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    Process for preparing organosilicon compounds containing (meth)acryloxy groups
    13.
    发明授权
    Process for preparing organosilicon compounds containing (meth)acryloxy groups 失效
    制备含有（甲基）丙烯酰氧基的有机硅化合物的方法

    公开(公告)号：US5869726A

    公开(公告)日：1999-02-09

    申请号：US931723

    申请日：1997-09-16

    申请人： Jochen Dauth ,  Bernward Deubzer ,  Petra Gratzl ,  Josef Wolferseder

    发明人： Jochen Dauth ,  Bernward Deubzer ,  Petra Gratzl ,  Josef Wolferseder

    IPC分类号： C08G77/12 ,  C08G77/20 ,  C08G77/38 ,  C09D183/06 ,  C09D183/07 ,  C07F7/08

    CPC分类号： C09D183/06 ,  C08G77/38

    摘要： A novel process for preparing organosilicon compounds containing (meth)acxyloxy groups is described, in which alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) of the formula ##STR1## where R.sup.2 is a hydrogen atom or a methyl radical,R.sup.3 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical andR.sub.4 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical, andz is an integer from 1 to 12,are reacted with organosilicon compounds (2) comprising units of the formula ##STR2## where R is an identical or different monovalent, optionally halogenated hydrocarbon radical having from 1 to 18 carbon atoms per radical, ande is 0 or 1, on average from 0.01 to 1.0,f is 0, 1, 2 or 3, on average from 0.0 to 3.0, andhaving at least one Si-bonded hydrogen atom per molecule in the presence of catalysts (3) which promote the addition Si-bonded hydrogen onto aliphatic multiple bonds and also in the presence of polymerization inhibitors (4), where alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) are used in amounts of from 1.01 to 1.5 mole per gram atom of Si-bonded hydrogen in organosilicon compound (2).

    摘要翻译： 描述了制备含有（甲基）丙氧基的有机硅化合物的新方法，其中式（II）的烷氧基​​化烷基-2-炔基1,4-二（甲基）丙烯酸酯（1）其中R2是氢 原子或甲基，R3是每个基团具有1至6个碳原子的直链或支链亚烷基，R4是每个基团具有1至6个碳原子的直链或支链亚烷基，z是1至 12与包含式（III）的单元的有机硅化合物（2）反应，其中R是相对或不同的每个基团具有1至18个碳原子的单价，任选卤代烃基，e是0或1 平均为0.01〜1.0，f为0,1,2或3，平均为0.0〜3.0，在催化剂（3）的存在下，每分子具有至少一个Si键合的氢原子，促进Si的添加 键合的氢键到脂族多重键上，并且在聚合抑制剂的存在下（4）， 其中烷氧基化的烷基-2-炔1,4-二（甲基）丙烯酸酯（1）的用量为有机硅化合物（2）中每克原子的Si键合氢的1.01至1.5摩尔。

    Soluble organopolysiloxane free-radical macroinitators for graft copolymerization
    14.
    发明授权
    Soluble organopolysiloxane free-radical macroinitators for graft copolymerization 失效
    用于接枝共聚的可溶性有机聚硅氧烷自由基大分子

    公开(公告)号：US5605983A

    公开(公告)日：1997-02-25

    申请号：US360102

    申请日：1994-12-20

    申请人： Jochen Dauth ,  Catherine Oleggini ,  Bernward Deubzer

    发明人： Jochen Dauth ,  Catherine Oleggini ,  Bernward Deubzer

    IPC分类号： C08F4/00 ,  C08F283/12 ,  C08G77/48 ,  C08G77/392 ,  C08G77/388

    CPC分类号： C08G77/48 ,  C08F283/12

    摘要： The invention relates to partially crosslinked organopolysiloxanes which contain a radical forming group, a base-catalyzed process for their preparation, graft copolymers produced from these organopolysiloxanes and a process for the preparation of the graft copolymers. The present invention avoids problems related to known methods wherein a considerable portion of the organopolymer chains do not graft to the organopolysiloxane graft back-bone but remain as an unattached homopolymers.

