公开(公告)号：US20170210943A1

公开(公告)日：2017-07-27

申请号：US15321665

申请日：2015-07-17

Applicant: TOKUYAMA CORPORATION

Inventor： Yasutomo SHIMIZU ,  Katsuhiro MORI

IPC: C09D183/14 ,  C08K5/357 ,  C08K5/1545 ,  G02B5/22 ,  C09D5/32 ,  C08G77/52 ,  G02B5/23 ,  C08K5/18 ,  C09K9/02

CPC classification number: C09D183/14 ,  C08F220/20 ,  C08F222/1006 ,  C08F230/08 ,  C08F290/06 ,  C08F290/14 ,  C08F299/08 ,  C08G77/52 ,  C08G77/80 ,  C08K5/1545 ,  C08K5/18 ,  C08K5/357 ,  C09D4/00 ,  C09D5/32 ,  C09K9/02 ,  C09K2211/1007 ,  C09K2211/1033 ,  C09K2211/1088 ,  G02B5/223 ,  G02B5/23 ,  G02B7/10 ,  G02C7/10 ,  G02C7/102 ,  C08F2222/108 ,  C08F2222/1073 ,  C08F2222/1026 ,  C08F2220/325 ,  C08F2230/085 ,  C08F220/36

Abstract: A curable composition having excellent storage stability and capable of forming a cured product having excellent scratch resistance.The composition comprises a silsesquioxane monomer having a radically polymerizable group in the molecule and a content of a component having a molecular weight measured by gel permeation chromatography (GPC) of not less than 10,000 of less than 9 mass % and a bifunctional polymerizable monomer represented by the following formula (1). (wherein B and B′ are each an linear or branched alkylene group having 2 to 15 carbon atoms, “c” is an average value of 1 to 20, when a plurality of B's are existent, B's may be the same or different, and R5 and R6 are each a hydrogen atom or methyl group.)

公开(公告)号：US20240209254A1

公开(公告)日：2024-06-27

申请号：US18286646

申请日：2022-03-30

Applicant: TOKUYAMA CORPORATION

Inventor： Yuki HATTORI ,  Katsuhiro MORI ,  Junji MOMODA

IPC: C09K9/02 ,  G02C7/10 ,  G02C7/12

CPC classification number: C09K9/02 ,  G02C7/102 ,  G02C7/12 ,  C09K2211/1018

Abstract: The optical article of the invention contains a photochromic compound, and a first compound having an absorption peak in a wavelength range of 550 to 600 nm, has a laminate structure in which (A) a first functional layer containing at least a photochromic compound and (B) a lens substrate independently exist, has a luminous transmittance of 30% or more in the state with no photochromic compound coloration, has a luminous transmittance of 25% or less in the state with photochromic compound coloration, and has a minimum transmittance of 0.1 to 20% in a wavelength range of 550 to 600 nm, in a state with photochromic compound coloration. According to the invention, there is provided a novel photochromic optical article exhibiting excellent photochromic properties, visibility and anti-glare properties, and further having a high contrast (red, green and blue can be clearly differentiated and the outline and protrusions/recesses of objects are clear).

公开(公告)号：US20230286912A1

公开(公告)日：2023-09-14

申请号：US17927852

申请日：2021-05-25

Applicant: TOKUYAMA CORPORATION

Inventor： Takao NOGUCHI ,  Katsuhiro MORI ,  Junji MOMODA

IPC: C07C323/52 ,  C09K9/02 ,  C09D175/08 ,  C08J7/04 ,  C08G18/38 ,  C08G65/334 ,  C09J175/08

CPC classification number: C07C323/52 ,  C08G18/3868 ,  C08G65/3344 ,  C08J7/04 ,  C09D175/08 ,  C09J175/08 ,  C09K9/02 ,  C08J2375/08 ,  C08J2475/08 ,  C09K2211/1018 ,  G02B5/23

Abstract: The present invention provides a novel compound for optical materials, and a curable composition, a cured body and an optical article containing the compound for optical materials. According to an embodiment, there is provided a compound for optical materials represented by Formula (Ia) below:





In Formula (Ia), X1 and X2 are each NH, S, or O. R1 is a 1- to 30-valent organic residue. R3 is a group composed of a polymer having a repeating unit selected from the group consisting of —(CH2)mO—, —(CH2CH2O)—, —(CH(CH3)CH2O)—, —(CH2CH(CH3)O)—, — (C(═O)—CH2CH2CH2CH2CH2O)—, —(C(═O)—O—CH2CH2CH2CH2CH2O)—, and —(C(═O)—O—CH2CH2CH2CH2CH2CH2O)—, a random copolymer having at least two repeating units selected from the group, or a block copolymer having at least two repeating units selected from the group.

