公开(公告)号：US20190046958A1

公开(公告)日：2019-02-14

申请号：US16158968

申请日：2018-10-12

申请人： BASF CORPORATION

发明人： Xinyi Wei ,  Olga Gerlach ,  Emily Schulman ,  Andreas Sunderman ,  Stanley Roth ,  Limiao An

IPC分类号： B01J23/42 ,  F01N3/10 ,  B01J23/44 ,  B01J21/06 ,  B01J35/10 ,  B01J35/04 ,  B01J35/00

摘要： The present invention provides an oxidation catalyst composition suitable for at least partial conversion of gaseous hydrocarbon emissions, e.g., methane. The oxidation catalyst composition includes at least one platinum group metal (PGM) component supported onto a porous zirconia-containing material that provides an effect on hydrocarbon conversion activity. The porous zirconia-containing material is at least 90% by weight in the monoclinic phase. Furthermore, the PGM component can comprise at least one platinum group metal in the form of colloidally deposited nanoparticles. The oxidation catalyst composition can be used in the treatment of emissions from lean compressed natural gas engines.

公开(公告)号：US10821423B2

公开(公告)日：2020-11-03

申请号：US15773705

申请日：2016-11-03

申请人： BASF Corporation

发明人： Oleg Ilinich ,  Stanley Roth

IPC分类号： B01J23/89 ,  B01D53/94 ,  B01J35/04 ,  F01N3/20 ,  B01J23/00 ,  B01J37/08 ,  B01J35/00 ,  B01J37/02 ,  F01N13/00 ,  B01J37/04 ,  F01N3/10 ,  F01N3/28

摘要： A diesel oxidation catalyst composition is provided, the composition including at least one platinum group metal impregnated onto a porous refractory oxide material in particulate form and at least one base metal oxide impregnated onto a porous refractory oxide material in particulate form, wherein the porous refractory oxide material impregnated with at least one platinum group metal and the porous refractory oxide material impregnated with at least one base metal oxide are in the form of a mixture or wherein the at least one platinum group metal and the at least one base metal oxide are impregnated on the same porous refractory oxide material. The diesel oxidation catalyst provides synergistic enhancement of carbon monoxide oxidation as well as relatively unimpaired hydrocarbon oxidation. Methods of making and using the catalyst composition are also provided, as well as emission treatment systems comprising a catalyst article coated with the catalyst composition.

公开(公告)号：US11713705B2

公开(公告)日：2023-08-01

申请号：US17483135

申请日：2021-09-23

申请人： BASF Corporation

发明人： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01J23/10 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/63 ,  B01J33/00 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  F01N3/08 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28 ,  B01D53/94 ,  B01J23/42 ,  B01J35/02

CPC分类号： F01N3/2066 ,  B01D53/9427 ,  B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/63 ,  B01J33/00 ,  B01J35/0006 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/0244 ,  B01J37/0246 ,  B01J37/0248 ,  B01J37/08 ,  B01J37/082 ,  B01J37/088 ,  F01N3/0842 ,  F01N3/101 ,  F01N3/2839 ,  B01D53/945 ,  B01D53/9468 ,  B01D53/9472 ,  B01D2255/1025 ,  B01D2255/2065 ,  B01D2255/9022 ,  B01D2255/9032 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01D2257/402 ,  B01J35/006 ,  B01J35/023 ,  B01J2523/00 ,  Y02C20/10 ,  Y02T10/12 ,  B01J2523/00 ,  B01J2523/36 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/3737 ,  B01J2523/822 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/375 ,  B01J2523/822

摘要： A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US20220010714A1

公开(公告)日：2022-01-13

申请号：US17483135

申请日：2021-09-23

申请人： BASF Corporation

发明人： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： F01N3/20 ,  B01J37/02 ,  B01J35/00 ,  B01J23/10 ,  B01D53/94 ,  B01J35/10 ,  B01J23/46 ,  B01J23/52 ,  B01J23/63 ,  B01J23/42 ,  B01J23/44 ,  B01J33/00 ,  B01J35/04 ,  B01J37/08 ,  F01N3/08 ,  F01N3/10 ,  F01N3/28

摘要： A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US11149610B2

公开(公告)日：2021-10-19

申请号：US16838751

申请日：2020-04-02

申请人： BASF Corporation

发明人： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： B01J23/10 ,  B01J23/46 ,  B01J23/63 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  F01N3/08 ,  F01N3/20 ,  B01D53/94 ,  B01J23/52 ,  B01J23/42 ,  B01J23/44 ,  B01J33/00 ,  F01N3/10 ,  F01N3/28 ,  B01J35/02

摘要： A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US10974198B2

公开(公告)日：2021-04-13

申请号：US16068418

申请日：2017-01-05

申请人： BASF Corporation

发明人： Xinyi Wei ,  Xiaoming Xu ,  Stanley Roth

IPC分类号： B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/12 ,  B01J23/10 ,  B01J23/38 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J23/48 ,  B01J23/50 ,  B01J23/52 ,  B01J23/54 ,  B01J23/56 ,  B01J23/63 ,  B01J23/66 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J37/08 ,  B01J37/10 ,  B01J37/16 ,  F01N3/10 ,  B01D53/86 ,  B01D53/94 ,  B82Y30/00 ,  B82Y40/00

摘要： The present invention relates to diesel oxidation catalyst compositions and catalyst articles, wherein the compositions and articles include a plurality of platinum group nanoparticles substantially in fully reduced form, wherein the nanoparticles have an average particle size of about 1 to about 10 nm and at least about 90% of the nanoparticles have a particle size of +/− about 2 nm of the average particle size. Such compositions can further include a refractory metal oxide material, wherein the nanoparticles and refractory metal oxide material can be combined within the same coating on a substrate or can be applied sequentially on a substrate. The nanoparticles can advantageously be substantially free of halides, alkali metals, alkaline earth metals, sulfur compounds, and boron compounds. Methods of preparing and using such compositions and catalyst articles (e.g., for the treatment of diesel exhaust gas streams) are also provided herein.