    摘要翻译： 本发明涉及含有自由基形成基团的部分交联的有机聚硅氧烷，其制备的碱催化方法，由这些有机聚硅氧烷制备的接枝共聚物和制备接枝共聚物的方法。 本发明避免了与已知方法相关的问题，其中相当大一部分的有机聚合物链不接枝到有机聚硅氧烷移植物背骨上，而是保留为未附着的均聚物。

    Amino silicone oil emulsions crosslinked by reactions similar to a Michael addition
    15.
    发明授权
    Amino silicone oil emulsions crosslinked by reactions similar to a Michael addition 失效
    通过与迈克尔加成相似的反应交联的氨基硅油乳液

    公开(公告)号：US06177511B1

    公开(公告)日：2001-01-23

    申请号：US09236809

    申请日：1999-01-25

    申请人： Jochen Dauth ,  Bernward Deubzer ,  Robert Schröck ,  Petra Gratzl

    发明人： Jochen Dauth ,  Bernward Deubzer ,  Robert Schröck ,  Petra Gratzl

    IPC分类号： C08G7720

    CPC分类号： C08G77/54 ,  C08F283/12 ,  C08L83/08 ,  C08L2666/34

    摘要： Novel organopolysiloxane compositions comprising (A) organopolysiloxanes which contain at least one SiC-bonded organic radical containing basic nitrogen, where the basic nitrogen is optionally present in part as a salt of a water-soluble organic acid, water-soluble inorganic acid, or water-insoluble organic acid, (B) anionic, cationic, nonionic or amphoteric surfactants, which are in soluble or soluble in (A) (C) substituted or unsubstituted diacrylates and/or oligoacrylates, and optionally, (C′) substituted or unsubstituted acrylates, and (D) water are described.

    摘要翻译： 新型有机聚硅氧烷组合物，其包含（A）含有至少一个含有碱性氮的SiC键合的有机基团的有机聚硅氧烷，其中碱性氮部分作为水溶性有机酸，水溶性无机酸或水的盐部分地部分存在 （A）（C）取代或未取代的二丙烯酸酯和/或低聚丙烯酸酯，和任选的（C'）取代或未取代的丙烯酸酯（C）的可溶性或可溶性的阴离子，阳离子，非离子或两性表面活性剂 ，（D）水。

    Organosilicon compounds having fluorescent groups, their preparation and use
    16.
    发明授权
    Organosilicon compounds having fluorescent groups, their preparation and use 失效
    具有荧光基团的有机硅化合物，其制备和用途

    公开(公告)号：US6160149A

    公开(公告)日：2000-12-12

    申请号：US150888

    申请日：1998-09-10

    申请人： Jochen Dauth ,  Bernward Deubzer ,  Josef Wolferseder

    发明人： Jochen Dauth ,  Bernward Deubzer ,  Josef Wolferseder

    IPC分类号： G01N21/91 ,  C07F7/08 ,  C07F7/10 ,  C07F7/18 ,  C08F299/08 ,  C08G77/20 ,  C08G77/38 ,  C08G77/388 ,  C08G77/392 ,  C08J3/24 ,  C08L83/07 ,  C09B69/10 ,  C09D5/00 ,  C09D5/22 ,  C09D183/07 ,  C09D183/08 ,  C09K11/00 ,  C09K11/06

    CPC分类号： C08G77/388 ,  C08G77/392 ,  C09D183/08

    摘要： The invention describes novel organosilicon compounds having fluorescent groups, containing units of the formula ##EQU1## where R is an identical or different, a monovalent, optionally substituted hydrocarbon radical having from 1 to 18 carbon atom(s) per radical, which may be interrupted by one or more oxygen atom(s),X is identical or different, and is a chlorine atom or a radical of the formula OR.sup.1,whereR.sup.1 is a hydrogen atom, or an alkyl radical having from 1 to 8 carbon atom(s) per radical which may be substituted by an ether oxygen atom,E is an organic radical having one or more (meth)acrylate groups,A is a radical of the formula--R.sup.2 [--NR.sup.3 --L].sub.x or --R.sup.2 [--S--L].sub.x(II),whereR.sup.2 is a divalent or trivalent, optionally substituted hydrocarbon radical having from 2 to 50 carbon atoms per radical, which is substituted by one or more groups of the formulae ##STR1## x is 1 or 2, R.sup.3 is as defined for R.sup.1 or is a radical of the formula --C(.dbd.O)--R.sup.1, andL is a fluorescent, organic radical,a is 0, 1 or 2, b is 0, 1, 2 or 3, c is 0, 1, 2 or 3, d is 0, 1 or 2 and the sum a+b+c+d.ltoreq.4,with the proviso that at least one radical A is present per molecule.

    摘要翻译： 本发明描述了具有荧光基团的新型有机硅化合物，其含有下式的单元，其中R是相同或不同的，每个基团具有1至18个碳原子的单价任选取代的烃基，其可被一个或多个 更多的氧原子，X是相同或不同的，并且是氯原子或式OR1的基团，其中R1是氢原子或每个基团具有1至8个碳原子的烷基，其中 可以被醚氧原子取代，E是具有一个或多个（甲基）丙烯酸酯基团的有机基团，A是式-R 2 [-NR 3 -L] x或-R 2 [-SL] x（II ），其中R 2是每个基团具有2至50个碳原子的二价或三价任选取代的烃基，其被一个或多个式x所代表的基团取代为1或2，R 3如对R 1所定义或是 式-C（= O）-R1的基团，L是荧光的有机基团，a是0,1或2，b是0,1或2， 2或3，c是0,1,2或3，d是0,1或2，并且和a + b + c + d 4，条件是每个分子存在至少一个基团A.