公开(公告)号：US20210040335A1

公开(公告)日：2021-02-11

申请号：US16965644

申请日：2019-01-30

Applicant: TOKUYAMA CORPORATION

Inventor： Manami OSHIO ,  Katsuhiro MORI ,  Yuuichirou KAWABATA

IPC: C09D7/61 ,  C09D183/00 ,  C09D7/20 ,  G02B1/14

Abstract: A coating composition comprising (A) inorganic oxide fine particles, (B) a hydrolyzable group-containing organic silicon compound, (C) water or an acid aqueous solution, (D) a curing catalyst and (E) an organic solvent, wherein the inorganic oxide fine particles (A) contain 100 parts by mass of (A1) first inorganic oxide fine particles containing not less than 50 mass % of a zirconium oxide component and 0.1 to 90 parts by mass of (A2) cerium oxide fine particles. This coating composition is used to form a hard coat film.

公开(公告)号：US20170240769A1

公开(公告)日：2017-08-24

申请号：US15518823

申请日：2015-12-02

Applicant: TOKUYAMA CORPORATION

Inventor： Katsuhiro MORI

IPC: C09D183/04 ,  G02C7/10 ,  G02B5/23 ,  G02B5/22 ,  C09D7/12 ,  G02B1/14

CPC classification number: C09D7/40 ,  C08G77/50 ,  C08K3/22 ,  C08K2003/2237 ,  C09D7/61 ,  C09D183/04 ,  G02B1/14 ,  G02B5/206 ,  G02B5/208 ,  G02B5/223 ,  G02B5/23 ,  G02B2207/109 ,  G02C7/02 ,  G02C7/10 ,  G02C7/102 ,  G02C2202/16 ,  C09D183/14

Abstract: A coating composition comprising inorganic oxide fine particles containing at least one element selected from the group consisting of Ti, Zr, Sn and Sb, a hydrolysable group-containing organic silicon compound, and (C1) a surfactant having an HLB value of 8 or less and (C2) a surfactant having an HLB value of more than 8, for forming a coat layer having little white turbidity, a good appearance and excellent scratch resistance, chemical resistance, hot water resistance and weather resistance on the surface of a plastic optical substrate.

公开(公告)号：US20160116765A1

公开(公告)日：2016-04-28

申请号：US14893711

申请日：2014-07-09

Applicant: TOKUYAMA CORPORATION

Inventor： Yasutomo SHIMIZU ,  Katsuhiro MORI ,  Junji MOMODA

IPC: G02C7/10 ,  G02B1/04 ,  B29C45/00 ,  G02B1/10 ,  C09K9/02 ,  B32B27/30

CPC classification number: G02C7/102 ,  B29C45/0001 ,  B29K2033/08 ,  B29L2011/0016 ,  B32B27/308 ,  B32B2250/02 ,  B32B2307/402 ,  B32B2551/00 ,  C08F2/44 ,  C08F20/32 ,  C09K9/02 ,  C09K2211/1033 ,  C09K2211/1088 ,  G02B1/04 ,  G02B1/10 ,  G02B5/23 ,  G02C2202/16

Abstract: A photochromic curable composition comprising (A) a polymerizable monomer component that contains a (meth)acrylic polymerizable monomer (X), and (B) a photochromic compound, wherein the (meth)acrylic polymerizable monomer (X) is constituted by 80 to 97 parts by mass of a polyfunctional monomer (Xp) having not less than two (meth)acrylic groups in a molecule thereof, and 3 to 20 parts by mass of a monofunctional monomer (Xm) having one (meth)acrylic group in a molecule thereof, the monofunctional polymerizable monomer (Xm) is constituted by an epoxy group-containing monomer (Xm1) and an isocyanate group-containing monomer (Xm2), and the isocyanate group-containing monomer (Xm2) and the epoxy group-containing monomer (Xm1) are contained at a mass ratio of Xm2/Xm1=3 to 40.

Abstract translation: 1.一种光致变色固化性组合物，其含有（A）含有（甲基）丙烯酸系聚合性单体（X）的聚合性单体成分和（B）光致变色化合物，其中，所述（甲基）丙烯酸系聚合性单体（X）为80〜97 分子内具有不少于2个（甲基）丙烯酸基团的多官能单体（Xp）质量份，分子内具有1个（甲基）丙烯酸基的单官能单体（Xm）3〜20质量份 ，单官能聚合性单体（Xm）由含环氧基的单体（Xm1）和含异氰酸酯基的单体（Xm2）构成，含异氰酸酯基的单体（Xm2）和含环氧基的单体（Xm1 ）以质量比Xm2 / Xm1 = 3〜40。

公开(公告)号：US20160002524A1

公开(公告)日：2016-01-07

申请号：US14770181

申请日：2014-02-26

Applicant: TOKUYAMA CORPORATION

Inventor： Yasutomo SHIMIZU ,  Junji TAKENAKA ,  Junji MOMODA ,  Katsuhiro MORI

IPC: C09K9/02 ,  G02C7/10 ,  G02B5/22 ,  G02B1/10 ,  G02B5/23

CPC classification number: C09K9/02 ,  C08F2/50 ,  C08F220/28 ,  C08F290/061 ,  C09K2211/1088 ,  C09K2211/1425 ,  G02B1/10 ,  G02B5/223 ,  G02B5/23 ,  G02C7/102

Abstract: A curable composition which comprises a carbonate-based polymerizable monomer represented by the following formula, other polymerizable monomers and a photochromic compound, can be used even under high-temperature and high-humidity conditions without any problems and provides a cured product having excellent photochromic properties. wherein A and A′ are each a linear or branched alkylene group having 2 to 15 carbon atoms, “a” is an average value of 1 to 20, when there are a plurality of A's, A's may be the same or different, R1 is a hydrogen atom or methyl group, and R2 is a (meth)acryloyloxy group or hydroxyl group.

