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11.发明申请公开(公告)号：US20070155618A1
公开(公告)日：2007-07-05
申请号：US11715949
申请日：2007-03-09
IPC分类号： B01J31/00
CPC分类号： C10G45/10 , B01J21/12 , B01J23/85 , B01J23/88 , B01J23/882 , B01J27/1802 , B01J31/0254 , B01J37/0203 , B01J37/20 , B01J2231/645 , C10G45/08
摘要： A hydrotreating catalyst that contains at least one element of group VIB and/or group VIII of the periodic table and optionally phosphorus and/or silicon, with an organic compound as an additive that contains at least one nitrogen atom, is used for the transformation of hydrocarbon-containing fractions, in particular the hydrodesulfurization, the hydrodenitrification, the hydrodemetallization, the hydrogenation of various petroleum fractions, such as residues, vacuum distillates, gas oils and gasolines, and the hydroconversion of vacuum distillates.
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12.发明授权Process for synthesizing C5+ hydrocarbons in the presence of a catalyst prepared using at least one cyclic oligosaccharide 有权在使用至少一种环状低聚糖制备的催化剂存在下合成C5 +烃的方法公开(公告)号：US08618182B2
公开(公告)日：2013-12-31
申请号：US13812701
申请日：2011-06-24
IPC分类号： C07C27/00
CPC分类号： C07C1/0445 , B01J21/005 , B01J21/04 , B01J21/12 , B01J23/005 , B01J23/75 , B01J23/8913 , B01J31/065 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/0226 , B01J37/12 , B01J2231/641 , B01J2231/648 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/10 , C07C2523/74 , C07C2523/75 , C07C2531/02 , C10G2/331 , C10G2/332 , C10G2/333 , C07C9/14
摘要： C5+ hydrocarbon synthesis by contracting a synthesis gas with a catalyst naming at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process of at least: i) contracting at least the support with at least one solution containing at least one precursor of metal from group VIII; ii) contracting at least the support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) at least one calcining to obtain at least the metal from group VIII in the oxide form; i) and ii) being carried out separately, in any order, or simultaneously.
摘要翻译： C5 +烃合成通过用催化剂收缩合成气，催化剂命名至少一种沉积在由至少一种氧化物形成的载体上的VIII族金属，所述催化剂使用以下方法制备，所述方法至少包括：i）至少在载体上收缩载体 含有至少一种来自VIII族金属的前体的至少一种溶液; ii）至少由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状低聚糖形成的有机化合物至少包含载体; iii）至少一种煅烧以至少获得氧化物形式的VIII族金属; i）和ii）以任何顺序或同时单独进行。
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公开(公告)号：US08071655B2
公开(公告)日：2011-12-06
申请号：US11721923
申请日：2005-11-17
CPC分类号： B01J21/12 , B01J23/005 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/405 , B01J29/7049 , B01J29/7088 , B01J29/7092 , B01J29/90 , B01J37/08 , C10G2/332 , Y10S502/524
摘要： A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM′(1−x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.
摘要翻译： 一种适用于合成气转化尤其是ET淤浆法的催化剂，所述催化剂包括：a）至少含有式M x M'（1-x）Al 2 O 4 / Al 2 O 3 -SiO 2的混合尖晶石结构的第一铝酸盐元素的载体， 并且不包括0和1，或者简单的尖晶石结构式为MA1204 / Al2O3.SiO2，所述载体在至少部分氧化的气氛中在850℃和900℃之间的温度下煅烧，和b） 活性相沉积在所述载体上，其含有一种或多种选自钴，镍，钌或铁的第VIII族金属。 所述催化剂用于固定床或悬浮在三相反应器中，用于从CO，H 2混合物合成碳氢化合物。
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公开(公告)号：US20100029792A1
公开(公告)日：2010-02-04
申请号：US11721923
申请日：2005-11-17
CPC分类号： B01J21/12 , B01J23/005 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/405 , B01J29/7049 , B01J29/7088 , B01J29/7092 , B01J29/90 , B01J37/08 , C10G2/332 , Y10S502/524
摘要： The invention relates to a catalyst which can be applied to a method for converting synthesis gas, said catalyst comprising: a) a support made of a solid solution containing at least one first aluminate element with a mixed spinel structure of formula MxM′(1-X)AI2O4/AI203.SiO2, x ranging from 0 to 1 being excluded, or a simple spinel structure of formula MAI2O4/AI2O3 SiO2, wherein the support is calcinated in an at least partially oxidizing atmosphere at a temperature ranging from 850° C. to 900° C., b) an active phase which is deposited on the support which contains one or several metals of group VIII, selected from amongst cobalt, nickel, ruthenium or iron. The catalyst is used in a fixed bed or in a suspension in a triphasic reactor for the synthesis of hydrocarbons from a CO, H2 mixture.
