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11.发明授权Processes for the use of cobalt-aluminum-phosphorus-silicon-oxide molecular sieve compositions 失效使用钴 - 铝 - 磷 - 氧化硅分子筛组合物的方法
公开(公告)号：US4824554A
公开(公告)日：1989-04-25
申请号：US149590
申请日：1988-01-28
IPC分类号： B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G47/02 , C07C2/68 , C07C4/12
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of CoO.sub.2, AlO.sub.2, SiO.sub.2, PO.sub.2 and tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of cobalt, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CoO 2，AlO 2，SiO 2，PO 2和四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（CowAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CowAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钴，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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12.发明授权
公开(公告)号：US4758419A
公开(公告)日：1988-07-19
申请号：US600180
申请日：1984-04-13
IPC分类号： C10G35/095 , B01J20/18 , B01J29/00 , B01J29/85 , C01B37/08 , C01B39/06 , C07C1/00 , C07C2/12 , C07C2/54 , C07C2/66 , C07C4/18 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C07C6/12 , C07C9/00 , C07C15/08 , C07C67/00 , C10G49/08 , C01B25/26 , B01J27/18 , B01J27/182
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/84 , Y10S423/30
摘要： Crystalline molecular sieves having a three-dimensional microporous framework structures of MgO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.
摘要翻译： 公开了具有MgO 2，AlO 2，SiO 2和PO 2四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（MgwAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（MgwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的镁，铝，磷和硅的摩尔分数。 公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4129450A
公开(公告)日：1978-12-12
申请号：US849896
申请日：1977-11-09
CPC分类号： F17C11/002 , C04B28/18 , C10L3/04
摘要： An aqueous slurry composition which is curable at saturated steam pressure and temperature of 360.degree. to 400.degree. F to form a hard porous mass suitable for containing dissolved acetylene gas solutions, comprising lime, crystalline silica, and a thickening agent selected from the group consisting of (a) polyethylene oxide, (b) amorphous glassy silica, (c) a soluble salt of phosphate and a soluble salt of calcium and (d) a soluble salt of phosphate and a neutralizing acid.
摘要翻译： 一种含水浆料组合物，其在饱和蒸汽压力和360°至400°F的温度下可固化，以形成适于含有溶解的乙炔气体溶液的硬质多孔体，其包含石灰，结晶二氧化硅和选自以下的增稠剂： （a）聚环氧乙烷，（b）无定形玻璃状二氧化硅，（c）可溶性磷酸盐和钙的可溶性盐，和（d）磷酸盐和中和酸的可溶性盐。
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公开(公告)号：US4744970A
公开(公告)日：1988-05-17
申请号：US600174
申请日：1984-04-13
IPC分类号： C10G11/02 , B01J20/10 , B01J29/00 , B01J29/85 , C01B37/04 , C01B37/08 , C01B39/04 , C01B39/10 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/00 , C10G49/08 , C01B25/00 , B01J29/02 , C01B33/26
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of CoO.sub.2, AlO.sub.2, SiO.sub.2, PO.sub.2 and tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of cobalt, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CoO 2，AlO 2，SiO 2，PO 2和四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（CowAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CowAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钴，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂催化剂等的用途。
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公开(公告)号：US4683217A
公开(公告)日：1987-07-28
申请号：US600173
申请日：1984-04-13
IPC分类号： C10G35/095 , B01J20/18 , B01J29/00 , B01J29/85 , C01B37/08 , C01B39/06 , C07C1/00 , C07C2/12 , C07C2/54 , C07C2/66 , C07C4/18 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C07C6/12 , C07C9/00 , C07C15/08 , C07C67/00 , C10G49/08 , B01J27/182
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/84
摘要： A novel class of iron-aluminum-phosphorus-silicon-oxide molecular sieves is disclosed which contain as framework constituents FeO.sub.2.sup.-, and/or FeO.sub.2.sup.-2, AlO.sub.2.sup.-, PO.sub.2.sup.+ and SiO.sub.2 tetrahedral oxide units. These compositions are prepared hydrothermally, preferably using organic templating agents and are suitably employed as adsorbents and catalysts.
摘要翻译： 公开了一类新型的铁 - 铝 - 磷 - 氧化硅分子筛，其包含作为骨架组分FeO 2 - 和/或FeO 2 -2，AlO 2 - ，PO 2+和SiO 2四面体氧化物单元。 这些组合物水热制备，优选使用有机模板剂，适合用作吸附剂和催化剂。
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公开(公告)号：US4554143A
公开(公告)日：1985-11-19
申请号：US514335
申请日：1983-07-15
IPC分类号： B01J20/02 , B01J27/185 , B01J29/84 , C01B25/45 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C07C11/09 , B01J27/18
CPC分类号： C07C5/41 , B01J20/0292 , B01J27/1853 , B01J29/84 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C01B39/00 , C07C2529/84
摘要： Novel class of crystalline microporous ferroaluminophosphate compositions containing as lattice constituents in addition to AlO.sub.2 and PO.sub.2 structural units, ferric and/or ferrous iron in tetrahedral coordination with oxygen atoms. These compositions are prepared hydrothermally using organic templating agents and are suitably employed as catalysts or adsorbents.
