摘要:
The present invention relates to a multi-layer oriented shrink film comprising at least one skin layer comprising a polystyrene material and at least one core layer comprising a polyolefin layer. The films are preferably primarily oriented in either the machine or the cross direction. These films are ideally suited for use as a shrink label which can be applied either as a CD shrink sleeve or applied using a continuous roll process. The films ideally have an overall density of less than 1.0 g/cm3, to facilitate recycling efforts.
摘要翻译:本发明涉及一种多层定向收缩膜,其包含至少一层包含聚苯乙烯材料的表皮层和至少一层包含聚烯烃层的芯层。 膜优选主要在机器或横向方向上定向。 这些膜理想地适合用作收缩标签,其可以作为CD收缩套筒使用,或者使用连续辊式方法施加。 这些膜理想地具有小于1.0g / cm 3的总密度,以便于再循环。
摘要:
The present invention includes a blend composition comprising at least one coupled propylene polymer and at least 55 weight percent of at least one ethylene polymer, based on the total weight of the coupled propylene polymer and the ethylene polymer. The invention also includes methods for making the coupled propylene polymer and methods for making the blend composition. The present invention further includes films made from the blend composition.
摘要:
Films with excellent machine direction (MD) tear properties comprise at least one layer made from a polymer comprising: (A) at least 50 weight percent (wt %) propylene; and (B) at least 5 wt % ethylene and/or one or more unsaturated comonomers. Representative of component (B) unsatuarated comonomers are the C4-20 α-olefins, C4-20 dienes, styrenic compounds, and the like. Preferably, the film has at least one of a (i) haze value of less than about 10, (ii) 45 degree gloss of greater than about 65, and (iii) dart value of greater than about 100 g/mil. In one preferred embodiment, the layer comprises a compolymer characterized as having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
摘要翻译:具有良好机器方向(MD)撕裂性能的膜包括由聚合物制成的至少一层,包括:(A)至少50重量%(wt%)丙烯; 和(B)至少5重量%的乙烯和/或一种或多种不饱和共聚单体。 组分(B)不饱和共聚单体的代表是C 4-14-20α-烯烃,C 4-20二烯烃,苯乙烯类化合物等。 优选地,膜具有小于约10的(i)雾度值,(ii)大于约65的45度光泽度和(iii)大于约100g / mil的飞镖值中的至少一种。 在一个优选的实施方案中,该层包含特征在于具有以下特性中的至少一个的共聚物:(i)对应于在约14.6和约15.7ppm的区域误差的13 C NMR峰, 大约相同强度的峰,(ii)当共聚单体含量(即衍生自共聚物的乙烯和/或不饱和共聚单体的单元)的B值至少为约3重量%时,B值大于约1.4, (iii)偏度指数S≈大于约-1.20,(iv)具有保持基本相同的T曲线和T max SUB>,和(v)报告更多的X射线衍射图 比使用齐格勒 - 纳塔(ZN)催化剂制备的可比共聚物更好。
摘要:
The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.
摘要:
The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a compostion and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.
摘要:
A sheet, film, fiber, foam or latex prepared from a blend of polymeric materials comprising a plurality of substantially random interpolymers comprising vinyl aromatic and ethylene and/or alpha olefin monomers and wherein: a) the amount of polymer units derived from said vinyl aromatic monomer in any interpolymer component differs from that amount in another interpolymer component by at least 0.5 mole percent; b) the amount of polymer units derived from said vinyl aromatic monomer in the blend is greater than about 19 mole percent; and wherein c) the observed stress relaxation of the resulting blend is greater than the additive stress relaxation of the of the individual blend components.
摘要:
Polymer mixtures are disclosed which comprise at least one homogeneously branched ethylene polymer (A) and at least one ethylene polymer (B) having a crystallinity which is at least 7% greater than the crystallinity of polymer (A) with certain provisos. A process for making a molded article using the disclosed polymer mixtures is disclosed as well as films, film layers, coatings and molded articles formed from those mixtures. These mixtures have several advantages over polymer compositions of the prior art, including improved properties at elevated temperatures such as improved softening point under load, improved hardness, improved toughness, improved 100% modulus of elasticity, improved compression set, improved ability to prevent oil bleed out at lower temperatures when the mixture contains oil and reduced injection molding cycle time. The mixtures retain their performance advantages even when substantial amounts of additives such as oil and filler are incorporated into the mixture. The mixtures may also be crosslinked after they are formed into the shape of an article to form vulcanized elastomeric products. The polymer mixtures have utility in a variety of applications.
摘要:
Super high flow ethylene polymer compositions comprising at least one linear ethylene polymer are disclosed which have improved processability for use in making thermally formed articles (e.g., thin-walled lids, cups and containers). The compositions have a processing index from about 0.005 KPoise to about 1 KPoise and are particularly useful in thermal forming processes having shear rates of at least 2,000 sec.sup.-1 (e.g., injection molding processes). The compositions can be used to make thin-walled lids and cups and have good environmental stress crack resistance and Gullwing Tear properties.
摘要:
A process for the preparation of blends including an ethylene copolymer by copolymerizing ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex.
摘要:
Blend compositions containing a novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength are disclosed. The homopolymers are important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibres, and cable and wire coatings and jacketings and, various forms of pipe.