摘要:
The invention relates to a tire with a tread. The tread is composed of at least two defined elastomers having Tg's spaced apart by at least 55° C. to the exclusion of elastomers having Tg's between −30° and −85° C. The tread composition can be reinforced with either carbon black or a combination of carbon black and silica reinforcing fillers.
摘要:
High viscosity elastomers are often difficult to utilize in rubber compositions without first creating a pre-blend of the high viscosity elastomer and a rubber processing oil to reduce their overall viscosity. This invention relates to utilization of a specialized pre-blend of high viscosity and low viscosity elastomers for use in rubber compositions and to the resulting rubber composition. The use of such resulting rubber composition may be for component(s) of tires, particularly including tire treads. The specialized pre-blend of high and low viscosity elastomers is required to be created by blending individual latices or, alternatively, by blending individual polymerizates of elastomers with diverse viscosities.
摘要:
This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend. Asymmetrical tin coupling in general also leads to better processability and other beneficial properties. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) from about 20 phr to about 60 phr of tin-coupled polybutadiene rubber, (2) from about 20 phr to about 60 phr of a rubber selected from the group consisting of natural rubber and synthetic polyisoprene and (3) from about 5 phr to about 40 phr of high vinyl polybutadiene rubber.
摘要:
The present invention relates to a rubber composition reinforced with a combination of silica and defined carbon black and to pneumatic tires having treads comprised of such rubber composition. The reinforced rubber composition comprises in one aspect, at least one elastomer, defined carbon black, precipitated silica and at least one silica coupling agent.
摘要:
The subject invention discloses a pneumatic tire having an outer circumferential tread wherein said tread is a sulfur-cured rubber composition comprised of (a) an isoprene-butadiene diblock rubber, said isoprene-butadiene diblock rubber being comprised of a butadiene block and an isoprene-butadiene block, wherein said butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene diblock rubber has essentially one glass transition temperature which is within the range of about -100.degree. C. to about -70.degree. C., wherein said isoprene-butadiene diblock polymer has a Mooney ML-4 viscosity at 100.degree. C. which is within the range of about 50 to about 140, wherein the repeat units derived from isoprene and 1,3-butadiene in the isoprene-butadiene block are in essentially random order, and wherein said isoprene-butadiene diblock polymer does not contain any blocks which are derived solely from isoprene; and (b) a second rubber selected from the group consisting of high vinyl polybutadiene rubber, styrene-isoprene-butadiene rubber, solution styrene-butadiene rubber and emulsion styrene-butadiene rubber.
摘要:
The invention relates to a tire of a structural combination of tire tread and sidewall components with compositional limitations containing minimal, if any, of in situ formed alcohol and methyl isobutyl ketone byproducts. The tread component rubber composition contains pre-hydrophobated silica reinforcement. The sidewall component contains low unsaturation EPDM or brominated copolymer of isobutylene and p-methylstyrene and may contain pre-hydrophobated silica reinforcement. The silica reinforcement for said tread and sidewall components is a pre-hydrophobated precipitated silica. The pre-hydrophobated silica is prepared, prior to mixing with the elastomer(s), by reacting hydroxyl groups (e.g. silanol groups) contained on the surface of a precipitated silica with an alkoxyorganomercaptosilane or a combination of an alkoxyorganomercaptosilane and a substituted alkylsilane or with a bis-3(trialkoxysilylalkyl) polysulfide which contains an average of from 2 to 4 connecting sulfur atoms in its polysulfidic bridge to form a composite thereof. The alcohol byproduct therefrom is removed from the composite prior to its introduction into the rubber composition(s). In another aspect of the invention, the connecting sidewall rubber composition, and optionally the tread composition is free of N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine antidegradant (referred herein to as 6PPD) in order to prevent in situ formation of methyl isobutyl ketone byproduct from the reaction of 6PPD with atmospheric oxygen and/or ozone.
摘要:
This invention discloses a pneumatic tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; wherein the tread is comprised of (a) about 60 phr to about 90 phr of a cis-1,4-polybutadiene rubber, wherein the cis-1,4-polybutadiene rubber has a glass transition temperature which is within the range of about −104° C. to about −80° C., (b) about 10 phr to about 40 phr of at least one additional rubbery polymer selected from the group consisting of polyisoprene rubber, polybutadiene rubber, isoprene-butadiene rubber, and styrene-isoprene-butadiene rubber, wherein the additional rubbery polymer has a glass transition temperature which is within the range of about −30° C. to about −10° C., and (c) about 20 phr to about 60 phr of carbon black, wherein the carbon black has a dibutylphthalate absorption value of at least 140 cm3/100 grams and wherein the carbon black has a cetyl trimethyl ammonium bromide adsorption area which is within the range of about 60 to about 90.
摘要:
The present invention relates to a tire with a carbon black-containing, black-colored, circumferential tread of a cap/base construction, wherein said tread cap has a lug and groove configuration and wherein the outer surface of a major portion of said grooves are designed to be ground contacting, and a co-extruded thin outer non-carbon black-containing rubber layer of a non-black color wherein said outer rubber layer is integral with and circumferentially extends from the axial outer edge of said tread cap to include at least of a visible surface of at least one groove in said tread cap. In one aspect, said tread contains a pair of black colored, carbon black reinforced, tread miniwings which extend from the axial outer edge of the tread over a portion of the tire sidewall, wherein said thin outer rubber layer joins said miniwing and wherein said tread cap, tread base, tread miniwings and thin outer layer are co-extruded, co-cured and therefore integral with each other.
摘要:
This invention relates to a tire having a tread of a cap/base construction wherein the tread cap is composed of trans 1,4-polybutadiene, solution polymerization prepared styrene/butadiene copolymer rubber, cis 1,4-polyisoprene rubber and defined amounts of carbon black and amorphous silica reinforcement.
摘要:
The present invention relates to a tire having a rubber tread of a lug and groove configuration and which may be of a co-extruded cap/base construction; wherein at least a part of the visible portion of the tread is exclusive of carbon black and thereby of a color other than black. Such non-black colored rubber includes the outer surface of at least one of said tread lugs intended to be ground-contacting. In one aspect of the invention, said non-black colored rubber composition contains (A) a precipitated silica reinforcement which has been pre-treated with a hydrophobation agent and optionally also pre-treated with a coupling agent or (B) a precipitated silica which has been pre-treated with a hydrophobating agent and a coupling agent which does not from an alcohol byproduct upon reacting with hydroxyl groups (e.g. silanol groups) contained on the surface of said precipitated silica. In another aspect of the invention, said non-black colored rubber composition is comprised of at least one diene based elastomer and a brominated poly(isobutylene-co-para-methylstyrene) where a coupling agent for said silica is an organo phosphite.