公开(公告)号：US5357908A

公开(公告)日：1994-10-25

申请号：US49098

申请日：1993-04-16

申请人： Shiang Sung ,  John J. Steger ,  Joseph C. Dettling ,  Patrick L. Burk

发明人： Shiang Sung ,  John J. Steger ,  Joseph C. Dettling ,  Patrick L. Burk

IPC分类号： F02M1/16 ,  F02M25/00 ,  F02M27/02 ,  F02M31/10 ,  F02M31/16 ,  F02M31/18 ,  F02B43/08

CPC分类号： F02M31/10 ,  F02M1/165 ,  F02M27/02 ,  F02M31/18 ,  Y02T10/126

摘要： A method for controlling exhaust gas emissions from an engine (16) includes extracting a light distillate fuel (Fd) from conventional gasoline or other liquid hydrocarbon fuel and supplying the engine with the light distillate fuel during an initial operation period of the engine. This reduces the oxidizable pollutants in the engine exhaust during a cold-start period before a catalytic converter (22) used to abate pollutants in the engine exhaust gases has not yet attained its operating temperature. After the catalytic converter (22) has been sufficiently heated, the fuel supply to the engine (16) is switched to gasoline or other liquid hydrocarbon fuel. Both the distillate fuel (Fd) and the liquid hydrocarbon fuel may be passed through a heated cracking catalyst bed (30) to crack the fuel fed to the engine.

摘要翻译： 用于控制来自发动机（16）的废气排放的方法包括在常规汽油或其它液态烃燃料中提取轻馏分燃料（Fd）并在发动机的初始运行期间向发动机供应轻馏分燃料。 在用于消除发动机废气中的污染物的催化转化器（22）尚未达到其工作温度之前，这在冷启动期间减少了发动机排气中的可氧化污染物。 在催化转化器（22）已被充分加热之后，向发动机（16）的燃料供应被切换到汽油或其它液态烃燃料。 馏出燃料（Fd）和液体烃燃料都可以通过加热的裂化催化剂床（30），以破坏供给发动机的燃料。

公开(公告)号：US4716139A

公开(公告)日：1987-12-29

申请号：US846219

申请日：1986-03-31

申请人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  John J. Steger ,  Angelo A. Montagna

发明人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  John J. Steger ,  Angelo A. Montagna

IPC分类号： B01J27/047 ,  C10G49/04 ,  B01J31/00 ,  B01J27/049 ,  B01J27/051

CPC分类号： B01J27/047 ,  C10G49/04

摘要： A catalyst composition comprising an amorphous sulfide of trivalent chromium and at least one metal selected from the group consisting of (a) molybdenum, tungsten and mixture thereof and (b) mixtures of (a) with Fe, Ni, Co, Mn, Cu, Zn and mixture thereof is prepared by heating one or more precursors at a temperature of at least about 200.degree. C. under oxygen-free conditions in the presence of a sulfur, wherein said precursor is selected from the group consisting of [Cr.sub.1-z M.sub.z LX.sub.y ](MoS.sub.4).sub.n, [Cr.sub.1-z M.sub.z LX.sub.y ](WS.sub.4).sub.n and mixtures thereof, wherein M is one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein L is one or more neutral nitrogen-containing ligands, wherein ligand X is a singly-charged anionic species and wherein 1>z.gtoreq.0, 1-z.gtoreq.y.gtoreq.0, and wherein n equals (3-z-y)/2. These compositions have been found to be good hydroprocessing catalysts, particularly hydrotreating catalysts exhibiting a very high hydrodenitrogenation activity and/or selectivity in nitrogen and sulfur-containing hydrocarbon feeds.

