,  Yuejin Li

IPC: F01N3/08 ,  B01J23/46 ,  B01J29/76 ,  B01J35/00 ,  F01N13/00 ,  B01D53/94 ,  F01N3/10 ,  F01N3/20 ,  F01N3/035 ,  B01J23/44 ,  B01J35/04

CPC classification number: F01N3/0814 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/944 ,  B01D53/9445 ,  B01D53/945 ,  B01D53/9463 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2258/014 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J29/04 ,  B01J29/072 ,  B01J29/763 ,  B01J35/0006 ,  B01J35/04 ,  F01N3/035 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/101 ,  F01N3/2066 ,  F01N13/0093 ,  F01N13/0097 ,  F01N2370/02 ,  Y02T10/22 ,  Y02T10/24

Abstract: Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream containing NOx, particulate matter, and sulfur. The exhaust gas treatment system comprises: one or more catalytic articles selected from a three-way conversion catalyst (TWC), a lean NOx trap (LNT), and an integrated LNT-TWC; a platinum-containing catalytic article downstream from the one or more catalytic articles; and one or more selective catalytic reduction (SCR) catalytic articles immediately downstream from the platinum-containing catalytic article, the one or more SCR catalytic articles including a molecular sieve. The system stabilizes the SCR catalytic article from poisoning by sulfur.

公开(公告)号：US20240207826A1

公开(公告)日：2024-06-27

申请号：US18555105

申请日：2022-04-15

Applicant: BASF Corporation ,  The Board of Trustees of the Leland Stanford Junior University

Inventor： Matteo Cargenllo ,  An-Chih Yang ,  Nadia Tahsini ,  Yuejin Li

IPC: B01J23/89 ,  B01D53/94 ,  B01J21/04 ,  B01J23/656 ,  B01J35/45 ,  B01J37/02 ,  F01N3/28

CPC classification number: B01J23/8926 ,  B01D53/94 ,  B01J21/04 ,  B01J23/6562 ,  B01J23/8913 ,  B01J23/892 ,  B01J35/45 ,  B01J37/0211 ,  F01N3/2803 ,  B01D2255/1021 ,  B01D2255/2073 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/9202 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/702 ,  B01D2258/01 ,  F01N2370/02

Abstract: Nanoparticles comprising a platinum group metal and a base metal, catalytic compositions comprising such nanoparticles and a support material, and methods of making such nanoparticles and catalytic compositions are disclosed. Catalytic articles and exhaust gas treatment systems, as well as methods of treating an exhaust gas stream comprising a pollutant using these catalytic articles and exhaust gas treatment systems, are also disclosed.