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11.发明授权Production of glutaric acid and derivatives from carbohydrate-containing materials 有权生产戊二酸和含碳水化合物材料的衍生物公开(公告)号：US09174911B2
公开(公告)日：2015-11-03
申请号：US14291600
申请日：2014-05-30
Applicant: Rennovia, Inc.
Inventor： Thomas R. Boussie , Eric L. Dias , Zachary M. Fresco , Vincent J. Murphy
IPC: C07C51/23 , C07C51/31 , C07C29/149 , C07C51/377 , C07C209/00 , C07C253/00 , C08G63/16 , C08G69/14 , C08G69/26 , C08G69/36
CPC classification number: C07C51/313 , C07C29/149 , C07C51/377 , C07C209/00 , C07C253/00 , C08G63/16 , C08G69/14 , C08G69/26 , C08G69/36 , C07C55/12 , C07C211/12 , C07C255/04 , C07C31/20
Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a pentose source to a glutaric acid product. The present invention includes processes for the conversion of pentose to a glutaric acid product via pentaric acid or derivatives thereof. The present invention also includes processes comprising the catalytic oxidation of pentose to pentaric acid and catalytic hydrodeoxygenation of pentaric acid or derivatives thereof to a glutaric acid product.
Abstract translation: 本发明一般涉及将戊糖源化学转化成戊二酸产物的方法。 本发明包括通过戊酸或其衍生物将戊糖转化成戊二酸产物的方法。 本发明还包括将戊糖催化氧化成戊酸并将戊酸或其衍生物催化加氢脱氧至戊二酸产物的方法。
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12.发明申请Production of Glutaric Acid and Derivatives from Carbohydrate-Containing Materials 有权从含碳水化合物的材料生产戊二酸和衍生物公开(公告)号：US20140350297A1
公开(公告)日：2014-11-27
申请号：US14291600
申请日：2014-05-30
Applicant: Rennovia, Inc.
Inventor： Thomas R. Boussie , Eric L. Dias , Zachary M. Fresco , Vincent J. Murphy
IPC: C07C51/31
CPC classification number: C07C51/313 , C07C29/149 , C07C51/377 , C07C209/00 , C07C253/00 , C08G63/16 , C08G69/14 , C08G69/26 , C08G69/36 , C07C55/12 , C07C211/12 , C07C255/04 , C07C31/20
Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a pentose source to a glutaric acid product. The present invention includes processes for the conversion of pentose to a glutaric acid product via pentaric acid or derivatives thereof. The present invention also includes processes comprising the catalytic oxidation of pentose to pentaric acid and catalytic hydrodeoxygenation of pentaric acid or derivatives thereof to a glutaric acid product.
Abstract translation: 本发明一般涉及将戊糖源化学转化成戊二酸产物的方法。 本发明包括通过戊酸或其衍生物将戊糖转化成戊二酸产物的方法。 本发明还包括将戊糖催化氧化成戊酸并将戊酸或其衍生物催化加氢脱氧至戊二酸产物的方法。
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13.发明申请Production of Adipic Acid and Derivatives from Carbohydrate-Containing Materials 有权由含碳水化合物材料生产己二酸和衍生物公开(公告)号：US20140256982A1
公开(公告)日：2014-09-11
申请号：US14153248
申请日：2014-01-13
Applicant: Rennovia, Inc.
Inventor： Thomas R. Boussie , Eric L. Dias , Zachary M. Fresco , Vincent J. Murphy , James Shoemaker , Raymond Archer , Hong Jiang
IPC: C07C51/31 , C07C51/377
CPC classification number: C07C51/377 , B01J21/063 , B01J21/066 , B01J21/08 , B01J21/16 , B01J21/18 , B01J23/40 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/468 , B01J23/52 , B01J23/6525 , B01J23/6562 , B01J23/6567 , B01J23/8906 , B01J23/8913 , B01J23/8926 , B01J35/006 , B01J37/0205 , C07B2200/07 , C07C51/235 , C07C51/31 , C07C51/412 , C07C201/08 , C07C209/00 , C07C253/00 , C07D201/08 , C07D223/10 , C07D309/30 , C08G63/16 , C08G69/14 , C08G69/26 , C08G69/36 , Y02P20/582 , C07C55/14 , C07C211/12 , C07C255/04
Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.
Abstract translation: 本发明一般涉及将葡萄糖源化学转化为己二酸产物的方法。 本发明包括通过葡糖二酸或其衍生物将葡萄糖转化成己二酸产物的方法。 本发明还包括将葡萄糖催化氧化成葡糖二酸或其衍生物的方法和包括将葡糖二酸或其衍生物催化加氢脱氧至己二酸产物的方法。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。
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公开(公告)号：US20180086688A1
公开(公告)日：2018-03-29
申请号：US15722454
申请日：2017-10-02
Applicant: Rennovia Inc.
