公开(公告)号：US20140221717A1

公开(公告)日：2014-08-07

申请号：US14252219

申请日：2014-04-14

Applicant: FINA TECHNOLOGY, INC.

Inventor： James R. Butler

IPC: C07C2/66

CPC classification number: C07C2/66 ,  C07C2523/10 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/70 ,  C07C15/073

Abstract: Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a reaction zone containing a gaseous phase and recovering ethylbenzene from the reaction zone.

Abstract translation: 本文描述了形成乙苯的方法。 在一个实施方案中，该方法包括在烷基化催化剂存在下使稀乙烯与苯接触以形成乙苯，其中这种接触在含有气相的反应区中发生并从反应区回收乙苯。

公开(公告)号：US20140154148A1

公开(公告)日：2014-06-05

申请号：US14088108

申请日：2013-11-22

Applicant: FINA TECHNOLOGY, Inc.

Inventor： Joseph E. Pelati ,  James R. Butler ,  Hollie Craig

IPC: B01F5/04

CPC classification number: B01F5/0403 ,  B01B1/005 ,  B01D7/00 ,  B01F5/045 ,  B01J4/001 ,  B01J8/02 ,  B01J38/06 ,  B01J38/64 ,  C07C5/32

Abstract: An apparatus and method for vaporizing and transporting an alkali metal salt is shown. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam forming a solution that can be transported, such as to a remote reaction zone. The solution can be transported via a third conduit that is capable of being heated by a heat source. The method can be used to add a promoter to a dehydrogenation catalyst during a dehydrogenation reaction.

Abstract translation: 示出了用于蒸发和运输碱金属盐的装置和方法。 该设备具有能够输送碱金属盐溶液的第一导管和与第一导管流体连通的第二导管，第二导管能够输送蒸汽，使得碱金属盐被散发到形成可以是 运送到远程反应区。 该溶液可以经由能够被热源加热的第三导管输送。 该方法可用于在脱氢反应期间向脱氢催化剂中加入助催化剂。

公开(公告)号：US20140138870A1

公开(公告)日：2014-05-22

申请号：US14081393

申请日：2013-11-15

Applicant: FINA TECHNOLOGY, INC.

Inventor： Michael McLeod ,  Gerhard Guenther ,  Shannon B. Hoesing

IPC: B29D22/00

CPC classification number: B29D22/003 ,  B29C45/0001 ,  B29C47/0004 ,  B29C47/0014 ,  B29C47/0021 ,  B29C47/0023 ,  B29C47/0026 ,  B29C47/0054 ,  B29C47/0057 ,  B29C47/0059 ,  B29C47/062 ,  B29C47/882 ,  B29C47/884 ,  B29C47/8845 ,  B29C49/0005 ,  B29C49/06 ,  B29C49/08 ,  B29C51/002 ,  B29C55/005 ,  B29C55/04 ,  B29C55/12 ,  B29D23/001 ,  B29K2023/06 ,  B29K2105/08 ,  B29L2007/007 ,  B29L2023/00 ,  B29L2031/7128 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  D01F6/04 ,  Y10T428/1397 ,  C08L2666/06

Abstract: Applicants have discovered that certain polyethylene (PE) homopolymers or copolymers of ethylene and C3 to C10 alpha-olefin monomers are more suitable for oriented processes than other polyethylene resins. In an aspect, the PE has a MFI of 0.3 g/10 min. to 5.0 g/10 min., a melting point of from 110° C. to 140° C., a density of from 0.912 g/cm3 to 0.965 g/cm3(%), a haze of 10% or less, a clarity of at least 90, and a gloss of at least 60. The polyethylene is heated and formed into an article, cooled, and then the article is stretch oriented. In an embodiment, the film, tape, the melt extruded, injection blow molded, injection stretch blow molded, cast, and thermoformed articles that can be produced with this polyethylene has a thickness of 0.1 mil to 100 mils. The polyethylene exhibits excellent elasticity, toughness, stretch and optical properties for such applications.

