公开(公告)号：US20130190457A1

公开(公告)日：2013-07-25

申请号：US13745346

申请日：2013-01-18

Applicant: tesa SE

Inventor： Alexander Prenzel ,  Sarah Bamberg ,  Jennifer Beschmann ,  Marten Papenbroock

IPC: C08F20/18

CPC classification number: C08F20/18 ,  C08K5/1515 ,  C08K5/17 ,  C09J133/00

Abstract: Controlled thermal crosslinking in a polyacrylate-based composition is accomplished by a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at leastone substance comprising at least one epoxide group (crosslinker) and at least one substance of the general formula (I) R1R2N—CR3R4—CR5R6—(CR7R8)n—NR9R10  (I) wherein the radicals R1, R2, R9 and R10 independently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or an alkylene group bonded to the main chain and having 1 to 8 carbon atoms, where at least one of the radicals R1, R2, R9 and R10 is not a hydrogen atom; the radicals R3, R4, R5, R6, R7 and R8 independently of one another are a hydrogen atom or an alkyl group having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; and n is an integer from 0 to 4 (accelerator).

Abstract translation: 基于聚丙烯酸酯的组合物中的受控热交联通过交联剂 - 促进剂体系完成，所述交联剂 - 促进剂体系用于具有适于进入与环氧基团的连接反应的官能团的聚丙烯酸酯的热交联，所述交联剂加速剂体系包含至少一种包含至少一个环氧基团的物质（交联剂） 和其中基团R 1，R 2，R 9和R 10彼此独立地为氢原子或取代或未取代的至少一种通式（I）R 1 R 2 N-CR 3 R 4 -CR 5 R 6 - （CR 7 R 8）n -NR 9 R 10（I） 具有1至8个碳原子的烷基或环烷基或与主链键合且具有1至8个碳原子的亚烷基，其中基团R 1，R 2，R 9和R 10中的至少一个不是氢原子; R 3，R 4，R 5，R 6，R 7和R 8彼此独立地为氢原子或具有1至8个碳原子的烷基或形成5-7元环亚烷基; n为0〜4的整数（促进剂）。

公开(公告)号：US10196549B2

公开(公告)日：2019-02-05

申请号：US15100799

申请日：2014-10-30

Applicant: TESA SE

Inventor： Marten Papenbroock ,  Alexander Prenzel

IPC: C08L51/00 ,  C09J151/00 ,  C08F290/04 ,  B32B37/12

Abstract: Multi-phase polymer composition comprising a comb polymer (A) which forms a continuous acrylate phase and a discontinuous hydrocarbon phase, and at least one hydrocarbon compound (B) which is soluble in the hydrocarbon phase of the comb polymer (A), an adhesive mass comprising the multi-phase polymer composition.

公开(公告)号：US20140057091A1

公开(公告)日：2014-02-27

申请号：US13948398

申请日：2013-07-23

Applicant: tesa SE

Inventor： Thorsten Krawinkel ,  Alexander Prenzel ,  Minyoung Bai

IPC: C09J7/02

CPC classification number: C09J7/38 ,  C09J7/22 ,  C09J7/26 ,  C09J7/383 ,  C09J2409/00 ,  C09J2425/00 ,  C09J2433/006 ,  C09J2453/00 ,  Y10T428/249971 ,  Y10T428/249983

Abstract: An adhesive tape, with a carrier material, has an acrylate-based foam layer bearing at least one layer of pressure-sensitive adhesive. The pressure-sensitive adhesive (a) being composed of a mixture of at least two different synthetic rubbers, more particularly based on vinylaromatic block copolymers, (b) comprising a resin which is not soluble in the acrylates forming the foam layer, and (c) being chemically uncrosslinked.