Inventor： Gary M. Diamond , Eric L. Dias , Raymond Archer , Vincent J. Murphy , Thomas R. Boussie
CPC classification number: C07C51/47 , B01D15/1821 , B01D15/363 , C07C51/16 , C07C51/23 , C07C51/27
Abstract: Processes for separating a di-carboxylic acid or salt thereof from a mixture containing the di-carboxylic acid or salt thereof and one or more other components are provided. Also separation media useful for these separation processes is provided. In particular, processes for preparing an aldaric acid are described, such as glucaric acid from glucose, which includes separating the aldaric acid from the reaction product. Also, various glucaric acid products are described.
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15.发明授权Production of adipic acid and derivatives from carbohydrate-containing materials 有权从含碳水化合物的材料生产己二酸和衍生物公开(公告)号：US08927768B2
公开(公告)日：2015-01-06
申请号：US13932413
申请日：2013-07-01
Applicant: Rennovia, Inc.
Inventor： Thomas R. Boussie , Eric L. Dias , Zachary M. Fresco , Vincent J. Murphy
IPC: C07C55/00 , C07C51/36 , C07C51/377 , C07C29/149 , C07C209/00 , C07C253/00 , C08G63/16 , C08G69/14 , C08G69/26
CPC classification number: C07C51/377 , C07C29/149 , C07C209/00 , C07C253/00 , C08G63/16 , C08G69/14 , C08G69/26 , C07C55/14 , C07C211/12 , C07C255/04 , C07C31/20
Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a carbohydrate source to an adipic acid product. The present invention includes processes for the conversion of a carbohydrate source to an adipic acid product via a furanic substrate, such as 2,5-furandicarboxylic acid or derivatives thereof. The present invention also includes processes for producing an adipic acid product comprising the catalytic hydrogenation of a furanic substrate to produce a tetrahydrofuranic substrate and the catalytic hydrodeoxygenation of at least a portion of the tetrahydrofuranic substrate to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.
Abstract translation: 本发明一般涉及将碳水化合物源化学转化为己二酸产物的方法。 本发明包括通过呋喃底物如2,5-呋喃二羧酸或其衍生物将碳水化合物源转化成己二酸产物的方法。 本发明还包括用于生产己二酸产物的方法，其包括呋喃底物的催化氢化以产生四氢呋喃基底，以及将至少一部分四氢呋喃底物催化加氢脱氧至己二酸产物。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。
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Patent Agency Ranking
16.发明申请Production of Adipic Acid and Derivatives from Carbohydrate-Containing Materials 有权由含碳水化合物材料生产己二酸和衍生物公开(公告)号：US20140024858A1
公开(公告)日：2014-01-23
申请号：US13932413
申请日：2013-07-01
Applicant: Rennovia, Inc.
Inventor： Thomas R. Boussie , Eric L. Dias , Zachary M. Fresco , Vincent J. Murphy
IPC: C07C51/377
CPC classification number: C07C51/377 , C07C29/149 , C07C209/00 , C07C253/00 , C08G63/16 , C08G69/14 , C08G69/26 , C07C55/14 , C07C211/12 , C07C255/04 , C07C31/20
Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a carbohydrate source to an adipic acid product. The present invention includes processes for the conversion of a carbohydrate source to an adipic acid product via a furanic substrate, such as 2,5-furandicarboxylic acid or derivatives thereof. The present invention also includes processes for producing an adipic acid product comprising the catalytic hydrogenation of a furanic substrate to produce a tetrahydrofuranic substrate and the catalytic hydrodeoxygenation of at least a portion of the tetrahydrofuranic substrate to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.
Abstract translation: 本发明一般涉及将碳水化合物源化学转化为己二酸产物的方法。 本发明包括通过呋喃底物如2,5-呋喃二羧酸或其衍生物将碳水化合物源转化成己二酸产物的方法。 本发明还包括用于生产己二酸产物的方法，其包括呋喃底物的催化氢化以产生四氢呋喃基底，以及将至少一部分四氢呋喃底物催化加氢脱氧至己二酸产物。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。
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公开(公告)号：US09611241B2
公开(公告)日：2017-04-04
申请号：US14606789
申请日：2015-01-27
Applicant: Rennovia, Inc.
Inventor： Thomas R. Boussie , Eric L. Dias , Vincent J. Murphy , James A. W. Shoemaker
IPC: C07D307/50 , B01D61/14 , B01D61/02 , C07D307/46
CPC classification number: C07D307/46 , B01D61/027 , B01D61/145 , B01D2311/02 , B01D2311/25 , C07D307/50
Abstract: The present invention relates generally to processes for converting fructose-containing feedstocks to a product comprising 5-(hydroxymethyl)furfural (HMF) and water in the presence of water, solvent and an acid catalyst. In some embodiments, the conversion of fructose to HMF is controlled at a partial conversion endpoint characterized by a yield of HMF from fructose that does not exceed about 80 mol %. In these and other embodiments, the processes provide separation techniques for separating and recovering the product, unconverted fructose, solvent and acid catalyst to enable the effective recovery and reutilization of reaction components.
