Abstract:
Advanced epoxy resins comprising the reaction product of an epoxy resin comprising a diglycidyl ether of Formula 1 as defined herein, and at least on difunctional compound selected from an aromatic diol and a dicarboxylic acid are described. The diglycidyl ether contains a cycloaliphatic ring of 3-5 carbon atoms. Purified diglycidyl ether is used to obtain substantially linear, high molecular weight, advanced epoxy resin. Curable compositions, cured compositions, and articles comprising the advanced epoxy resins are also disclosed. The advanced epoxy resins provide cured coatings having improved flexibility and low total chlorine content.
Abstract:
The present invention relates to an article comprising metal coated with an aqueous dispersion of polyolefin particles as well as metal coated with a polyolefin film arising from this dispersion. More particularly the polyolefin particles of the present invention are predominantly polypropylene particles.
Abstract:
A curable coating composition is provided having multi-functionalized acrylic copolymer and amino-functional silicone resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.
Abstract:
The instant invention provides a coated container device, and method of making the same. The coated container device according to the instant invention comprises: (1) a metal substrate; and (2) one or more crosslinked coating layers associated with the metal substrate, wherein the one or more crosslinked coating layers are derived from the application of one or more aqueous dispersions to at least one surface of the metal substrate, and wherein the one or more aqueous dispersion comprise: (a) one or more a base polymer; (b) one or more a stabilizing agent; (c) optionally one or more neutralizing agents, (d) one or more crosslinking agents; and (e) water.
Abstract:
A coating system comprising an epoxy coating layer prepared from an epoxy formulation which comprises an epoxy resin; a curing agent with no more than 4.5 wt % free amine based on a weight solids of the curing agent; and an adjacent layer prepared from a non-isocyanate polyurethane formulation wherein the epoxy formulation and/or non-isocyanate polyurethane formulation optionally further comprise one or more additives selected from the group consisting of solvent, reactive diluent, plasticizer, pigment, filler; rheology modifiers, dispersants, surfactants, UV stabilizers, and corrosion inhibitors is provided. Also provided are a method of applying a multi-layer coating system and an article comprising a coating system.
Abstract:
The instant invention is an aqueous based blend composition and method of producing the same. The aqueous based blend composition according to the present invention comprises: (a) an aqueous polyolefin dispersion comprising the melt blending product of one or more base polymers and one or more stabilizing agents in the presence of water and optionally one or more neutralizing agents, wherein the polyolefin dispersion has an average volume particle size diameter in the range of from 400 to 1500 nm, and a pH range from 8 to 11; and (b) one or more crosslinking agents selected from the group consisting of phenol-formaldehyde resins, hydroxyalkylamide resins, amino-formaldehyde resins; epoxy group containing resins, and combinations thereof, wherein said crosslinking agents comprise form 0.1 to 50 percent by weight based on the solid content of the dispersion; wherein said aqueous based blend composition has a solid content in the range of from 15 to 70 percent by weight of solids, based on the weight of the aqueous based blend composition, wherein said solid content of said blend composition comprises up to 99.9 percent by weight of the one or more base polymers, based on the weight of the solid content of the aqueous based blend composition, based on the weight of the solid content of the aqueous based blend composition, and a pH in the range of from 8 to 11.
Abstract:
A waterborne dispersion containing a high molecular weight cycloaliphatic epoxy resin based on a diglycidyl ether of a cycloaliphatic diol polymerized with, for example, a diphenolic or diacid compound.
Abstract:
An epoxy resin adduct comprising the reaction product of an epoxy resin comprising a diglycidyl ether of Formula 1 as defined herein, and at least one reactive compound having two or more active hydrogen atoms per molecule, wherein the active hydrogen atoms are reactive with epoxide groups are described. The diglycidyl ether contains a cycloaliphatic ring of 3-5 carbon atoms. Curable compositions, methods of curing, cured compositions, and articles comprising the epoxy resin adducts are also disclosed. The epoxy resin adduct has improved cure behavior and provides cured compositions having increased glass transition temperature, good weatherability, and a low total chlorine content.
Abstract:
The present invention relates to a composition comprising an aqueous dispersion of a thermosettable compound and polymer particles functionalized with aminoalkyl ester groups. The composition is useful as a two-component waterborne curing system and is effective in providing corrosion and blister resistance in industrial coatings applications.
Abstract:
The present invention relates to an article and a method for its preparation; the article comprises a cured polymeric film superposing paper or paperboard. The polymeric film is derived from a dispersion which comprises: a) a dispersant which is a copolymer with an acid value of 130 or less, comprising structural units of ethylene and a carboxylic acid monomer, wherein the copolymer has a melt flow index in the range of from 50 to 2000 g/10 min at 190° C./2.16 kg; wherein the weight-to-weight ratio of structural units of ethylene to carboxylic acid monomer is in the range of from 95:5 to 70:30; and wherein the dispersant has a concentration in the range of from 9 to 50 weight percent based on the weight of polymer solids in the dispersion; b) a base polymer comprising non-functionalized ethylene-co-alkene copolymers, wherein the weight-to-weight ratio of the structural units of ethylene to alkene is in the range of from 99.8:0.2 to 50:50; and c) a neutralizing agent which is a hard base and excludes an organic base having a boiling point of less than 250° C.; wherein the concentration of the neutralizing agent is sufficient to neutralize at least half of the carboxylic acid groups associated with the dispersion composition. The article of the present invention is useful as a barrier to a wide range of hydrophobic and hydrophilic materials.