摘要翻译： 本发明涉及可用于转化合成气的方法的催化剂，所述催化剂包括：a）由含有至少一种第一铝酸盐元素与具有式MxM'（1- X）Al 2 O 4 / Al 2 O 3·Si 2 O 2，排除0至1的x，或式MAI 2 O 4 / Al 2 O 3 SiO 2的简单尖晶石结构，其中载体在至少部分氧化气氛中在850℃的温度下煅烧。 至900℃，b）沉积在载体上的活性相，其含有一种或几种选自钴，镍，钌或铁的VIII族金属。 该催化剂用于固定床或三相反应器中用于从CO，H 2混合物合成烃的悬浮液中。
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15.发明申请Use Of A Catalyst Comprising A Beta Silicon Carbide Support In A Selective Hydrodesulphurization Process 审中-公开在选择性加氢脱硫工艺中使用包含β碳化硅载体的催化剂公开(公告)号：US20080179220A1
公开(公告)日：2008-07-31
申请号：US12045359
申请日：2008-03-10
申请人： Christophe Bouchy , Fabrice Diehl
发明人： Christophe Bouchy , Fabrice Diehl
IPC分类号： C10G45/04
CPC分类号： C10G45/10 , B01J23/24 , B01J23/74 , B01J23/85 , B01J23/882 , B01J27/224 , B01J37/0203 , B01J37/0205 , B01J37/20 , C10G45/06 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2400/02
摘要： The invention concerns the use of supported catalysts comprising at least one metal or metallic compound of a metal from group VI and/or group VIII deposited on a support essentially constituted by β silicon carbide in a process for selective hydrodesulphurization of an olefinic hydrocarbon feed that is substantially free of polynuclear aromatics and metals.The invention can be used to carry out deep desulphurization of catalytically cracked gasoline cuts with very limited saturation of olefins and thus a minimum loss of octane number.
摘要翻译： 本发明涉及使用负载型催化剂，该催化剂包括至少一种金属或金属化合物，该金属或金属化合物沉积在基本上由β碳化硅构成的载体上的第VI族和/或第VIII族金属在选择性加氢脱硫烯烃原料的方法中使用， 基本上不含多环芳烃和金属。 本发明可用于以非常有限的烯烃饱和度进行催化裂化汽油馏分的深度脱硫，因此最小的辛烷值损失。
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16.发明申请Proess for desulfurization, denitrating and/or dearomatization of a hydrocarbon feedstock by adsorption on a spent solid adsorbent 审中-公开通过在废固体吸附剂上的吸附来预测烃原料的脱硫，脱硝和/或脱芳构化公开(公告)号：US20050075528A1
公开(公告)日：2005-04-07
申请号：US10793751
申请日：2004-03-08
CPC分类号： B01J20/08 , B01J20/103 , B01J20/18 , B01J20/20 , B01J20/3416 , B01J20/3433 , B01J20/3458 , B01J20/3475 , B01J2220/60 , C10G25/003 , C10G25/12
摘要： A process for purification by adsorption of a hydrocarbon feedstock that uses a novel adsorption agent is described. This adsorption agent is a spent solid adsorbent that has been used in a first application of catalytic treatment of hydrocarbon feedstocks, or of adsorption, and whose adsorption or catalytic performance levels are degraded such that its use for the first application has become impossible. The use of this spent solid adsorbent for the purification of hydrocarbon feedstocks by adsorption does not require specific treatment in advance, in particular not heat treatment.