摘要翻译： 一种催化剂组合物，其包含三价铬的无定形硫化物和选自（a）钼，钨及其混合物的至少一种金属和（b）（a）与Fe，Ni，Co，Mn，Cu， Zn及其混合物通过在无硫条件下在硫存在下在至少约200℃的温度下加热一种或多种前体而制备，其中所述前体选自[Cr1-zMzLXy] （MoS4）n，[Cr1-zMzLXy]（WS4）n及其混合物，其中M是一种或多种选自Mn，Fe，Co，Ni，Cu，Zn的二价助催化剂金属及其混合物，其中L 是一种或多种中性含氮配体，其中配体X是单电荷阴离子物质，并且其中n等于（3-zy） ）/ 2。 已经发现这些组合物是良好的加氢处理催化剂，特别是在含氮和含硫烃进料中表现出非常高的加氢脱氮活性和/或选择性的加氢处理催化剂。

公开(公告)号：US4648960A

公开(公告)日：1987-03-10

申请号：US837780

申请日：1986-03-10

申请人： Kenneth R. Poeppelmeier ,  Walter G. Funk ,  John J. Steger ,  Shun C. Fung ,  Virginia R. Cross ,  Jar-Lin Kao

发明人： Kenneth R. Poeppelmeier ,  Walter G. Funk ,  John J. Steger ,  Shun C. Fung ,  Virginia R. Cross ,  Jar-Lin Kao

IPC分类号： B01J29/62 ,  C10G35/06 ,  C10G35/095

CPC分类号： C10G35/095 ,  B01J29/62 ,  B01J2229/26 ,  B01J2229/42

摘要： A class of bound catalysts which exhibit superior activity maintenance in dehydrocyclization reactions are defined as a type L zeolite having exchangeable cations of which at least 75% are selected from Group IA and calcium and barium cations and containing well dispersed particles of at least one Group VIII noble metal where at least 90% of the noble metal thereof is dispersed in the form of particles having a diameter less than 7 .ANG.. The catalysts may also be identified as type L zeolites loaded with at least one Group VIII noble metal which have a terminal cracking index (as a measure of production of pentanes versus butanes from hexane) of at least 1.5.

摘要翻译： 在脱氢环化反应中表现出优异的活性维持性的一类结合的催化剂定义为具有可交换阳离子的L型沸石，其中至少75％选自IA族和钙和钡阳离子，并且含有至少一种VIII族的良好分散的颗粒 贵金属，其中至少90％的贵金属以直径小于7安士的颗粒形式分散。 催化剂也可以被鉴定为负载有至少一种VIII族贵金属的L型沸石，其具有至少1.5的末端裂解指数（作为戊烷与己烷的丁烷的生成量的量度）。

公开(公告)号：US4224182A

公开(公告)日：1980-09-23

申请号：US18188

申请日：1979-03-07

申请人： Arthur W. Langer, Jr. ,  John J. Steger ,  Terry J. Burkhardt

发明人： Arthur W. Langer, Jr. ,  John J. Steger ,  Terry J. Burkhardt

IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/60 ,  C08F10/00 ,  C08F4/64

CPC分类号： C08F10/00 ,  C08F4/022 ,  B01J2531/0288 ,  B01J27/135 ,  B01J31/02 ,  B01J31/0201 ,  B01J31/0252 ,  B01J31/143 ,  B01J31/38

摘要： A new catalyst system for alphaolefin type polymerizations, includes at least one hindered alkyl metal amide compound having the formula R'.sub.2 YNR.sub.2 in combination with a Group IVB-VIII transition metal compound on a support and at least one Lewis base wherein R is selected from the group consisting of C.sub.4 to C.sub.20 bulky alkyl, cycloalkyl, aralkyl, aryl and substituted aryl groups or R.sub.2 N is a hindered cyclic amide group; R' is selected from the group consisting of C.sub.1 to C.sub.20 primary alkyl, secondary alkyl, tertiary alkyl, neopentyl alkyl, branched alkyl, cycloalkyl or aralkyl groups, and Y is selected from the group consisting of aluminum, gallium or indium. The catalyst system provides polymers having increased isotactic stereoregularity as well as lower catalyst residue.

