公开(公告)号：US20080156694A1

公开(公告)日：2008-07-03

申请号：US11963231

申请日：2007-12-21

Applicant: Thierry Chapus ,  Karin Marchand

Inventor： Thierry Chapus ,  Karin Marchand

IPC: C10G69/00

CPC classification number: C10G65/12 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G3/54 ,  C10G45/02 ,  C10G45/08 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/04 ,  Y02P30/20

Abstract: The invention relates to a process for the treatment of heavy petroleum feedstocks in order to produce a gas oil fraction having a sulphur content of less than 50 ppm and generally 10 ppm which comprises the following stages: a) mild hydrocracking in a catalyst fixed bed, b) separation of the hydrogen sulphide, of a distillate cut including a gas oil fraction and of a fraction which is heavier than the gas oil, c) hydrotreating, by contact with at least one catalyst, of at least a portion of the said distillate cut obtained in stage b) including the gas oil fraction, as a mixture with a feedstock resulting from a crude or refined renewable source, d) separation of a gas oil cut comprising less than 50 ppm of sulphur. Advantageously, the heavy fraction is sent for catalytic cracking. Preferably, the process is carried out with makeup hydrogen introduced in stage c) and very advantageously all the makeup hydrogen for the process is introduced in stage c).The invention also relates to a plant which can be used for implementing this process.

Abstract translation: 本发明涉及一种处理重质石油原料的方法，以生产硫含量小于50ppm，通常为10ppm的瓦斯油馏分，其包括以下阶段：a）催化剂固定床中的轻度加氢裂化， b）分离硫化氢，馏分馏分，其包括粗柴油馏分和比粗柴油重的馏分，c）通过与至少一种催化剂接触加氢处理所述馏出物的至少一部分 在包括粗油或精制可再生来源的原料的混合物中包含粗柴油馏分的步骤b）中得到的切割，d）分离包含小于50ppm硫的瓦斯油馏分。 有利地，将重馏分送入催化裂化。 优选地，通过在阶段c）中引入的补充氢来进行该方法，并且非常有利地，用于该方法的所有补充氢在阶段c）中引入。 本发明还涉及可用于实施该方法的设备。

公开(公告)号：US20080020926A1

公开(公告)日：2008-01-24

申请号：US11878308

申请日：2007-07-23

Applicant: Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

Inventor： Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

IPC: B01J23/28

CPC classification number: B01J23/882 ,  B01J21/04 ,  B01J23/002 ,  B01J23/883 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/08 ,  B01J37/12 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G45/12 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847

Abstract: A process is described for preparing a solution formed by at least one cobalt and/or nickel salt of at least one heteropolyanion combining molybdenum and cobalt or molybdenum and nickel in its structure, said process comprising: a) mixing at least one source of molybdenum and at least one oxidizing compound in aqueous solution to synthesize peroxomolybdate ions at an acidic pH, the (oxidizing compound/molybdenum source) mole ratio being in the range 0.1 to 20; b) introducing at least one cobalt precursor and/or at least one nickel precursor into the solution from step a) to form a solution comprising at least said salt in which the (Co+Ni)/Mo mole ratio is in the range 0.25 to 0.85.

Abstract translation: 描述了一种制备由至少一种结合钼和钴或钼和镍的杂多阴离子的至少一种钴和/或镍盐形成的溶液的方法，所述方法包括：a）将至少一种钼源和 至少一种氧化性化合物在水溶液中，在酸性pH下合成过氧钼酸根离子，（氧化化合物/钼源）的摩尔比在0.1至20的范围内; b）将至少一种钴前体和/或至少一种镍前体引入到步骤a）的溶液中以形成至少包含所述盐的溶液，其中（Co + Ni）/ Mo摩尔比在0.25至 0.85。

公开(公告)号：US20100133147A1

公开(公告)日：2010-06-03

申请号：US12375757

申请日：2007-07-06

Applicant: Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

Inventor： Alexandra Chaumonnot ,  Denis Guillaume ,  Benoit Fremon ,  Karin Marchand ,  Renaud Revel

IPC: C10G45/00 ,  B01J31/12 ,  B01J31/02

CPC classification number: B01J31/0269 ,  B01J21/12 ,  B01J23/20 ,  B01J23/24 ,  B01J23/40 ,  B01J23/74 ,  B01J23/882 ,  B01J31/0274 ,  B01J37/20 ,  C10G49/02

Abstract: A supported and sulphur-containing catalyst is described, comprising; a porous support constituted by an organic-inorganic hybrid material for which the covalent bond between the organic and inorganic phases conforms to the formula M-O—Z—R where M represents at least one metal constituting the inorganic phase, Z at least one heteroelement from among phosphorus and silicon and R an organic fragment, at least one metal of group VIB and/or of group VB and/or of group VIII. The invention also relates to the use of this catalyst for the hydrorefining and the hydroconversion of hydrocarbon-containing feedstocks such as petroleum fractions, fractions from coal or biomass or hydrocarbons produced from natural gas.