摘要翻译： 除AlO 2和PO 2结构单元之外还含有作为晶格组分的结晶微孔铁铝磷酸盐组合物的新型，与氧原子四面体配位的铁和/或亚铁。 这些组合物是使用有机模板剂水热制备的，并且适合用作催化剂或吸附剂。
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公开(公告)号：US4440871A
公开(公告)日：1984-04-03
申请号：US400438
申请日：1982-07-26
申请人： Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
发明人： Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
IPC分类号： C01B33/26 , B01J20/18 , B01J21/00 , B01J29/04 , B01J29/85 , C01B37/08 , C01B39/04 , C01B39/10 , C01B39/14 , C01B39/28 , C01B39/32 , C07B61/00 , C07C2/54 , C07C2/70 , C07C2/86 , C07C4/08 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/32 , C07C5/41 , C10G11/05 , C10G35/095 , C10G45/12 , C10G45/34 , C10G45/54 , C10G45/64 , C10G47/16 , C10G49/08 , B01J27/14
CPC分类号： C07C5/41 , B01J20/18 , B01J29/85 , C01B37/08 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/85
摘要： A novel class of crystalline microporous silicoaluminophosphates is synthesized by hydrothermal crystallization of silicoaluminophosphate gels containing a molecular structure-forming templating agent. The class comprises a number of distinct species, each with a unique crystal structure. The compositions exhibit properties somewhat analogous to zeolitic molecular sieves which render them useful as adsorbent or catalysts in chemical reactions such as hydrocarbon conversions.
摘要翻译： 通过含有分子结构形成模板剂的硅铝磷酸凝胶的水热结晶合成了一类新型的结晶微孔硅铝磷酸盐。 该类包括许多不同的物种，每个具有独特的晶体结构。 该组合物显示出类似于沸石分子筛的性质，其使得它们可用作化学反应如烃转化中的吸附剂或催化剂。
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18.发明授权Hydrocarbon conversion processes using a novel crystalline microporous metal oxysulfide composition 失效使用新的结晶微孔金属氧硫化物组合物的烃转化方法
公开(公告)号：US5128025A
公开(公告)日：1992-07-07
申请号：US803936
申请日：1991-12-09
CPC分类号： B01J29/85 , B01J29/005 , C01B33/2884 , B01J29/84
摘要： This invention deals with a hydrocarbon conversion process using a crystalline oxysulfide composition. The crystalline oxysulfide composition has a three-dimensional microporous framework structure of at least MO.sub.2, MS.sub.2, and MOS tetrahedral units, having an intracrystalline pore system and an empirical formula expressed in molar ratios:(M.sub.s Al.sub.t P.sub.u Si.sub.v)S.sub.w O.sub.2-wwhere M is at least one metal selected from the group consisting of metals which: 1) can be incorporated into the framework structure of a microporous molecular sieve and 2) form hydrolytically stable sulfides; s, t, u, v and w are the mole fractions of M, Al, P, Si and S respectively. The values of s, t, u and v are chosen such that when t is greater than zero u is greater than zero, s+t+u+v=1 and when s=1, M is only a combination of gallium and germanium.
摘要翻译： 本发明涉及使用结晶氧硫化物组合物的烃转化方法。 结晶氧硫化物组合物具有至少具有MO2，MS2和MOS四面体单元的三维微孔骨架结构，具有结晶孔系统和以摩尔比表示的经验式：（MsAltPuSiv）SwO 2 -w，其中M为至少一个 选自以下的金属的金属：1）可以结合到微孔分子筛的骨架结构中，2）形成水解稳定的硫化物; s，t，u，v和w分别是M，Al，P，Si和S的摩尔分数。 选择s，t，u和v的值，使得当t大于零时，u大于零，s + t + u + v = 1，当s = 1时，M只是镓和锗的组合 。
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19.发明授权Process for separating a mixture of molecular species using crystalline microporous metal sulfide compositions 失效使用结晶微孔金属硫化物组合物分离分子物质的混合物的方法
公开(公告)号：US5013337A
公开(公告)日：1991-05-07
申请号：US507819
申请日：1990-04-12
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82 , Y10S95/902
摘要： This invention relates to a process for separating a mixture of molecular species based on the molecular size (kinetic diameter) or on the degree of polarity of the molecular species using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. A composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium may also be used in the process.
摘要翻译： 本发明涉及使用具有MA2单元的三维微孔结构的结晶组合物，基于分子大小（动力学直径）或分子物质的极性的程度来分离分子种类的混合物的方法，其中A是硫 或硒，并具有以摩尔比表示的经验式：xR：MA2 +/- 0.2：zH2O其中R表示晶体内孔体系中存在的至少一种有机模板剂，x是R的摩尔数，z是水的摩尔数， M是锗或锡。 具有以摩尔比表示的经验式的组合物：xR：M1-yM'yA2 +/- 0.2：zH2O，其中M'是诸如钴，锌，锰，铁，镍，铜，镉和镓的金属也可以是 在过程中使用。
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20.发明授权
公开(公告)号：US4973460A
公开(公告)日：1990-11-27
申请号：US218494
申请日：1988-07-06
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of LiO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of lithium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有LiO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（LiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（LiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锂，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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