摘要:
Novel crystalline zeolitic materials of the faujasite structure having an increased ratio of zeolitic surface area to mesoporous surface area and distinctive X-Ray Diffraction peak ratios are produced by calcining zeolite Y of low sodium content at temperatures above 600.degree. C.
摘要:
Silicon-containing species which evolve from the calcination of silicone treated catalysts may be removed by the use of an alumina-containing guard bed. The method is particularly useful for the production of silicone treated ZSM-5 catalysts.
摘要:
Relatively heavy or relatively light lube chargestocks are dewaxed in two parallel, separate reactors. The reactor used for dewaxing the relatively light chargestocks contains a crystalline aluminosilicate zeolite exemplified natural or synthetic ferrierite, ZSM-22, ZSM-23 and ZSM-35 zeolites and/or mixtures thereof. The reactor used for dewaxing the relatively heavy chargestocks contains a crystalline aluminosilicate zeolite exemplified by ZSM-5, ZSM-11 zeolites, ZSM-5/ZSM-11 intermediates and/or mixtures thereof.
摘要:
A feedstock of low molecular weight oxygenates such as methanol and/or dimethylether is contacted with a mildly presteamed or hydro-thermally treated zeolite catalyst in a reaction zone to produce liquid hydrocarbons in the gasoline boiling range. The pretreated zeolite catalyst has an .alpha.-value (acid cracking activity) substantially the same as the .alpha.-value of fresh unsteamed catalyst and shows increased stability and resistance to aging under oxygenate conversion conditions of elevated temperature and pressure.
摘要:
A process for removing catalyst fines from the wax product produced in a slurry Fischer-Tropsch reactor comprises removing the wax product from the reactor and separating the catalyst fines by passing the wax product through a high gradient magnetic field, whereby the catalyst fines are held by a magnetized filter element and the wax product passes through unhindered to form a purified wax product which is ready for upgrading. The separated catalyst fines are returned to the reactor by backwashing the filter element.
摘要:
A highly dispersed platinum ZSM-5 catalyst used in hydrodewaxing lube stock yields a product with improved overnight cloud performance and lighter ASTM color.
摘要:
There is provided the polymerization of 1-olefins such as ethylene with zeolite supported, chromium catalyst compositions. Chromium ions are ion exchanged with zeolites to produce such catalysts.
摘要:
A catalytic process is provided for converting gaseous feedstocks containing ethane to liquid aromatics by contacting said gaseous feeds in the absence of added air or oxygen, under conversion conditions, with a crystalline zeolite catalyst having incorporated therein a minor amount of gallium, thereby converting the ethane in the feedstock to aromatics and recovering a liquid mixture of benzene, toluene and xylene.
摘要:
Octane and total yield improvement in catalytic cracking processes can be attained by the addition to conventional cracking catalysts of very small amounts of additive catalyst comprising a class of zeolites characterized by a silica to alumina mole ratio greater than 12 and a constraint index of about 1 to 12. The weight ratio of said zeolite of the additive catalyst to the amount of active component, e.g. faujasite zeolite, in the conventional cracking catalyst ranges from between about 1:400 and about 1:15.
摘要:
A metal combustion promoter is introduced to the circulating inventory of catalyst in a catalytic cracking unit as a mixture of particles rich in metal with particles free of metal such that the net concentration of metal in the mixture is about 1 to 10 ppm. According to a preferred embodiment the particles rich in metal contain about 50 ppm of platinum, iridium, osmium, palladium, rhodium, ruthenium or rhenium. When such mixtures are supplied to the circulating inventory, it is found that specific activity of the metal is enhanced in the sense that activity of the mixture for oxidation of carbon monoxide is higher than that of catalyst in which an equal amount of metal is evenly distributed among all the particles.