Abstract translation: 即使在高温高湿条件下也可以使用包含下式表示的碳酸酯系聚合性单体的固化性组合物，其它的可聚合单体和光致变色化合物，并且提供具有优异的光致变色特性的固化物 。 其中A和A'各自为具有2至15个碳原子的直链或支链亚烷基，“a”为1至20的平均值，当存在​​多个A时，A可以相同或不同，R 1为 氢原子或甲基，R2为（甲基）丙烯酰氧基或羟基。

公开(公告)号：US20140295096A1

公开(公告)日：2014-10-02

申请号：US14302903

申请日：2014-06-12

Applicant: TOKUYAMA CORPORATION

Inventor： Naoto TAKAHASHI ,  Katsuhiro MORI

IPC: B29D11/00

CPC classification number: B29D11/00865 ,  B29D11/00903

Abstract: A process is provided whereby a photocurable coating agent is applied to a surface of a plastic lens having a central area less than 2 mm in thickness and thinner than the peripheral area, and the coating agent is cured to produce an objective coated plastic lens without any special cooling apparatus, with high productivity and without deforming the lens. The process for producing a lens includes: holding a lens on a lens holder, the lens having an uncured coating of a photocurable composition on its surface, the lens holder having a lens-contact member composed of an elastic material, the lens-contact member having a surface configuration substantially conforming with a back surface of the lens, the lens being held such that the back surface of the lens is in close contact with the lens-contact part; and curing the uncured coating by irradiation.

Abstract translation: 提供了一种方法，其中将光固化涂层剂施加到具有小于2mm的中心区域并且比周边区域更薄的塑料透镜的表面，并且涂覆剂固化以产生目标涂覆的塑料透镜，而没有任何 特殊冷却装置，生产率高，不会使镜片变形。 制造透镜的方法包括：将透镜保持在透镜支架上，所述透镜在其表面上具有未固化的可光固化组合物的涂层，所述透镜保持器具有由弹性材料构成的透镜接触构件，所述透镜接触构件 具有基本上与透镜的背面一致的表面形状，透镜被保持使得透镜的后表面与透镜接触部分紧密接触; 并通过照射固化未固化的涂层。

公开(公告)号：US20240241291A1

公开(公告)日：2024-07-18

申请号：US18606814

申请日：2024-03-15

Applicant: TOKUYAMA CORPORATION

Inventor： Katsuhiro MORI ,  Toshimitsu HIRAREN ,  Junji MOMODA

IPC: G02B1/04 ,  B32B7/12 ,  B32B23/08 ,  B32B27/08 ,  B32B27/28 ,  B32B27/30 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  G02C7/02 ,  G02C7/10 ,  G02C7/12

CPC classification number: G02B1/041 ,  B32B7/12 ,  B32B23/08 ,  B32B27/08 ,  B32B27/283 ,  B32B27/306 ,  B32B27/308 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  G02C7/02 ,  G02C7/102 ,  G02C7/12 ,  B32B2250/03 ,  B32B2250/05 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2307/412 ,  B32B2307/42 ,  B32B2551/00

Abstract: A functional lens comprising a functional laminate (A) having a functional layer (Ac) having photochromic properties and/or polarizability between a first optical sheet (Aa) and a second optical sheet (Ab) both made of a resin such as polyamide resin and a synthetic resin layer (B) made of a resin such as allyl resin or polythiourethane resin on the first optical sheet (Aa) and/or the second optical sheet (Ab) of the functional laminate (A) and having an adhesive strength between the first optical sheet (Aa) and/or the second optical sheet (Ab) and the synthetic resin layer (B) of not less than 50 N.

公开(公告)号：US20240182749A1

公开(公告)日：2024-06-06

申请号：US18278324

申请日：2022-03-08

Applicant: TOKUYAMA CORPORATION

Inventor： Taichi HANASAKI ,  Masayuki MIYAZAKI ,  Toshimitsu HIRAREN ,  Katsuhiro MORI ,  Junji MOMODA

IPC: C09D183/10 ,  C08F290/14 ,  C09D7/63 ,  C09K9/02 ,  G02B1/04 ,  G02B5/23

CPC classification number: C09D183/10 ,  C08F290/148 ,  C09D7/63 ,  C09K9/02 ,  G02B1/04 ,  G02B5/23

Abstract: The present invention provides a photochromic curable composition capable of providing a cured product excellent in appearance, a photochromic optical article including the cured product, and a method for producing the same. According to an embodiment, there is provided a photochromic curable composition including (A) a siloxane having an acyclic polysiloxane bond and at least one of a radically polymerizable group and a group reactive with a radically polymerizable group, (B) a radically polymerizable monomer component, and (C) a photochromic compound.