Abstract translation: 申请人已经发现，乙烯和C 3至C 10α-烯烃单体的某些聚乙烯（PE）均聚物或共聚物比其它聚乙烯树脂更适用于取向过程。 在一方面，PE具有0.3g / 10min的MFI。 至5.0g / 10分钟，熔点为110℃至140℃，密度为0.912g / cm 3至0.965g / cm 3（％），雾度为10％以下，透明度 至少为90，光泽度至少为60.将聚乙烯加热并形成制品，冷却，然后将制品拉伸定向。 在一个实施方案中，可以用该聚乙烯生产的膜，带，熔体挤出，注射吹塑，注射拉伸吹塑，铸造和热成型制品的厚度为0.1密耳至100密耳。 聚乙烯表现出优异的弹性，韧性，拉伸性和光学性能。

公开(公告)号：US20140100337A1

公开(公告)日：2014-04-10

申请号：US14104801

申请日：2013-12-12

Applicant: FINA TECHNOLOGY, INC.

Inventor： Mark Leland

IPC: C08L23/14 ,  C08L23/12

CPC classification number: C08J5/18 ,  B29C45/0001 ,  B29K2021/00 ,  B29K2023/14 ,  B29L2007/002 ,  C08J2323/12 ,  C08J2323/14 ,  C08L23/12 ,  C08L23/14 ,  C08L23/142 ,  C08L23/16 ,  C08L2201/10 ,  C08L2203/16 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2207/02 ,  C08L2308/00 ,  C08L2314/02

Abstract: Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included.

Abstract translation: 通过选择具有第一熔体流动速率的连续相聚合物和选择橡胶相聚合物材料使得冲击共聚物的最终熔体流动速率在第一熔体流动速率的2g / 10min内来制备抗冲共聚物的方法。 还包括由这种方法制成的抗冲共聚物和由这种抗冲共聚物制成的膜和模制品。

公开(公告)号：US20140072746A1

公开(公告)日：2014-03-13

申请号：US14081073

申请日：2013-11-15

Applicant: FINA TECHNOLOGY, INC.

Inventor： Fengkui Li ,  John Ashbaugh ,  David Rauscher ,  Robert Dotter

IPC: C08L67/04 ,  C08L23/12

CPC classification number: C08L67/04 ,  B29C45/0001 ,  B29C47/0004 ,  B29C47/0014 ,  B29C47/0021 ,  B29C47/0023 ,  B29C47/065 ,  B29C49/0005 ,  B29C51/002 ,  B29K2067/046 ,  B32B7/12 ,  B32B27/08 ,  B32B27/32 ,  B32B27/36 ,  B32B2250/24 ,  B32B2270/00 ,  C04B28/18 ,  C04B38/0054 ,  C04B38/0074 ,  C04B40/0245 ,  C08G63/912 ,  C08L15/00 ,  C08L23/10 ,  C08L23/12 ,  F17C11/002 ,  Y10T428/139 ,  Y10T428/31515 ,  Y10T428/31797 ,  C08L23/02

Abstract: Polymeric compositions and processes of forming the same are discussed herein. The processes generally include contacting a polylactic acid with a reactive modifier selected from epoxy-functionalized polybutadiene, ionic monomer, and combinations thereof.

Abstract translation: 本文讨论了聚合物组合物及其形成方法。 方法通常包括使聚乳酸与选自环氧官能化聚丁二烯，离子单体及其组合的反应性改性剂接触。

公开(公告)号：US08653212B2

公开(公告)日：2014-02-18

申请号：US13964781

申请日：2013-08-12

Applicant: Fina Technology, Inc.

Inventor： John Gaustad ,  Juan Aguirre ,  Joe Shuler

IPC: C08F30/04 ,  C08F20/00 ,  C08L33/06

CPC classification number: C08F30/04 ,  C08F212/08 ,  C08F220/06 ,  C08F230/04 ,  C08J5/18 ,  C08J9/00 ,  C08J9/04 ,  C08J2325/14 ,  C08K5/0091 ,  C08L35/06 ,  C08L35/00 ,  C08F220/14 ,  C08F222/10

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

Abstract translation: 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / 10min。 至1.9g / 10分钟。

公开(公告)号：US08623484B2

公开(公告)日：2014-01-07

申请号：US13793743

申请日：2013-03-11

Applicant: Fina Technology, Inc.

Inventor： Luyi Sun

IPC: B29D22/00 ,  B29D23/00 ,  B32B1/08

CPC classification number: B29D22/003 ,  B29C49/0005 ,  B29C49/06 ,  B29K2023/12 ,  B29K2995/0025 ,  B29L2031/7158 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1397 ,  Y10T428/31855

Abstract: Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a propylene-based impact copolymer.

