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21.发明授权Hydrocarbon conversion processes using a novel crystalline microporous metal oxysulfide composition 失效使用新的结晶微孔金属氧硫化物组合物的烃转化方法
公开(公告)号：US5128025A
公开(公告)日：1992-07-07
申请号：US803936
申请日：1991-12-09
CPC分类号： B01J29/85 , B01J29/005 , C01B33/2884 , B01J29/84
摘要： This invention deals with a hydrocarbon conversion process using a crystalline oxysulfide composition. The crystalline oxysulfide composition has a three-dimensional microporous framework structure of at least MO.sub.2, MS.sub.2, and MOS tetrahedral units, having an intracrystalline pore system and an empirical formula expressed in molar ratios:(M.sub.s Al.sub.t P.sub.u Si.sub.v)S.sub.w O.sub.2-wwhere M is at least one metal selected from the group consisting of metals which: 1) can be incorporated into the framework structure of a microporous molecular sieve and 2) form hydrolytically stable sulfides; s, t, u, v and w are the mole fractions of M, Al, P, Si and S respectively. The values of s, t, u and v are chosen such that when t is greater than zero u is greater than zero, s+t+u+v=1 and when s=1, M is only a combination of gallium and germanium.
摘要翻译： 本发明涉及使用结晶氧硫化物组合物的烃转化方法。 结晶氧硫化物组合物具有至少具有MO2，MS2和MOS四面体单元的三维微孔骨架结构，具有结晶孔系统和以摩尔比表示的经验式：（MsAltPuSiv）SwO 2 -w，其中M为至少一个 选自以下的金属的金属：1）可以结合到微孔分子筛的骨架结构中，2）形成水解稳定的硫化物; s，t，u，v和w分别是M，Al，P，Si和S的摩尔分数。 选择s，t，u和v的值，使得当t大于零时，u大于零，s + t + u + v = 1，当s = 1时，M只是镓和锗的组合 。
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22.发明授权Process for separating a mixture of molecular species using crystalline microporous metal sulfide compositions 失效使用结晶微孔金属硫化物组合物分离分子物质的混合物的方法
公开(公告)号：US5013337A
公开(公告)日：1991-05-07
申请号：US507819
申请日：1990-04-12
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82 , Y10S95/902
摘要： This invention relates to a process for separating a mixture of molecular species based on the molecular size (kinetic diameter) or on the degree of polarity of the molecular species using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. A composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium may also be used in the process.
摘要翻译： 本发明涉及使用具有MA2单元的三维微孔结构的结晶组合物，基于分子大小（动力学直径）或分子物质的极性的程度来分离分子种类的混合物的方法，其中A是硫 或硒，并具有以摩尔比表示的经验式：xR：MA2 +/- 0.2：zH2O其中R表示晶体内孔体系中存在的至少一种有机模板剂，x是R的摩尔数，z是水的摩尔数， M是锗或锡。 具有以摩尔比表示的经验式的组合物：xR：M1-yM'yA2 +/- 0.2：zH2O，其中M'是诸如钴，锌，锰，铁，镍，铜，镉和镓的金属也可以是 在过程中使用。
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23.发明授权
公开(公告)号：US4973460A
公开(公告)日：1990-11-27
申请号：US218494
申请日：1988-07-06
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of LiO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of lithium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有LiO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（LiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（LiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锂，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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24.发明授权
公开(公告)号：US4917876A
公开(公告)日：1990-04-17
申请号：US195474
申请日：1988-05-17
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of FeO.sub.2, TiO.sub.2, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and titanium, "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represnt the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有FeO 2，TiO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和钛，“m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4861743A
公开(公告)日：1989-08-29
申请号：US126192
申请日：1987-11-25
CPC分类号： C01B37/08 , B01J29/84 , C01B37/04 , C01B37/06 , B01J2229/64
摘要： Non-zeolitic molecular sieves are prepared by contacting a body of alumina or silica-alumina (optionally containing reactive sources of phosphorus pentoxide and/or other elements desired in the non-zeolitic molecular sieve) with a liquid reaction mixture containing a reactive source of phosphorus pentoxide (and optionally reactive sources of silica and/or other elements desired in the non-zeolitic molecular sieve), and an organic templating agent, thereby causing the body to react with the liquid reaction mixture and to form crystals of the non-zeolitic molecular sieve within the body.
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公开(公告)号：US4788380A
公开(公告)日：1988-11-29
申请号：US81680
申请日：1987-08-05
IPC分类号： C10G11/05 , B01J20060101 , B01J29/70 , B01J29/89 , B01J31/02 , C01B39/04 , C01B39/06 , C07B61/00 , C07C1/00 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/41 , C07C67/00 , C10G35/095 , C10G49/08 , C07C7/13
CPC分类号： C01B39/065 , B01J29/89 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/222 , C07C5/41 , C07C2529/89
摘要： Titanium-aluminum-silicon-oxide molecular sieves are disclosed having use as molecular sieves and as catalyst compositions in hydrocarbon conversion and other processes. The molecular sieves have a unit empirical formula on an anhydrous basis ofmR: (Ti.sub.x Al.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic+ emplating agent; "m" represents the moles of "R" present per mole of (Ti.sub.x Al.sub.y Si.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of titanium, aluminum and silicon, respectively, present as tetrahedral oxides. The molecular sieve is useful in separating molecular species having different degrees of polarity and/or kinetic diameters.