摘要翻译： 用于α-烯烃型聚合的新的催化剂体系包括至少一种具有式R'2YNR2的受阻烷基金属酰胺化合物与载体上的IVB-VIII族过渡金属化合物和至少一种路易斯碱，其中R选自 由C4〜C20大体积烷基，环烷基，芳烷基，芳基和取代芳基组成的基团或R2N是受阻环酰胺基; R'选自C1至C20伯烷基，仲烷基，叔烷基，新戊基烷基，支链烷基，环烷基或芳烷基，Y选自铝，镓或铟。 催化剂体系提供具有增加的全同立构立构规整性以及较低催化剂残余物的聚合物。

公开(公告)号：US08372477B2

公开(公告)日：2013-02-12

申请号：US12793586

申请日：2010-06-03

申请人： Mark T. Buelow ,  Laif R. Alden ,  John Kauffman ,  John J. Steger ,  William McMaster ,  Zhenguo Liu ,  Raghuram Gummaraju

发明人： Mark T. Buelow ,  Laif R. Alden ,  John Kauffman ,  John J. Steger ,  William McMaster ,  Zhenguo Liu ,  Raghuram Gummaraju

IPC分类号： B01D53/04 ,  F02M25/08

CPC分类号： B01J20/3223 ,  B01D2259/4516 ,  B01D2259/4591 ,  B01J20/103 ,  B01J20/18 ,  B01J20/20 ,  B01J20/226 ,  B01J20/321 ,  B01J20/3212 ,  B01J20/3234 ,  B01J20/3238 ,  B01J20/324 ,  B01J23/34 ,  B01J23/40 ,  B01J31/06 ,  B01J35/004 ,  B01J37/0219

摘要： A method of adhering a particulate material, such as a hydrocarbon adsorbent material and/or a catalytic material, to a plastic surface, and products comprising the adhered material are disclosed.

摘要翻译： 公开了一种将诸如烃类吸附剂材料和/或催化材料的颗粒材料粘附到塑料表面的方法，以及包含粘附材料的产品。

公开(公告)号：US06237575B1

公开(公告)日：2001-05-29

申请号：US09288243

申请日：1999-04-08

申请人： Jordan K. Lampert ,  Andrian I. Kouznetsov ,  Jacob Y. Wong ,  Ronald M. Heck ,  John J. Steger ,  Arthur Bruce Robertson ,  Jeff H. Moser

发明人： Jordan K. Lampert ,  Andrian I. Kouznetsov ,  Jacob Y. Wong ,  Ronald M. Heck ,  John J. Steger ,  Arthur Bruce Robertson ,  Jeff H. Moser

IPC分类号： F02M2508

CPC分类号： F02D41/0042 ,  F02D41/0045 ,  F02M25/08

摘要： A pre-vaporized fuel system for use in fueling an internal combustion engine is provided with a dynamic infrared sensor. The infrared sensor senses the hydrocarbon content of the vaporized fuel which information is used by the engine control module to control engine fueling to minimize emissions. The infrared source is operated to maintain the pre-vaporized fuel below its lower explosive limit and the thermopile detector electronics is synchronized with the light pulse frequency to develop fast signal responses suitable for fueling control.

摘要翻译： 用于燃料内燃机的预蒸发燃料系统设置有动态红外传感器。 红外传感器感测汽化燃料的烃含量，该信息由发动机控制模块用于控制发动机加油以最小化排放。 操作红外源以将预蒸发的燃料保持在其较低的爆炸极限以下，并且热电堆检测器电子设备与光脉冲频率同步，以开发适合于加油控制的快速信号响应。

公开(公告)号：US5981427A

公开(公告)日：1999-11-09

申请号：US706480

申请日：1996-09-04

申请人： Shiang Sung ,  Rudolf M. Smaling ,  John J. Steger

发明人： Shiang Sung ,  Rudolf M. Smaling ,  John J. Steger

IPC分类号： B01J23/40 ,  B01D53/94 ,  B01J23/58 ,  B01J23/63 ,  B01J23/89 ,  B01J35/00 ,  B01J37/02 ,  B01J37/03 ,  B01J23/00