Abstract translation: 具有载体材料的胶带具有至少一层压敏粘合剂的基于丙烯酸酯的泡沫层。 压敏粘合剂（a）由至少两种不同的合成橡胶，特别是基于乙烯基芳族嵌段共聚物的混合物组成，（b）包含不溶于形成泡沫层的丙烯酸酯的树脂，和（c ）在化学上是未交联的。

公开(公告)号：US20130165606A1

公开(公告)日：2013-06-27

申请号：US13720487

申请日：2012-12-19

Applicant: TESA SE

Inventor： Alexander Prenzel

IPC: C09J141/00

CPC classification number: C09J141/00 ,  C08F293/00 ,  C08F2438/03 ,  C09J133/02 ,  C09J133/08 ,  C09J133/10

Abstract: The invention relates to a process for preparing pressure-sensitive adhesives (PSAs) which have high molar masses in combination with a narrow molar mass distribution, and also to PSAs, especially polyacrylate-based PSAs, prepared accordingly.It has been found that, surprisingly, polymers with high molar masses and a narrow molar mass distribution, more particularly polyacrylates with high molar masses and a narrow molar mass distribution, can be prepared outstandingly in particular by means of RAFT processes in the presence of a diradical initiator which undergoes thermal cyclization to form a diradical, these polymers being suitable for use as high-shear-strength PSAs.

Abstract translation: 本发明涉及一种制备具有高摩尔质量并且结合窄摩尔质量分布的压敏粘合剂（PSA）的方法，以及相应制备的PSA，特别是基于聚丙烯酸酯的PSA。 已经发现令人惊奇的是，具有高摩尔质量和较低摩尔质量分布的聚合物，更特别是具有高摩尔质量和较窄摩尔质量分布的聚丙烯酸酯，可以特别通过RAFT方法在存在 经历热环化以形成双向的双基引发剂，这些聚合物适合用作高剪切强度的PSA。

公开(公告)号：US10023773B2

公开(公告)日：2018-07-17

申请号：US14683376

申请日：2015-04-10

Applicant: TESA SE

Inventor： Michael Siebert ,  Alexander Prenzel ,  Inga Auktun ,  Jennifer Beschmann

IPC: C09J133/00 ,  C09J133/08 ,  C09J133/02 ,  D06M17/04 ,  D21H19/00 ,  C08F220/06 ,  C09J7/38 ,  C09J7/21 ,  C08F220/18

Abstract: Adhesives and pressure-sensitive adhesives comprising polymerization products of acrylates, the adhesives being meltable and comprising polymerization products of esters of (meth)acrylic acid and (meth)acrylic acid, the polymerization product having a molecular weight Mn of greater than 50 000 g/mol and Mw of greater than 500 000 g/mol.

公开(公告)号：US09951162B2

公开(公告)日：2018-04-24

申请号：US15115991

申请日：2015-02-18

Applicant: TESA SE

Inventor： Alexander Prenzel

IPC: C08F2/46 ,  C08F2/50 ,  C08G61/04 ,  C08F220/18 ,  C08J3/28 ,  C08J3/24 ,  C09J133/08 ,  C09J4/06

CPC classification number: C08F220/18 ,  C08F2220/1825 ,  C08F2220/1858 ,  C08J3/24 ,  C08J3/28 ,  C08J2433/08 ,  C08L67/07 ,  C08L75/14 ,  C09J4/06 ,  C09J133/08 ,  C09J133/14 ,  C08F2220/1808 ,  C08F220/06 ,  C08F2220/302

Abstract: Monomer composition comprising (i) acrylic monomers selected from the group consisting of (meth)acrylic acid and (meth)acrylic esters; (ii) orthoalkyl phenyl ketone- and/or orthoalkyl phenyl aldehyde-functionalized (meth)acrylate monomers; and (iii) optionally, further olefinically unsaturated monomers having functional groups; process for preparing a first polymer composition comprising the free-radical polymerization of the monomer composition, and polymer composition obtainable by this process; composition comprising the polymer composition and a dienophile which can react with hydroxy-ortho-quinodimethane functional groups in a Diels-Alder or hetero-Diels-Alder reaction and conversion of this composition to a crosslinked polymer composition.

