公开(公告)号：US20240084205A1

公开(公告)日：2024-03-14

申请号：US18261948

申请日：2022-01-17

Applicant: CHEVRON U.S.A. INC.

Inventor： Viorel DUMA ,  Theodorus Ludovicus Michael MAESEN ,  Hyungjae Alexander YOON

IPC: C10G47/20 ,  B01J29/76 ,  B01J29/78

CPC classification number: C10G47/20 ,  B01J29/7661 ,  B01J29/7861 ,  B01J2229/16 ,  B01J2229/186 ,  C10G2300/1007 ,  C10G2300/104 ,  C10G2300/1051 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/302 ,  C10G2300/304

Abstract: Described herein is a hydrocracking catalyst and process that may be used to make middle distillates and unconverted oil having beneficial yield and product characteristics. The process generally comprises contacting a hydrocarbon feed with the hydrocracking catalyst under hydrocracking conditions to produce a product comprising middle distillates and unconverted oil products. The hydrocracking catalyst comprises an SSZ-91 molecular sieve and a modifying metal selected from one or more Group 6 metals, and, optionally, one or more Group 8 to 10 metals, or a modifying metal selected from Group 8 to 10 metals and combinations thereof, and, optionally, one or more Group 6 metals. The hydrocracking catalyst may comprise a matrix material and/or an additional zeolite.

公开(公告)号：US20230226533A1

公开(公告)日：2023-07-20

申请号：US18001887

申请日：2021-06-15

Applicant: CHEVRON U.S.A. INC.

Inventor： Jifei JIA ,  Bi-Zeng ZHAN ,  Theodorus Ludovicus Michael MAESEN

IPC: B01J29/80 ,  B01J29/16 ,  B01J29/78 ,  B01J21/12 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  C10G47/20

CPC classification number: B01J29/80 ,  B01J29/166 ,  B01J29/7815 ,  B01J21/12 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/088 ,  C10G47/20 ,  B01J2029/062

Abstract: The process comprises hydrocracking a hydrocarbon feed in a single stage. The catalyst comprises a base impregnated with metals from Group 6 and Groups 8 through 10 of the Periodic Table, as well as citric acid. The base of the catalyst used in the present hydrocracking process comprises alumina, an amorphous silica-alumina (ASA) material, a USY zeolite, and a beta zeolite.

公开(公告)号：US20220033723A1

公开(公告)日：2022-02-03

申请号：US17385782

申请日：2021-07-26

Applicant: Chevron U.S.A. Inc.

Inventor： Varut KOMALARAJUN ,  Theodorus Ludovicus Michael MAESEN

IPC: C10G67/02 ,  B01J23/888 ,  B01D3/14

Abstract: A hydrocracking process for converting a petroleum feed to lower boiling products. The process comprises hydrotreating a petroleum feed in a pre-treating zone in the presence of hydrogen to produce a hydrotreated effluent stream comprising a liquid product. At least a portion of the hydrotreated effluent stream is then passed to an MMS catalyst zone, and then to a hydrocracking zone. In one embodiment, the MMS catalyst zone comprises a self-supported multi-metallic catalyst prepared from a precursor in the oxide or hydroxide form. The percentage work of the hydrotreating in the pre-treating zone is maintained at a level of at least 56%.

公开(公告)号：US20200048566A1

公开(公告)日：2020-02-13

申请号：US16533545

申请日：2019-08-06

Applicant: Chevron U.S.A. Inc.

Inventor： Theodorus Ludovicus Michael MAESEN ,  Derek BLACKWELL ,  Viorel DUMA ,  Varut KOMALARAJUN ,  Alexander E. KUPERMAN ,  Hyunuk RYU ,  Horacio TREVINO ,  Alex YOON ,  Ujjal MUKHERJEE

IPC: C10G47/20 ,  C10G47/34 ,  B01J31/22 ,  B01J31/02

Abstract: A catalyst system has been designed that disrupts the sedimentation process. The catalyst system achieves this by saturating key feed components before the feed components are stripped into their incompatible aromatic cores. The efficacy of this disruptive catalyst system is particularly evident in a hydrocracker configuration that runs in two-stage-recycle operation. The catalyst is a self-supported multi-metallic catalyst prepared from a precursor in the hydroxide form, and the catalyst must be toward the top level of the second stage of the two-stage system.