CPC分类号： B01D53/945 ,  B01J23/63 ,  B01J35/0006 ,  B01J37/0215 ,  B01J37/038 ,  Y02T10/22

摘要： A catalyst composition comprising at least one first support, at least one first precious metal component, at least one second support, and at least one second precious metal component. The total amount of the first precious metal component comprises from 1 to 99 weight percent based on the total of the first and second precious metal components. The average particle size of the second support is greater than the average particle size of the first support. The present invention includes a method to prepare the catalyst composition and a method to use the catalyst composition as a three-way catalyst. The composition results in a coated layer from a slurry where the more supported first precious metal component is in the bottom half and more supported second precious metal component is in the top half.

摘要翻译： 一种催化剂组合物，其包含至少一种第一载体，至少一种第一贵金属组分，至少一种第二载体和至少一种第二贵金属组分。 基于第一和第二贵金属组分的总和，第一贵金属组分的总量为1至99重量％。 第二载体的平均粒径大于第一载体的平均粒径。 本发明包括制备催化剂组合物的方法和使用催化剂组合物作为三元催化剂的方法。 组合物得到来自浆料的涂层，其中较为支撑的第一贵金属组分在下半部分中，并且更多支持的第二贵金属组分在上半部分。

公开(公告)号：US5419121A

公开(公告)日：1995-05-30

申请号：US48496

申请日：1993-04-16

申请人： Shiang Sung ,  John J. Steger ,  Joseph C. Dettling ,  Patrick L. Burk

发明人： Shiang Sung ,  John J. Steger ,  Joseph C. Dettling ,  Patrick L. Burk

IPC分类号： F01N3/02 ,  F01N3/20 ,  F01N3/26 ,  F01N3/28 ,  F01N3/30 ,  F01N3/32 ,  F01N3/36

CPC分类号： F01N3/306 ,  F01N3/02 ,  F01N3/2033 ,  F01N3/26 ,  F01N3/2807 ,  F01N3/36 ,  F01N2240/14 ,  F01N2240/20 ,  F01N2610/10 ,  F01N3/32 ,  Y02T10/26

摘要： A method of improving the performance of a pollutant abatement means, e.g., catalytic converter (16), used to purify engine exhaust gas streams and the like includes combusting a combustion mixture of air and a low ignition temperature fuel in the exhaust gas stream upstream of the catalytic converter (16) to oxidize carbon monoxide and unburned hydrocarbons, and/or to rapidly heat the catalytic converter to its operating temperature. Reaction conditions are maintained so as to cause the combustion mixture to ignite spontaneously. A control system may be used to regulate the supply of the combustion mixture in response to time lapse or temperature of the catalyst or both. The apparatus includes a fuel supply (18) and a fuel line (20) controlled by a valve (22) to deliver a low ignition temperature fuel into the exhaust gas discharge line (14) associated with the engine (12). An air pump (26) provides combustion air through an air line (28) into the exhaust gas discharge line (14). Optionally, a thermocouple (36) attached to the catalytic converter (16) signals a controller (38) to reduce or stop the flow of air and/or low ignition temperature fuel in response to the temperature of the catalytic converter (16).