    Organosilicon compounds containing oligoisobutylene or polyisobutylene groups
    17.
    发明授权
    Organosilicon compounds containing oligoisobutylene or polyisobutylene groups 失效
    含有低聚异丁烯或聚异丁烯基团的有机硅化合物

    公开(公告)号：US6040383A

    公开(公告)日：2000-03-21

    申请号：US52508

    申请日：1998-03-31

    申请人： Jochen Dauth ,  Thomas Hierstetter ,  Bernward Deubzer ,  Petra Gratzl

    发明人： Jochen Dauth ,  Thomas Hierstetter ,  Bernward Deubzer ,  Petra Gratzl

    IPC分类号： C08G81/02 ,  C07F7/18 ,  C08F8/42 ,  C08F10/10 ,  C08G77/382 ,  C08G77/388 ,  C08G77/442 ,  C08G77/46 ,  C09D183/10 ,  C09G1/16 ,  C08F8/00 ,  C08L43/00

    CPC分类号： C09G1/16 ,  C08G77/382 ,  C08G77/388 ,  C08G77/442 ,  C08G77/46

    摘要： The invention describes novel organosilicon compounds containing oligoisobutylene or polyisobutylene groups and comprising at least one unit of the formulaA.sub.a R.sub.b SiX.sub.c O.sub.4-(a+b+c)/2, (I)where R are identical or different and are each a monovalent, divalent or trivalent unsubstituted or substituted hydrocarbon radical, X are identical or different and are each a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 is a hydrogen atom or an alkyl radical which may be substituted by an ether oxygen atom, or a radical of the formula--R.sup.2 ([OCH(CH.sub.3)CH.sub.2 ].sub.e [OCH.sub.2 CH.sub.2 ].sub.f [O(CH.sub.2).sub.4 ].sub.g OR.sup.3).sub.y (II)where R.sup.2 is a divalent or trivalent, unsubstituted or substituted hydrocarbon radical which is substituted by one or more groups of the formulae--(C.dbd.O)--O--, --(C.dbd.O)--NR.sup.3 --, --NR.sup.3 --, --O--, --S--,R.sup.3 is a hydrogen atom or R.sup.1 or a radical of the formula--(C.dbd.O)--R.sup.1,e, f and g are each an integer of 0-200, with the proviso that the sum e+f+g.gtoreq.1 and y is 1 or 2,a is 0, 1 or 2,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the sum a+b+c.ltoreq.4, andA is a radical which contains an oligoisobutylene or polyisobutylene group, with the proviso that at least one radical of the formula A is present per molecule.

    摘要翻译： 本发明描述了含有低聚异丁烯或聚异丁烯基团的新型有机硅化合物，并且包含至少一个式A a R b Si X c O 4 - （a + b + c）/ 2，（I）的单元，其中R相同或不同，并且各自是一价，二价或三价未取代的 或取代的烃基，X相同或不同，并且各自为氯原子或式-OR1的基团，其中R 1为氢原子或可被醚氧原子取代的烷基，或 其中R 2是被一个或多个基团取代的二价或三价，未取代或取代的烃基，其中R 2是（C 1 -C 4 式（C = O）-O - ， - （C = O）-NR 3 - ， - NR 3 - ， - O-，-S-，R 3是氢原子或R 1或式 - （ C = O）-R1，e，f和g各自为0-200的整数，条件是和e + f + g> / = 1和y为1或2，a为0,1或2 ，b为0,1,2或3，c为0,1,2或3，并且和a + b + c为4， 并且A是含有低聚异丁烯或聚异丁烯基团的基团，条件是每个分子存在至少一个式A的基团。

    Ionic organosilicon compounds and their preparation and use
    18.
    发明授权
    Ionic organosilicon compounds and their preparation and use 失效
    离子有机硅化合物及其制备与应用