Abstract translation: 注射拉伸吹塑（ISBM）制品及其形成方法在本文中描述。 ISBM制品通常包括丙烯类抗冲共聚物。

公开(公告)号：US20140005454A1

公开(公告)日：2014-01-02

申请号：US14014098

申请日：2013-08-29

Applicant: FINA TECHNOLOGY, INC.

Inventor： James R. Butler ,  Xin Xiao ,  James T. Merrill

IPC: C07C2/66

CPC classification number: C07C2/66 ,  B01J29/06 ,  B01J29/7057 ,  B01J2219/00006 ,  C07C6/126 ,  C07C7/12 ,  C07C15/073 ,  C07C2529/08 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P20/588 ,  C07C15/04

Abstract: Alkylation systems and methods of minimizing alkylation catalyst regeneration are described herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a preliminary alkylation catalyst disposed therein to form a first output stream. The preliminary alkylation catalyst generally includes a zeolite catalyst having a SiO2/Al2O3 ratio of less than about 25. The alkylation systems further include a first alkylation system adapted to receive the first output stream and contact the first output stream with a first alkylation catalyst disposed therein and an alkylating agent to form a second output stream.

Abstract translation: 本文描述了使烷基化催化剂再生最小化的烷基化系统和方法。 烷基化系统通常包括适于接收包含烷基芳族烃的输入流并将输入流与设置在其中的预置烷基化催化剂接触以形成第一输出流的初步烷基化系统。 初步烷基化催化剂通常包括SiO 2 / Al 2 O 3比小于约25的沸石催化剂。烷基化系统还包括适于接收第一输出流并将第一输出流与置于其中的第一烷基化催化剂接触的第一烷基化系统 和烷基化剂以形成第二输出流。

公开(公告)号：US20130331471A1

公开(公告)日：2013-12-12

申请号：US13964781

申请日：2013-08-12

Applicant: Fina Technology, Inc.

Inventor： John Gaustad ,  Juan Aguirre ,  Joe Shuler

IPC: C08F230/04 ,  C08L35/06

CPC classification number: C08F30/04 ,  C08F212/08 ,  C08F220/06 ,  C08F230/04 ,  C08J5/18 ,  C08J9/00 ,  C08J9/04 ,  C08J2325/14 ,  C08K5/0091 ,  C08L35/06 ,  C08L35/00 ,  C08F220/14 ,  C08F222/10

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/min. to 1.9 g/10 min.

Abstract translation: 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / min。 至1.9g / 10分钟。

公开(公告)号：US20130210948A1

公开(公告)日：2013-08-15

申请号：US13754036

申请日：2013-01-30

Applicant: FINA TECHNOLOGY, INC.

Inventor： Camille Grossetete ,  David W. Knoeppel ,  Jose M. Sosa ,  Shane Steagall ,  Carlos Corletto

IPC: C08L25/06

CPC classification number: C08L25/06 ,  C08L2205/02 ,  C08L2207/20

Abstract: A method of preparing a polystyrene blend that includes combining a first polystyrene composition having a first melt flow index with a second polystyrene composition having a second melt flow index and forming a polystyrene blend, the second melt flow index being at least 2 dg/min higher that the first melt flow index. The polystyrene blend has an observed tensile strength value greater than 3% above the expected tensile strength value. The second polystyrene composition can include a recycled polystyrene material, which can include expanded polystyrene. An alternate method of preparing the polystyrene blend includes combining a polystyrene composition with a styrene monomer to form a reaction mixture, polymerizing the reaction mixture and obtaining a polystyrene blend, where the polystyrene containing composition has a melt flow index at least 2 dg/min higher than the melt flow index of the styrene monomer after it has been polymerized.

Abstract translation: 一种制备聚苯乙烯共混物的方法，其包括将具有第一熔体流动指数的第一聚苯乙烯组合物与具有第二熔体流动指数的第二聚苯乙烯组合物组合并形成聚苯乙烯共混物，所述第二熔体流动指数至少为2dg / min 第一个熔体流动指数。 聚苯乙烯共混物的观测拉伸强度值大于预期拉伸强度值的3％以上。 第二聚苯乙烯组合物可以包括再循环的聚苯乙烯材料，其可以包括发泡聚苯乙烯。 制备聚苯乙烯共混物的替代方法包括将聚苯乙烯组合物与苯乙烯单体组合以形成反应混合物，使反应混合物聚合并获得聚苯乙烯共混物，其中含聚苯乙烯的组合物的熔体流动指数至少为2dg / min 比苯乙烯单体聚合后的熔体流动指数高。