Abstract translation: 描述了负载型和含硫催化剂，其包含： 由有机和无机相之间的共价键符合式MO-Z-R的有机 - 无机杂化材料构成的多孔载体，其中M表示构成无机相的至少一种金属，Z至少一种来自 磷和硅，R是有机片段，至少一种VIB族金属和/或VB族和/或VIII族金属。 本发明还涉及该催化剂用于加氢精制和加氢转化含烃原料如石油馏分，来自煤或生物质的馏分或天然气生产的烃。

公开(公告)号：US20100111825A1

公开(公告)日：2010-05-06

申请号：US12612004

申请日：2009-11-04

Applicant: Thierry Becue ,  Karin Marchand ,  Arnold Lambert ,  Etienne Lebas

Inventor： Thierry Becue ,  Karin Marchand ,  Arnold Lambert ,  Etienne Lebas

IPC: C01B3/26

CPC classification number: F23C10/005 ,  B01J8/10 ,  B01J19/28 ,  B01J21/066 ,  B01J23/002 ,  B01J23/83 ,  B01J2523/00 ,  C01B3/02 ,  F23C2900/99008 ,  F23J2215/50 ,  H01M8/0612 ,  H01M8/0668 ,  Y02E20/346 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/847

Abstract: A redox mass for chemical looping combustion processes includes a redox pair or set of pairs having a material able to be alternatively oxidized and reduced between CuO and Cu, between Cu2O and Cu, between NiO and Ni, between MnO2 and Mn2O3, between Mn2O3 and Mn3O4, between Mn3O4 and MnO, between MnO and Mn, between CO3O4 and CoO or between CoO and Co, and a binder containing at least one mixed cerine-zirconia oxide (Ce/Zr) of the general formula CexZr1-xO2, where 0.05≦x≦0.95.

Abstract translation: 用于化学循环燃烧过程的氧化还原物质包括在MnO 2和Mn 2 O 3之间，Mn 2 O 3和Mn 3 O 4之间具有能够在CuO和Cu之间，NiO和Ni之间，NiO和Ni之间，MnO 2和Mn 2 O 3之间在CuO和Cu之间交替氧化和还原的材料的氧化还原对或成对 MnO和Mn之间，CO 3 O 4与CoO之间或CoO和Co之间的粘合剂，以及含有至少一种通式CexZr1-xO2的混合铈 - 氧化锆（Ce / Zr）的粘合剂，其中0.05＆lt; x＆nlE; 0.95。

公开(公告)号：US07687430B2

公开(公告)日：2010-03-30

申请号：US11878308

申请日：2007-07-23

Applicant: Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

Inventor： Denis Guillaume ,  Edmond Payen ,  Carole Lamonier ,  Karin Marchand

IPC: B01J23/00

CPC classification number: B01J23/882 ,  B01J21/04 ,  B01J23/002 ,  B01J23/883 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0213 ,  B01J37/08 ,  B01J37/12 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G45/12 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847

Abstract: A process is described for preparing a solution formed by at least one cobalt and/or nickel salt of at least one heteropolyanion combining molybdenum and cobalt or molybdenum and nickel in its structure, said process comprising: a) mixing at least one source of molybdenum and at least one oxidizing compound in aqueous solution to synthesize peroxomolybdate ions at an acidic pH, the (oxidizing compound/molybdenum source) mole ratio being in the range 0.1 to 20; b) introducing at least one cobalt precursor and/or at least one nickel precursor into the solution from step a) to form a solution comprising at least said salt in which the (Co+Ni)/Mo mole ratio is in the range 0.25 to 0.85.

Abstract translation: 描述了一种制备由至少一种结合钼和钴或钼和镍的杂多阴离子的至少一种钴和/或镍盐形成的溶液的方法，所述方法包括：a）将至少一种钼源和 至少一种氧化性化合物在水溶液中，在酸性pH下合成过氧钼酸根离子，（氧化化合物/钼源）的摩尔比在0.1至20的范围内; b）将至少一种钴前体和/或至少一种镍前体引入到步骤a）的溶液中以形成至少包含所述盐的溶液，其中（Co + Ni）/ Mo摩尔比在0.25至 0.85。

公开(公告)号：US20070049489A1

公开(公告)日：2007-03-01

申请号：US11491038

申请日：2006-07-24

Applicant: Thierry Becue ,  Karin Marchand ,  Arnold Lambert ,  Etienne Lebas

Inventor： Thierry Becue ,  Karin Marchand ,  Arnold Lambert ,  Etienne Lebas

IPC: B01J23/10

CPC classification number: F23C10/005 ,  B01J8/10 ,  B01J19/28 ,  B01J21/066 ,  B01J23/002 ,  B01J23/83 ,  B01J2523/00 ,  C01B3/02 ,  F23C2900/99008 ,  F23J2215/50 ,  H01M8/0612 ,  H01M8/0668 ,  Y02E20/346 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/847

Abstract: The present invention relates to a new type of redox mass that can be used in any chemical looping combustion process, said mass comprising a binder containing at least cerine-zirconia.