摘要翻译： 描述了通过吸附使用新型吸附剂的烃原料进行纯化的方法。 该吸附剂是一种废固体吸附剂，已被用于烃原料或吸附的催化处理的第一次应用，其吸附或催化性能水平降低，使得其在第一次使用中的用途已变得不可能。 使用这种废固体吸附剂通过吸附来纯化烃原料不需要预先特别的处理，特别是不进行热处理。
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17.发明申请Use of a catalyst comprising a beta silicon carbide support in a selective hydrodesulphurization process 审中-公开在选择性加氢脱硫过程中使用含有β碳化硅载体的催化剂公开(公告)号：US20050056568A1
公开(公告)日：2005-03-17
申请号：US10921301
申请日：2004-08-19
申请人： Christophe Bouchy , Fabrice Diehl
发明人： Christophe Bouchy , Fabrice Diehl
IPC分类号： B01J23/24 , B01J23/74 , B01J23/85 , B01J23/882 , B01J27/224 , B01J32/00 , B01J35/10 , B01J37/02 , B01J37/20 , C10G45/06 , C10G45/08 , C10G45/10 , C10G45/04
CPC分类号： C10G45/10 , B01J23/24 , B01J23/74 , B01J23/85 , B01J23/882 , B01J27/224 , B01J37/0203 , B01J37/0205 , B01J37/20 , C10G45/06 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2400/02
摘要： The invention concerns the use of supported catalysts comprising at least one metal or metallic compound of a metal from group VI and/or group VIII deposited on a support essentially constituted by β silicon carbide in a process for selective hydrodesulphurization of an olefinic hydrocarbon feed that is substantially free of polynuclear aromatics and metals. The invention can be used to carry out deep desulphurization of catalytically cracked gasoline cuts with very limited saturation of olefins and thus a minimum loss of octane number.
摘要翻译： 本发明涉及使用负载型催化剂，该催化剂包括至少一种金属或金属化合物，该金属或金属化合物沉积在基本上由β碳化硅构成的载体上的第VI族和/或第VIII族金属在选择性加氢脱硫烯烃原料的方法中使用， 基本上不含多环芳烃和金属。 本发明可用于以非常有限的烯烃饱和度进行催化裂化汽油馏分的深度脱硫，因此最小的辛烷值损失。
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18.发明申请PROCESS FOR HYDROCRACKING A HYDROCARBON FEED IN THE PRESENCE OF A SULPHIDE CATALYST PREPARED USING A CYCLIC OLIGOSACCHARIDE 审中-公开在使用环状低聚物制备的硫化物催化剂存在下加氢烃的方法公开(公告)号：US20130140215A1
公开(公告)日：2013-06-06
申请号：US13812716
申请日：2011-06-24
申请人： Fabrice Diehl , Audrey Bonduelle
发明人： Fabrice Diehl , Audrey Bonduelle
IPC分类号： B01J29/14 , B01J23/883 , C10G47/02
CPC分类号： B01J29/146 , B01J21/12 , B01J23/883 , B01J35/1019 , B01J35/1042 , B01J37/0201 , B01J37/0203 , B01J37/20 , B01J37/22 , B01J37/28 , C10G47/02 , C10G47/20 , C10G2300/1011 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2300/703 , Y02P30/20
摘要： Hydrocracking a hydrocarbon feed in the presence of a catalyst comprising an acidic support and an active phase formed from at least one metal from group VIII and at least one metal from group VIB, said catalyst being prepared using a process comprising, in succession: contacting a pre-catalyst comprising said metal from group VIII, said metal from group VIB and said acidic support with a cyclic oligosaccharide of at least 6α-(1,4)-bonded glucopyranose subunits; contacting the acidic support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide of at least 6α-(1,4)-bonded glucopyranose subunits; and contacting acidic support with a cyclic oligosaccharide of at least 6α-(1,4)-bonded glucopyranose subunits followed by a second contacting acidic solid with a precursor of metal from group VIII and a precursor of metal from group VIB; drying; heat treatment; sulphurization.