    公开(公告)号：US5990334A

    公开(公告)日：1999-11-23

    申请号：US987727

    申请日：1997-12-09

    申请人： Thomas Hierstetter ,  Jochen Dauth ,  Birgit Peschanel ,  Bernward Deubzer

    发明人： Thomas Hierstetter ,  Jochen Dauth ,  Birgit Peschanel ,  Bernward Deubzer

    IPC分类号： C07F7/10 ,  C07F7/08 ,  C08G77/38 ,  C08G77/388 ,  C08G77/392 ,  C08G77/395

    CPC分类号： C07F7/0854 ,  C07F7/0856 ,  C08G77/388 ,  C08G77/392 ,  C08G77/395

    摘要： Ionic organosilicon compounds comprising siloxane units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),in whichR is an identical or different, optionally halogenated hydrocarbon radicals having 1 to 12 carbon atoms or radicals of the formulae--R'--((NHCH.sub.2 CH.sub.2).sub.o --(N.sup.+ H.sub.2 CH.sub.2 CH.sub.2).sub.p --N.sup.(x+q-2)+ H.sub.x R".sub.q).sub.d-1 (II)--R'--(SH).sub.d-1 (III)or--R'--(Z--C (O)--CR'"=CH.sub.2).sub.d-1 (IV)in whichR', R", Z, R'", o, p, q, x, d, X and A have the meaning given in claim 1 anda is 0 or 1,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3and the sum a+b+c is.ltoreq.4,with the proviso that at least one radical A is contained in each molecule, and, optionally, non-bonding counter-ions from the group consisting of alkali metal, alkaline earth metal and ammonium ions of organic amines are present to compensate the negative charges and non-bonded counter-ions from the group consisting of organic anions, such as, for example, acetate ions, are present to compensate the positive charges,their preparation and their use.

    摘要翻译： 包含式AaRbXcSiO（4-abc）/ 2（I）的硅氧烷单元的离子有机硅化合物，其中R是具有1至12个碳原子的相同或不同的任选卤代烃基或式-R' - （ （NHCH2CH2）o-（N + H2CH2CH2）pN（x + q-2）+ HxR''q）d-1（II）-R' - （SH）d-1（III）或-R' - （ZC （O）-CR“'= CH 2）d-1（IV）其中R'，R”，Z，R“'，o，p，q，x，d，X和A具有给定的含义 在权利要求1中，a为0或1，b为0,1,2或3，c为0,1,2或3，并且a + b + c为+4，条件是至少一个 自由基A包含在每个分子中，并且可选地，存在来自有机胺的碱金属，碱土金属和铵离子的非结合反离子以补偿负电荷和非结合的抗衡离子 存在由有机阴离子例如乙酸根离子组成的组，以补偿正电荷及其制备及其用途。

    Crosslinkable compositions
    20.
    发明授权
    Crosslinkable compositions 失效
    可交联组合物

    公开(公告)号：US5703190A

    公开(公告)日：1997-12-30

    申请号：US697359

    申请日：1996-08-23

    申请人： Jochen Dauth ,  Christian Herzig ,  Bernward Deubzer ,  Klaus Schnitzer ,  David Huettner

    发明人： Jochen Dauth ,  Christian Herzig ,  Bernward Deubzer ,  Klaus Schnitzer ,  David Huettner

    IPC分类号： C08G77/20 ,  C08G77/22 ,  C08K5/01 ,  C08K5/05 ,  C08L83/04 ,  C08L83/05 ,  C08L83/07 ,  C09D183/04 ,  C09D183/07 ,  C08G77/06

    CPC分类号： C08L83/04 ,  C08K5/01 ,  C08K5/05 ,  C09D183/04 ,  C08G77/045 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80

    摘要： The present invention relates to crosslinkable compositions are described, containing (1) organosilicon compounds which have radicals containing aliphatic carbon-carbon multiple bonds, and (2) organosilicon compounds having Si-bonded hydrogen atoms, or (3) organosilicon compounds where radicals with aliphatic carbon-carbon multiple bonds and Si-bonded hydrogen atoms are present in the same compound, (4) catalysts which promote the addition of Si-bonded hydrogen onto aliphatic multiple bond, and (5) agents which retard the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature, of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are a hydrogen atom or a monovalent, substituted or unsubstituted hydrocarbon radical having 1 to 12 carbon atoms per radical,R.sup.3 is a divalent hydrocarbon radical having 1 to 6 carbon atoms per radical, X is a radical of the formula --OH, --Cl, Br and --CN, and x and y are identical or different and are 0 or 1, with the proviso that there is at least one double bond.

    摘要翻译： 本发明涉及可交联组合物，其含有（1）具有含有脂族碳 - 碳多键的基团的有机硅化合物，和（2）具有硅键合氢原子的有机硅化合物，或（3）有机硅化合物， 碳 - 碳多键和硅键合的氢原子存在于同一化合物中，（4）促进在脂肪族多键上加入Si键的氢的催化剂，和（5）阻止加入Si键的氢 在其中R 1，R 2，R 4，R 5和R 6相同或不同且为氢原子或具有1至12个碳原子的单价，取代或未取代的烃基的式（I） 每个基团的碳原子，R 3是每个基团具有1至6个碳原子的二价烃基，X是式-OH，-Cl，Br和-CN的基团，x和y相同或不同， 0或1，条件是存在至少一个双键。