摘要翻译： 公开了钛 - 铝 - 氧化硅分子筛，其用作分子筛和用作烃转化和其它方法中的催化剂组合物。 分子筛具有无水基于mR：（TixAlySiz）O 2的单位经验式，其中“R”表示至少一种有机+表面活性剂; “m”表示每摩尔（TixAlySiz）O 2存在的“R”摩尔数; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的钛，铝和硅的摩尔分数。 分子筛可用于分离具有不同极性和/或动力学直径的分子种类。
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公开(公告)号：US4765458A
公开(公告)日：1988-08-23
申请号：US919083
申请日：1986-10-14
申请人： Edith M. Flanigen
发明人： Edith M. Flanigen
CPC分类号： C04B38/0051 , C04B28/18 , F17C11/002 , C04B2111/12
摘要： A calcium silicate filler mass for use in storing a gas solution or liquid gas, said filler mass having a high compressive strength and containing at least 0.5 weight percent reinforcing carbon fibers uniformly disposed within said calcium silicate, said filler having uniformly distributed throughout very fine pores of less than about 25 microns, and being substantially absent of voids and having a porosity of at least about 85%. There is also disclosed an acetylene storage vessel for storing gas solutions of acetylene which includes said silicate filler mass disposed within a metal shell and a method of forming said acetylene storage vessel.
摘要翻译： 一种用于储存气体溶液或液体气体的硅酸钙填料，所述填料具有高抗压强度，并且含有均匀地设置在所述硅酸钙内的至少0.5重量％的增强碳纤维，所述填料均匀分布在非常细的孔中 小于约25微米，并且基本上不存在空隙并具有至少约85％的孔隙率。 还公开了一种用于储存乙炔气体溶液的乙炔储存容器，其包括设置在金属壳内的所述硅酸盐填料块和形成所述乙炔储存容器的方法。
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公开(公告)号：US4759919A
公开(公告)日：1988-07-26
申请号：US830756
申请日：1986-02-19
CPC分类号： B01J29/84 , C01B39/00 , C07C2527/173 , C07C2529/84
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of CrO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Cr.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Cr.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of chromium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CrO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（CrxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CrxAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的铬，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4211760A
公开(公告)日：1980-07-08
申请号：US18074
申请日：1979-03-06
申请人： Robert W. Grose , Edith M. Flanigen
发明人： Robert W. Grose , Edith M. Flanigen
CPC分类号： B01D53/28 , C01B33/2869 , C01B33/2884 , C01B33/2892
摘要： A novel zeolitic molecular sieve composition denominated Upsilon is synthesized from aqueous gels in the Na.sub.2 O--Al.sub.2 O.sub.3 --SiO.sub.2 system. The molecular sieve has a pore diameter of about 3.5 Angstroms, a characteristic x-ray diffraction pattern and a composition expressed in moles of oxides as:Na.sub.2 O.Al.sub.2 O.sub.3.2.4-3.4 SiO.sub.2.O-4.5 H.sub.2 O
摘要翻译： 一种名为Upsilon的沸石分子筛组合物，由Na2O-Al2O3-SiO2体系中的水凝胶合成。 分子筛具有约3.5埃的孔径，特征x射线衍射图和以氧化物摩尔数表示的组成：Na2O.Al2O3.2.4-3.4SiO2.O-4.5H2O
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公开(公告)号：US4124686A
公开(公告)日：1978-11-07
申请号：US853762
申请日：1977-11-21
申请人： Robert W. Grose , Edith M. Flanigen
发明人： Robert W. Grose , Edith M. Flanigen
IPC分类号： C10G11/02 , B01J29/70 , B01J29/74 , C01B39/04 , C01B39/48 , C10G11/00 , C01B33/28 , C07F5/06
摘要： A novel synthetic crystalline zeolite denominated zeolite "Phi" is prepared hydrothermally from aqueous gels in the [N(CH.sub.3).sub.4 ].sub.2 O - Na.sub.2 O - Al.sub.2 O.sub.3 - SiO.sub.2 system. As synthesized, the zeolite exhibits large-pore adsorption characteristics, a characteristic X-ray powder diffraction pattern and a composition expressed in moles of oxides as: 0.95-1.05 Na.sub.2 0:0.02-0.05 {N(CH.sub.3).sub.4 }.sub.2 O:Al.sub.2 O.sub.3 :4-7 SiO.sub.2 :O-6 H.sub.2 O.
摘要翻译： 通过[N（CH 3）4] 2 O - Na 2 O-Al 2 O 3 -SiO 2体系中的水凝胶水热制备新型合成结晶沸石“Phi”。 合成时，沸石表现出大孔吸附特性，特征X射线粉末衍射图和以氧化物摩尔数表示的组成：0.95-1.05 Na 2 O：0.02-0.05 {N（CH 3）4} 2 O：Al 2 O 3：4 -7 SiO2：O-6H2O。
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