Abstract translation: 本发明涉及可用于任何化学循环燃烧过程的新型氧化还原物质，所述物质包含至少含有铈氧化锆的粘合剂。

公开(公告)号：US09321973B2

公开(公告)日：2016-04-26

申请号：US13996762

申请日：2011-12-15

Applicant: Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

Inventor： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC: C10G47/00 ,  B01J27/186 ,  B01J27/19 ,  C10G47/12 ,  B01J29/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/10 ,  C10G65/12 ,  C10G3/00 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J37/20

CPC classification number: C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

Abstract: A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

Abstract translation: 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。

公开(公告)号：US20140183100A1

公开(公告)日：2014-07-03

申请号：US13995800

申请日：2011-12-15

Applicant: Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

Inventor： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC: C10G45/10 ,  C10G45/04

CPC classification number: C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

Abstract: The invention relates to a process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus (P), silicon (Si), boron (B), nickel (Ni) and cobalt (Co), the said element being taken alone, M is one or more element(s) selected from molybdenum (Mo), tungsten (W), nickel (Ni) and cobalt (Co), O is oxygen, H is hydrogen, h is an integer within the range 0 to 12, x is an integer within the range 0 to 4, m is an integer equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18, y is an integer within the range 17 to 72 and q is an integer within the range 1 to 20, the said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.

Abstract translation: 本发明涉及至少一种汽油馏分的加氢脱硫方法，其实施催化剂，其以其氧化物形式包含至少一种来自元素周期表的VIB族金属和/或至少一种来自元素周期第Ⅷ族的金属，其形式为 的至少一种式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷（P），硅（Si），硼（B），镍（Ni）和钴（Co）的元素，所述元素为 单独使用时，M是选自钼（Mo），钨（W），镍（Ni）和钴（Co）中的一种或多种元素，O为氧，H为氢，h为0 至12，x为0至4范围内的整数，m为等于5,6,7,8,9,10,11,12和18的整数，y为17至72的整数，q为 是1至20范围内的整数，所述多金属氧酸盐存在于孔径在1.5至50nm范围内且具有厚度的无定形壁的介孔结构氧化硅基质中 s在1至30nm的范围内，所述催化剂在被实施在所述方法之前被硫化。

公开(公告)号：US20130334099A1

公开(公告)日：2013-12-19

申请号：US13996762

申请日：2011-12-15

Applicant: Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

Inventor： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC: C10G47/12

CPC classification number: C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

Abstract: A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

Abstract translation: 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。

公开(公告)号：US20130186806A1

公开(公告)日：2013-07-25

申请号：US13813016

申请日：2011-06-24

Applicant: Fabrice Diehl ,  Elodie Devers ,  Karin Marchand ,  Bertrand Guichard

Inventor： Fabrice Diehl ,  Elodie Devers ,  Karin Marchand ,  Bertrand Guichard

IPC: B01J27/19 ,  C10G45/10 ,  C10G45/08

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/652 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/94 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/086 ,  B01J37/20 ,  B01J38/14 ,  C10G45/08 ,  C10G45/10 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/04

Abstract: Preparation of a catalyst having at least one metal from group VIII, at least one metal from group VIB and at least one support; in succession: i) one of i1) contacting a pre-catalyst with metal from group VIII, metal from group VIB and support with a cyclic oligosaccharide naming at least 6 α-(1,4)-bonded glucopyranose subunits; i2) contacting support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; or i3) contacting support with a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits followed by contacting solid derived therefrom with a precursor of metal from group VIII and a precursor of metal from group VIB.

Abstract translation: 制备具有至少一种来自第VIII族的金属的催化剂，至少一种来自VIB族的金属和至少一种载体; i）i）使预催化剂与VIII族金属，VIB族金属接触，并与至少6个α-（1,4）键的吡喃葡萄糖亚基命名的环状低聚糖进行支持; i2）使载体与含有VIII族金属的前体的溶液接触，所述VIB族的所述金属的前体和由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状寡糖; 或i3）使支持物与由至少6个α-（1,4） - 键合的吡喃葡萄糖亚基组成的环状寡糖接触，然后将从其衍生的固体与来自VIII族的金属前体和来自VIB族的金属前体接触。