公开(公告)号：US20240189801A1

公开(公告)日：2024-06-13

申请号：US18344380

申请日：2023-06-29

Applicant: Chevron U.S.A. Inc.

Inventor： Xiaoying OUYANG ,  Viorel DUMA ,  Alexander KUPERMAN ,  Ibrahim UCKUNG ,  Theodorus Ludovicus Michael MAESEN ,  Axel BRAIT ,  Charles WILSON

IPC: B01J23/89 ,  B01J35/31 ,  B01J35/61 ,  B01J35/63 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  C07C5/10 ,  C10G45/00 ,  C10G47/00 ,  C10G49/00

CPC classification number: B01J23/8993 ,  B01J35/31 ,  B01J35/615 ,  B01J35/633 ,  B01J37/0045 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  C07C5/10 ,  C10G45/00 ,  C10G47/00 ,  C10G49/00 ,  C10G2300/1055 ,  C10G2300/1074 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/42 ,  C10G2300/70

Abstract: Bulk catalysts comprised of nickel, molybdenum, tungsten and titanium and methods for synthesizing bulk catalysts are provided. The catalysts are useful for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.

公开(公告)号：US20240101913A1

公开(公告)日：2024-03-28

申请号：US18270202

申请日：2021-12-29

Applicant: CHEVRON U.S.A. INC.

Inventor： Ling JIAO ,  Bi-Zheng ZHAN ,  Don BUSHEE ,  Theodorus Ludovicus Michael MAESEN ,  Hye-Kyung TIMKEN ,  Richard DUTTA ,  Jay PAREKH

IPC: C10G65/12 ,  C10G7/00 ,  C10G47/14

CPC classification number: C10G65/12 ,  C10G7/00 ,  C10G47/14 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/4006 ,  C10G2300/4081

Abstract: Provided is a hydrocracking process with a recycle loop for converting a petroleum feed to lower boiling products, which process comprises reacting a stream over a non-zeolite noble metal catalyst at a temperature of about 650° F. (343° C.) or less in a reactor positioned in the recycle loop of the hydrocracking reactor.

公开(公告)号：US20230191381A1

公开(公告)日：2023-06-22

申请号：US17999535

申请日：2021-05-14

Applicant: Chevron U.S.A. Inc.

Inventor： Bi-Zeng ZHAN ,  Ann Jia-Bao LIANG ,  Theodorus Ludovicus Michael MAESEN

IPC: B01J29/80 ,  B01J21/12 ,  B01J29/16 ,  B01J29/78 ,  B01J23/888 ,  B01J31/02 ,  B01J37/00 ,  B01J37/08 ,  B01J37/02 ,  C10G47/20

CPC classification number: B01J29/80 ,  B01J21/12 ,  B01J29/166 ,  B01J29/7815 ,  B01J29/7869 ,  B01J23/888 ,  B01J31/0202 ,  B01J37/0018 ,  B01J37/08 ,  B01J37/0213 ,  B01J37/0203 ,  B01J37/0236 ,  C10G47/20 ,  B01J2029/062

Abstract: The process comprises hydrocracking a hydrocarbon feed in a single stage. The catalyst comprises a base impregnated with metals from Group 6 and Groups 8 through 10 of the Periodic Table. The base of the catalyst used in the present hydrocracking process comprises alumina, an amorphous silica-alumina (ASA) material, a USY zeolite, optionally a beta zeolite, and zeolite ZSM-12.