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18.发明申请公开(公告)号：US20170015642A1
公开(公告)日：2017-01-19
申请号：US15132178
申请日：2016-04-18
Applicant: RENNOVIA, INC.
Inventor： Valery Sokolovskii , Eric L. Dias , Hong X. Jiang , James M. Longmire , Vincent J. Murphy , Christopher Paul Dunckley , Gary M. Diamond , Thomas R. Boussie , James A.W. Shoemaker , Liza Lopez Soto
IPC: C07D307/46 , B01D61/14 , C07D307/42
CPC classification number: C07D307/46 , B01D61/027 , B01D61/145 , B01D61/362 , B01D61/58 , B01D2311/04 , B01D2311/06 , B01D2311/2623 , B01D2311/2626 , B01D2311/263 , B01D2311/2649 , B01D2311/2669 , C07D307/42 , C07D307/50
Abstract: The present invention relates generally to processes for converting fructose-containing feedstocks to a product comprising 5-(hydroxymethyl)furfural (HMF) and water in the presence of water, solvent and an acid catalyst. In some embodiments, the conversion of fructose to HMF is controlled at a partial conversion endpoint characterized by a yield of HMF from fructose that does not exceed about 80 mol %. In these and other embodiments, the processes provide separation techniques for separating and recovering the product, unconverted fructose, solvent and acid catalyst to enable the effective recovery and reutilization of reaction components.
Abstract translation: 本发明一般涉及在水，溶剂和酸催化剂存在下将含果糖的原料转化成包含5-（羟甲基）糠醛（HMF）和水的产物的方法。 在一些实施方案中，将果糖转化成HMF是在部分转化终点处控制的，其特征在于果糖的HMF的产率不超过约80mol％。 在这些和其它实施方案中，该方法提供了用于分离和回收产物，未转化的果糖，溶剂和酸催化剂的分离技术，以使得能够有效地回收和再利用反应组分。
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19.发明授权Process for production of hexamethylenediamine from carbohydrate-containing materials and intermediates therefor 有权由含碳水化合物的材料及其中间体生产六亚甲基二胺的方法公开(公告)号：US09518005B2
公开(公告)日：2016-12-13
申请号：US14687892
申请日：2015-04-15
Applicant: Rennovia, Inc.
Inventor： Eric L. Dias , James A. W. Shoemaker , Thomas R. Boussie , Vincent J. Murphy
IPC: C07C209/16 , C07D307/46 , C07C29/157 , C07D307/50 , C07C29/132 , C07D307/48 , C07C29/17 , C07C29/141
CPC classification number: C07C29/157 , C07C29/132 , C07C29/141 , C07C29/175 , C07C209/16 , C07D307/46 , C07D307/48 , C07D307/50 , C07C31/20 , C07C31/22 , C07C211/12
Abstract: Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1,6-hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1,6-hexanediol wherein 1,2,6-hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1,2,6-hexanediol is then converted by hydrogenation in the presence of a catalyst comprising Pt to 1,6 hexanediol, each process then proceding to the production of HMDA by known routes, such as amination of the 1,6 hexanediol. Catalysts useful for the direct and indirect production of 1,6-hexanediol are also disclosed.
Abstract translation: 公开了用于将碳水化合物源转化为六亚甲基二胺（HMDA）的方法和用于生产六亚甲基二胺和其它工业化学品的中间体。 HMDA通过在氢存在下将糠醛底物直接还原为1,6-己二醇和通过Pt的多相还原催化剂或通过将糠醛底物间接还原成1,6-己二醇来制备，其中1,2,6-己三醇 通过在氢气存在下还原糠醛底物而制备，然后在包含Pt至1,2,6-己二醇的催化剂存在下，通过氢化转化包含Pt和1,2,6-己二醇的催化剂，然后每个过程进行 通过已知途径生产HMDA，如1,6己糖胺的胺化。 还公开了用于直接和间接生产1,6-己二醇的催化剂。
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公开(公告)号：US20160090346A1
公开(公告)日：2016-03-31
申请号：US14869237
申请日：2015-09-29
Applicant: Rennovia Inc.
Inventor： Gary M. Diamond , Eric L. Dias , Raymond Archer , Vincent J. Murphy , Thomas R. Boussie
CPC classification number: C07C51/47 , B01D15/1821 , B01D15/363 , C07C51/16 , C07C51/23 , C07C51/27
Abstract: Processes for separating a di-carboxylic acid or salt thereof from a mixture containing the di-carboxylic acid or salt thereof and one or more other components are provided. Also separation media useful for these separation processes is provided. In particular, processes for preparing an aldaric acid are described, such as glucaric acid from glucose, which includes separating the aldaric acid from the reaction product. Also, various glucaric acid products are described.
Abstract translation: 提供了从含有二羧酸或其盐和一种或多种其它组分的混合物中分离二羧酸或其盐的方法。 还提供了用于这些分离方法的分离介质。 特别地，描述了制备阿拉德酸的方法，例如葡萄糖的葡糖二酸，其包括从反应产物中分离出醛酸。 另外，还描述了各种葡糖二酸产物。
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