Fixation of nitrogen using silicon oxide catalysts
    15.
    发明授权
    Fixation of nitrogen using silicon oxide catalysts 失效
    使用氧化硅催化剂固氮

    公开(公告)号:US4308246A

    公开(公告)日:1981-12-29

    申请号:US226592

    申请日:1981-01-21

    Applicant: Paul Harteck

    Inventor: Paul Harteck

    CPC classification number: C01B21/48 C01F11/38 C01G1/08

    Abstract: A process for the fixation of nitrogen comprising, combining a gaseous nitrogen and oxygen at a total pressure of above 100 atmospheres with a solid oxide which can produce a nitrate, in the presence of an oxide of silicon catalyst for the acceleration of a reaction between nitrogen and oxygen to produce nitrogen oxides, initially heating the combination to a temperature of between 600.degree. C. to 800.degree. C. and below the dissociation pressure of the nitrate to start an exothermic reaction for producing nitrogen oxides from the nitrogen and oxygen and for producing nitrate from the solid oxide and to establish an equilibrium between the nitrogen, oxygen, nitrogen oxides, solid oxide and nitrate. The reacting combination in equilibrium is then cooled and either the nitrate or the nitrogen oxides are removed from the reaction as products.

    Abstract translation: 一种用于固氮的方法,其包括:在硅催化剂氧化物存在下,将总气压为100多个大气压的气态氮和氧气与可产生硝酸盐的固体氧化物混合,以加速氮气之间的反应 和氧气以产生氮氧化物,最初将组合物加热至600℃至800℃的温度并低于硝酸盐的解离压力,以开始从氮气和氧气产生氮氧化物的放热反应并产生 硝酸盐,固体氧化物和氮,氧,氮氧化物,固体氧化物和硝酸盐之间的平衡。 然后将平衡中的反应组合冷却,并将硝酸盐或氮氧化物作为产物从反应中除去。

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