摘要翻译： 在包含酸性载体和由至少一种来自第VIII族的金属和至少一种VIB的金属形成的活性相的催化剂的存在下加氢裂解烃进料，所述催化剂使用以下方法制备，所述方法包括： 包含来自VIII族的所述金属的预催化剂，来自VIB族的所述金属和所述酸性载体与至少6α-（1,4） - 键合的吡喃葡萄糖亚基的环状寡糖; 使酸性载体与含有第VIII族金属的前体的溶液和VIB族的所述金属的前体和至少6α-（1,4）键的吡喃葡萄糖亚基的环状低聚糖接触; 并使酸性载体与至少6α-（1,4） - 键合的吡喃葡萄糖亚基的环状寡糖接触，然后将酸性固体与第VIII族金属前体和VIB族金属前体接触; 烘干; 热处理; 硫化。
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19.发明授权Hydrotreating catalyst that contains a nitrogen-containing organic compound and its use 有权含有有机化合物的加氢处理催化剂及其用途公开(公告)号：US07235173B2
公开(公告)日：2007-06-26
申请号：US10612288
申请日：2003-07-03
CPC分类号： C10G45/10 , B01J21/12 , B01J23/85 , B01J23/88 , B01J23/882 , B01J27/1802 , B01J31/0254 , B01J37/0203 , B01J37/20 , B01J2231/645 , C10G45/08
摘要： A hydrotreating catalyst that contains at least one element of group VIB and/or group VIII of the periodic table and optionally phosphorus and/or silicon, with an organic compound as an additive that contains at least one nitrogen atom, is used for the transformation of hydrocarbon-containing fractions, in particular the hydrodesulfurization, the hydrodenitrification, the hydrodemetallization, the hydrogenation of various petroleum fractions, such as residues, vacuum distillates, gas oils and gasolines, and the hydroconversion of vacuum distillates.
摘要翻译： 含有至少一种元素周期表VIB族元素和/或第Ⅷ族元素以及任选的磷和/或硅的加氢处理催化剂与含有至少一个氮原子的添加剂的有机化合物用于转化 特别是加氢脱硫，加氢脱氮，加氢脱金属，各种石油馏分（例如残渣，真空馏分，瓦斯油和汽油）的氢化和真空馏分的加氢转化。
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20.发明授权公开(公告)号：US07198712B2
公开(公告)日：2007-04-03
申请号：US10462809
申请日：2003-06-17
CPC分类号： C10G21/12 , C10G29/205
摘要： For desulfurization and, if necessary, for denitrification of hydrocarbon fractions the hydrocarbon mixture is brought into contact with a non-aqueous ionic liquid of general formula Q+A−, wherein Q+ is a ammonium, phosphonium or sulfonium cation, that contains at least one alkylating agent of the formula RX−, making it possible to form ionic sulfur-containing derivatives (and, if necessary, nitrogen-containing derivatives) that have a preferred solubility in the ionic liquid; and the ionic liquid is separated from the hydrocarbon mixture that is low in sulfur and nitrogen by decanting.
摘要翻译： 对于脱硫，如果需要，使烃馏分脱氮，使烃混合物与通式为Q +的非水离子液体接触，其中Q 含有至少一种式RX的烷基化剂的铵，鏻或锍阳离子，使得可以形成离子含硫衍生物（和， 如果需要，含氮衍生物）在离子液体中具有优选的溶解度; 离子液体通过倾析从硫和氮低的烃混合物中分离出来。
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