公开(公告)号：US20200347309A1

公开(公告)日：2020-11-05

申请号：US16533510

申请日：2019-08-06

Applicant: Chevron U.S.A. Inc.

Inventor： Theodorus Ludovicus Michael MAESEN ,  Derek BLACKWELL ,  Viorel DUMA ,  Varut KOMALARAJUN ,  Alexander E. KUPERMAN ,  Hyunuk RYU ,  Horacio TREVINO ,  Alex YOON ,  Ujjal MUKHERJEE

IPC: C10G65/12 ,  C10G67/02 ,  B01J31/04 ,  B01J37/20

Abstract: A catalyst system has been designed that disrupts the sedimentation process. The catalyst system achieves this by saturating key feed components before the feed components are stripped into their incompatible aromatic cores. The efficacy of this disruptive catalyst system is particularly evident in a hydrocracker configuration that runs in two-stage-recycle operation. The catalyst is a self-supported multi-metallic catalyst prepared from a precursor in the hydroxide form, and the catalyst must be toward the top level of the second stage of the two-stage system.

公开(公告)号：US20160089665A1

公开(公告)日：2016-03-31

申请号：US14862341

申请日：2015-09-23

Applicant: CHEVRON U.S.A. INC.

Inventor： Yihua ZHANG ,  Kamala Raghunathan KRISHNA ,  Guan-Dao LEI ,  Theodorus Ludovicus Michael MAESEN

IPC: B01J29/74 ,  C10M101/02 ,  C10G45/64 ,  B01J35/10 ,  B01J35/00

CPC classification number: B01J29/74 ,  B01J21/04 ,  B01J29/7461 ,  B01J29/7492 ,  B01J35/00 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/1085 ,  C10G45/60 ,  C10G45/64 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/302 ,  C10G2300/304 ,  C10M101/02

Abstract: The present invention is directed to an improved finished hydroisomerization catalyst manufactured from a first high nanopore volume (HNPV) alumina having a broad pore size distribution (BPSD), and a second HNPV alumina having narrow pore size distribution (NPSD). Their combination yields a HNPV base extrudate having a low particle density as compared to a conventional base extrudates.

Abstract translation: 本发明涉及由具有宽孔径分布（BPSD）的第一高纳米孔体积（HNPV）氧化铝和具有窄孔径分布（NPSD）的第二HNPV氧化铝制成的改进的成品加氢异构化催化剂。 与传统的基础挤出物相比，它们的组合产生具有低颗粒密度的HNPV基础挤出物。

公开(公告)号：US20160089663A1

公开(公告)日：2016-03-31

申请号：US14862302

申请日：2015-09-23

Applicant: CHEVRON U.S.A. INC.

Inventor： Yihua ZHANG ,  Kamala Raghunathan KRISHNA ,  Guan-Dao LEI ,  Theodorus Ludovicus Michael MAESEN

IPC: B01J29/74 ,  C10G45/64 ,  C10M101/02 ,  B01J35/10

CPC classification number: B01J29/74 ,  B01J21/04 ,  B01J29/7461 ,  B01J29/7492 ,  B01J35/00 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J2229/20 ,  C10G45/64 ,  C10M101/02

Abstract: The present invention is directed to an improved finished hydroisomerization catalyst manufactured from a first high nanopore volume (HNPV) alumina having a broad pore size distribution (BPSD), and a second HNPV alumina having narrow pore size distribution (NPSD). Their combination yields a HNPV base extrudate having larger porosity with a bimodal pore size distribution as compared to a conventional base extrudates.

Abstract translation: 本发明涉及由具有宽孔径分布（BPSD）的第一高纳米孔体积（HNPV）氧化铝和具有窄孔径分布（NPSD）的第二HNPV氧化铝制成的改进的成品加氢异构化催化剂。 与常规的基础挤出物相比，它们的组合产生具有更大孔隙率的HNPV基础挤出物，具有双峰孔径分布。