公开(公告)号：US20200232366A1

公开(公告)日：2020-07-23

申请号：US16838751

申请日：2020-04-02

申请人： BASF Corporation

发明人： Yuejin Li ,  Xiaolai Zheng ,  Stanley Roth ,  Olga Gerlach ,  Andreas Sundermann

IPC分类号： F01N3/20 ,  B01J37/02 ,  B01J23/63 ,  B01J23/52 ,  B01J23/46 ,  F01N3/28 ,  F01N3/10 ,  F01N3/08 ,  B01J37/08 ,  B01J35/04 ,  B01J33/00 ,  B01J23/44 ,  B01J23/42 ,  B01J35/10 ,  B01D53/94 ,  B01J23/10 ,  B01J35/00

摘要： A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.

公开(公告)号：US09044734B2

公开(公告)日：2015-06-02

申请号：US13624524

申请日：2012-09-21

申请人： BASF SE ,  BASF Corporation

发明人： Gerd Grubert ,  Torsten Neubauer ,  Alfred Punke ,  Marcus Hilgendorff ,  Torsten Müller-Stach ,  Olga Gerlach ,  Xinyi Wei ,  Jeffrey Hoke ,  Shiang Sung ,  Stanley Roth

IPC分类号： B01J23/63 ,  B01D53/94 ,  B01J29/04 ,  B01J37/02 ,  B01J29/70 ,  B01J35/04 ,  B01J35/02 ,  B01J37/00

CPC分类号： B01J29/04 ,  B01D53/944 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/9025 ,  B01D2258/012 ,  B01J23/63 ,  B01J29/7007 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0036 ,  B01J37/0244 ,  B01J37/0246 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3718 ,  B01J2523/48 ,  B01J2523/49 ,  B01J2523/31 ,  B01J2523/824 ,  B01J2523/828

摘要： The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.

摘要翻译： 本发明涉及层状柴油氧化催化剂（DOC），其包括：a）载体基材; b）一种柴油氧化催化材料，其包含：b1）位于所述载体基底上的第一层，所述第一层包含浸渍在载体材料上的钯，所述载体材料包含基于载体材料总重量至少45重量％的二氧化铈 ，并且任选地包含铂; b2）位于所述第一层上的第二层，所述第二层包含钯和铂，各自浸渍在包含金属氧化物的载体材料上; 其中第一层的铂与钯的重量比低于第二层的铂与钯的重量比。

公开(公告)号：US11724248B2

公开(公告)日：2023-08-15

申请号：US17206963

申请日：2021-03-19

申请人： BASF Corporation

发明人： Wen-Mei Xue ,  Xiaofan Yang ,  Haiyang Zhu ,  Stanley Roth ,  Jeff Yang ,  Subramanian Prasad ,  Ahmad Moini

IPC分类号： B01J29/04 ,  B01D53/94 ,  B01J23/42 ,  B01J35/04 ,  G01N21/3563 ,  G01N21/35

CPC分类号： B01J29/044 ,  B01D53/9418 ,  B01D53/9468 ,  B01J23/42 ,  B01J35/04 ,  G01N21/3563 ,  B01D2255/102 ,  B01D2255/20761 ,  B01D2255/9022 ,  B01D2255/9155 ,  G01N2021/3595

摘要： The present disclosure relates to copper-containing molecular sieve catalysts that are highly suitable for the treatment of exhaust containing NOx pollutants. The copper-containing molecular sieve catalysts contain ion-exchanged copper as Cu+2 and Cu(OH)+1, and DRIFT spectroscopy of the catalyst exhibits perturbed T-O-T vibrational peaks corresponding to the Cu+2 and Cu(OH)+1. In spectra taken of the catalytic materials, a ratio of the Cu+2 to the Cu(OH)+1 peak integration areas preferably can be ≥1. The copper-containing molecular sieve catalysts are aging stable such that the peak integration area percentage of the Cu+2 peak (area Cu+2/(area Cu+2+area Cu(OH)+1)) increases by ≤20% upon aging at 800° C. for 16 hours in the presence of 10% H2O/air, compared to the fresh state.

公开(公告)号：US11648534B2

公开(公告)日：2023-05-16

申请号：US16158968

申请日：2018-10-12

申请人： BASF CORPORATION

发明人： Xinyi Wei ,  Olga Gerlach ,  Emily Schulman ,  Andreas Sundermann ,  Stanley Roth ,  Limiao An

IPC分类号： B01J23/42 ,  B01J23/44 ,  B01J21/06 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  F01N3/10 ,  B01D53/94

CPC分类号： B01J23/42 ,  B01J21/066 ,  B01J23/44 ,  B01J35/0026 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1038 ,  F01N3/103 ,  B01D53/945 ,  B01D2255/102 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/20715 ,  B01D2258/018 ,  B01J2523/824 ,  B01J2523/828 ,  Y02T10/12

摘要： The present invention provides an oxidation catalyst composition suitable for at least partial conversion of gaseous hydrocarbon emissions, e.g., methane. The oxidation catalyst composition includes at least one platinum group metal (PGM) component supported onto a porous zirconia-containing material that provides an effect on hydrocarbon conversion activity. The porous zirconia-containing material is at least 90% by weight in the monoclinic phase. Furthermore, the PGM component can comprise at least one platinum group metal in the form of colloidally deposited nanoparticles. The oxidation catalyst composition can be used in the treatment of emissions from lean compressed natural gas engines.