公开(公告)号：US09834636B2

公开(公告)日：2017-12-05

申请号：US15104323

申请日：2014-11-19

Applicant: TESA SE

Inventor： Bernd Lühmann ,  Alexander Prenzel ,  Benjamin Pütz ,  Helmut Ritter ,  Stephan Zöllner

IPC: B32B27/00 ,  B32B7/12 ,  C08F265/06 ,  C09J151/00 ,  C09J7/02 ,  B32B27/08 ,  B32B27/30

CPC classification number: C08F265/06 ,  B32B7/12 ,  B32B27/08 ,  B32B27/308 ,  B32B2307/718 ,  B32B2405/00 ,  C08F285/00 ,  C09J151/003 ,  C08F220/18 ,  C08F220/06 ,  C08F2220/1833 ,  C08F2220/1858

Abstract: Crosslinked pressure-sensitive adhesives (PSAs) based on polymers of branched macromolecules each comprising a main chain and one or more sidechains pendent to the main chain, the constitutional units thereof originating from a) X wt % of one or more acrylic and/or methacrylic esters, with 80 =1000 g/mol, and the respective amounts of constitutional units originating from a), b) and c) can be the same in each case or differ by not more than 1%, and where a), b) and c) may in each case be the same or different monomers, have detachment properties which can be set independently of one another.

公开(公告)号：US09540458B2

公开(公告)日：2017-01-10

申请号：US14356477

申请日：2012-09-28

Applicant: TESA SE

Inventor： Alexander Prenzel

IPC: C08F8/42 ,  C08F2/38 ,  C08F220/18 ,  C09J153/00 ,  C08F8/00

CPC classification number: C08F8/42 ,  C08F2/38 ,  C08F8/00 ,  C08F8/48 ,  C08F220/18 ,  C08F2438/03 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/30 ,  C08F2810/40 ,  C09J153/005 ,  C08F2220/1858 ,  C08F2220/1825 ,  C08F220/06 ,  C08F293/005

Abstract: Method for producing polyacrylate adhesive compounds with a narrow molar mass distribution by radical polymerization and subsequent decolorization of colored reaction products resulting therefrom.

Abstract translation: 通过自由基聚合制造具有窄摩尔质量分布的聚丙烯酸酯粘合剂化合物的方法，随后由其产生的着色反应产物脱色。

公开(公告)号：US20140329971A1

公开(公告)日：2014-11-06

申请号：US14358577

申请日：2012-09-28

Applicant: TESA SE

Inventor： Alexander Prenzel

IPC: C09J133/08 ,  C08F220/18

CPC classification number: C09J133/08 ,  C08F2/38 ,  C08F220/18 ,  C08F2438/03 ,  C08F2220/1858 ,  C08F2220/1825 ,  C08F220/06

Abstract: The invention relates to a method for producing polyacrylate adhesive compounds with a narrow molar mass distribution by means of a radical polymerization and a subsequent increase of the molar masses by reacting with bis- or multi-dienyl compounds, in particular with α,ω-bis-dienyl compounds, in order to increase the cohesion in particular.

Abstract translation: 本发明涉及通过自由基聚合制备具有窄摩尔质量分布的聚丙烯酸酯粘合剂化合物的方法，随后通过与双或多二烯基化合物，特别是与α，ω-双 二烯基化合物，特别是增加内聚力。

公开(公告)号：US20140170326A1

公开(公告)日：2014-06-19

申请号：US14139198

申请日：2013-12-23

Applicant: tesa SE

Inventor： Norbert Grittner ,  Sven Hansen ,  Alexander Prenzel ,  Stephan Zöllner

IPC: C08F220/10 ,  B05D3/02

CPC classification number: C08F220/10 ,  B05D3/02 ,  B29B7/485 ,  B29B7/487 ,  B29B7/726 ,  B29B7/7495 ,  B29B7/90 ,  C08F2220/1858 ,  C09J133/08 ,  C09J2201/61 ,  C08F220/06 ,  C08F220/14 ,  C08F2220/185 ,  C08F2220/281

Abstract: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates with functional groups suitable for entering into linking reactions with cyclic ethers, more particularly epoxide groups or oxetane groups, comprising at least one substance containing epoxide or oxetane groups (crosslinker) and at least one substance with an accelerating action for the linking reaction at a temperature below the melting temperature of the polyacrylate (accelerator).

Abstract translation: 用于聚丙烯酸酯与适于与环醚，更特别是环氧基团或氧杂环丁烷基团进行交联反应的官能团的热交联的交联剂 - 加速剂体系，其包含至少一种含有环氧化物或氧杂环丁烷基团的物质（交联剂）和至少一种具有 在低于聚丙烯酸酯（促进剂）的熔融温度的温度下的连接反应的加速作用。