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公开(公告)号：US06573353B1
公开(公告)日：2003-06-03
申请号：US09660578
申请日：2000-09-12
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Daniel Joseph Tempel
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Daniel Joseph Tempel
IPC分类号： C08F1006
CPC分类号： C08F110/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5916989A
公开(公告)日：1999-06-29
申请号：US891472
申请日：1997-07-10
申请人： Maurice S. Brookhart, III , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain
发明人： Maurice S. Brookhart, III , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是关于它们的微结构，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5880241A
公开(公告)日：1999-03-09
申请号：US590650
申请日：1996-01-24
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Steven Dale Ittel , Daniel Joseph Tempel
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Steven Dale Ittel , Daniel Joseph Tempel
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是关于它们的微结构，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US5866663A
公开(公告)日：1999-02-02
申请号：US891332
申请日：1997-07-10
申请人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
发明人： Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
IPC分类号： B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号： C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译： 本文公开了聚合乙烯，无环烯烃和/或选择的环烯烃，和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物，有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性，因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的，特别是在它们的微结构方面，这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂，以及一些制备它们的新方法。 制备的聚合物可用作弹性体，模塑树脂，粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃，将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸，或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号：US20120062228A1
公开(公告)日：2012-03-15
申请号：US13300784
申请日：2011-11-21
IPC分类号： G01R33/46 , C08G63/183 , C08G64/00 , C08L77/00 , C09D177/00 , C08L33/10 , C08L33/08 , C08L27/06 , C08L67/00 , C08L25/06 , C08G69/48 , C08L33/12
摘要： This invention relates to the preparation of polyamide block copolymers by sequential monomer addition. More particularly, it relates to catalysts capable of copolymerizing not only cyclic amides, but other monomers such as cyclic esters and epoxides as well, using sequential addition so as to produce useful and novel block copolymers.
摘要翻译： 本发明涉及通过连续单体添加制备聚酰胺嵌段共聚物。 更具体地说，本发明涉及能够不仅使环状酰胺，也可以使其它单体例如环状酯和环氧化物共聚的催化剂，这些催化剂也使用顺序加成来生产有用和新的嵌段共聚物。
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公开(公告)号：US08697816B2
公开(公告)日：2014-04-15
申请号：US13291673
申请日：2011-11-08
IPC分类号： C08G81/00
CPC分类号： D01F6/84
摘要： Disclosed are shaped articles fabricated from polymer blends comprising a fluorinated block copolyester and a non-fluorinated polyester wherein the fluorinated block copolyester comprises blocks of fluoroether modified aromatic polyester and blocks of unmodified polyester. Suitable block copolyesters have a blockiness index, B, in the range of 0.25 to 1.0. Shaped articles that can be made from the copolyesters include films, fibers, and molded parts.
摘要翻译： 公开的是由包含氟化嵌段共聚酯和非氟化聚酯的聚合物共混物制成的成型制品，其中氟化嵌段共聚酯包含氟醚改性芳族聚酯嵌段和未改性聚酯嵌段。 合适的嵌段共聚酯的嵌段指数B在0.25-1.0的范围内。 可以由共聚酯制成的成型制品包括膜，纤维和模制件。
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公开(公告)号：US07041764B2
公开(公告)日：2006-05-09
申请号：US10919181
申请日：2004-08-16
IPC分类号： C08F210/16 , C08F4/80 , C08F4/70
CPC分类号： C08F10/00 , C08F210/16 , C08F210/14 , C08F2500/04 , C08F2500/02 , C08F2500/10 , C08F4/7042
摘要： Ethylene and/or propylene, and α-olefins may be copolymerized by contacting then with certain iron or cobalt complexes of selected 2,6-pyridinecarboxaldehydebis(imines) and 2,6-diacylpyridinebis(imines). The polymers produced, some of which are novel, are useful as molding resins.
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公开(公告)号：US06699955B1
公开(公告)日：2004-03-02
申请号：US09712673
申请日：2000-11-14
IPC分类号： C08F3620
CPC分类号： C08F210/02 , C08F10/00 , C08F210/18 , C08F236/20 , C08F2500/05 , C08F4/7042
摘要： Ethylene, dienes and optionally &agr;-olefins are copolym-erized by selected iron complexes of 2,6-pyridinecarbox-aldehydebis(imines) and 2,6-diacylpyridinebis(imines). The resulting copolymers contain residual olefinic unsaturation from the diene monomers, and some of these copolymers contain cyclic units in the main chain.
摘要翻译： 乙烯，二烯和任选的α-烯烃由选择的2,6-吡啶甲醛 - 二（亚胺）和2,6-二酰基吡啶双（亚胺）的铁络合物共聚。 所得共聚物含有来自二烯单体的残余烯属不饱和度，并且这些共聚物中的一些在主链中含有环状单元。
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公开(公告)号：US20130116390A1
公开(公告)日：2013-05-09
申请号：US13291673
申请日：2011-11-08
IPC分类号： C08G81/00
CPC分类号： D01F6/84
摘要： Disclosed are shaped articles fabricated from polymer blends comprising a fluorinated block copolyester and a non-fluorinated polyester wherein the fluorinated block copolyester comprises blocks of fluoroether modified aromatic polyester and blocks of unmodified polyester. Suitable block copolyesters have a blockiness index, B, in the range of 0.25 to 1.0. Shaped articles that can be made from the copolyesters include films, fibers, and molded parts.
摘要翻译： 公开的是由包含氟化嵌段共聚酯和非氟化聚酯的聚合物共混物制成的成型制品，其中氟化嵌段共聚酯包含氟醚改性芳族聚酯嵌段和未改性聚酯嵌段。 合适的嵌段共聚酯的嵌段指数B在0.25-1.0的范围内。 可以由共聚酯制成的成型制品包括膜，纤维和模制件。
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公开(公告)号：US6100350A
公开(公告)日：2000-08-08
申请号：US125466
申请日：1998-08-19
IPC分类号： C08F2/00 , C08F2/38 , C08F2/42 , C08F16/14 , C08F18/04 , C08F20/00 , C08F290/02 , C08F290/04 , C08G83/00
CPC分类号： C08G83/003 , C08F2/38 , C08F290/04
摘要： This invention relates to a process for the synthesis of addition polymers containing branches upon branches and having a polymerizable olefin end group by a convenient one-pot copolymerization of selected vinyl monomers with chain polymerization initiators and a method to provide olefin end groups by chain transfer or termination agents; and polymers produced thereby.
摘要翻译： PCT No.PCT / US97 / 02913 Sec。 371日期1998年8月19日 102（e）1998年8月19日PCT PCT 1997年2月18日提交PCT公布。 公开号WO97 / 31031 日期：1997年8月28日本发明涉及一种通过方便的选择的乙烯基单体与链聚合引发剂的一锅共聚合成含有支链上含有支链并具有可聚合烯烃端基的加成聚合物的方法和提供烯烃末端的方法 链转移或终止剂; 和由此生产的聚合物。
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