摘要翻译： 改善污染物减排性能的方法，例如用于净化发动机废气流等的催化转化器（16）包括在上游的废气流中燃烧空气和低点火温度燃料的燃烧混合物 催化转化器（16）以氧化一氧化碳和未燃烧的烃，和/或将催化转化器快速加热到其工作温度。 维持反应条件以使燃烧混合物自发点燃。 可以使用控制系统来响应于催化剂的时间流逝或温度或二者调节燃烧混合物的供应。 该装置包括由阀（22）控制的燃料供应（18）和燃料管路（20），以将低点火温度燃料输送到与发动机（12）相关联的废气排放管线（14）中。 空气泵（26）通过空气管路（28）将燃烧空气提供到废气排放管线（14）中。 可选地，附接到催化转化器（16）的热电偶（36）响应于催化转化器（16）的温度发信号通知控制器（38）以减少或停止空气流和/或低点燃温度燃料。

公开(公告)号：US4824820A

公开(公告)日：1989-04-25

申请号：US100479

申请日：1987-09-24

申请人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  John J. Steger ,  Angelo A. Montagna

发明人： Allan J. Jacobson ,  Teh C. Ho ,  Russell R. Chianelli ,  John J. Steger ,  Angelo A. Montagna

IPC分类号： B01J27/047 ,  C10G49/04

CPC分类号： B01J27/047 ,  C10G49/04

摘要： A composition of matter comprising a mixture of (i) a sulfide of at least one promoter metal selected from the group consisting of Ni, Co, Mn, Cu, Zn and mixture thereof and mixtures thereof with Fe, (ii) an amorphous sulfide of trivalent chromium and (iii) microcrystallites of metal sulfide of a metal selected from the group consisting of molybdenum, tungsten and mixture thereof. These compositions have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts such as cobalt-molybdate on alumina.

摘要翻译： 一种物质组合物，其包含（i）选自Ni，Co，Mn，Cu，Zn及其混合物中的至少一种助催化剂金属的硫化物及其与Fe的混合物的混合物，（ii） 三价铬和（iii）选自钼，钨及其混合物的金属的金属硫化物的微晶。 已经发现这些组合物是具有优于在氧化铝上的商业催化剂如钼酸钴的除氮活性的有用的加氢处理催化剂。

公开(公告)号：US4267157A

公开(公告)日：1981-05-12

申请号：US103536

申请日：1979-11-14

申请人： Edward T. Maas, Jr. ,  John J. Steger

发明人： Edward T. Maas, Jr. ,  John J. Steger

IPC分类号： C01F5/00 ,  C01F11/00 ,  C01G1/00 ,  C01B25/14

CPC分类号： C01F11/00 ,  C01F5/00 ,  C01G1/00

摘要： A process for producing relatively pure metal phosphorus trisulfides of the formula MPS.sub.3 wherein M is a metal selected from the group consisting of Mg, Ca, Sr, V, Mn, Fe, Co, Ni, Pd, Zn, Cd, Hg, Sn, Pb, Sm, Eu, Yb and mixtures thereof, said process comprising contacting in a reaction zone, phosphides of said metals of the formula M.sub.x P.sub.y, wherein the ratio of y/x ranges between 1/8 to 5/1, with one or more compounds of the formula PS.sub.z wherein z ranges from 1-3 and is preferably 2, said PS.sub.z being present in the reaction zone in an amount sufficient to exceed the amount of P and S stoichiometrically required to form the desired MPS.sub.3, at a temperature ranging from about 300.degree.-600.degree. C. and confined so as to maintain the PS.sub.z present in the reaction zone as a gas in equilibrium with its liquid for a time sufficient to produce said relatively pure metal phosphorus trisulfide.

摘要翻译： 一种制备式MPS3的相对纯的金属磷三硫化物的方法，其中M是选自Mg，Ca，Sr，V，Mn，Fe，Co，Ni，Pd，Zn，Cd，Hg，Sn， Pb，Sm，Eu，Yb及其混合物，所述方法包括在反应区中接触所述式M x P y的金属的磷化物，其中y / x的比例在1/8至5/1之间，与一种或多种 式PSz的化合物，其中z为1-3，优选为2，所述PSz以足以超过形成所需MPS 3的化学计量所需的P和S的量存在于反应区中，温度范围为 约300℃-600℃，并限制在保持反应区中的PSz作为与其液体平衡的气体足以产生所述相对纯的金属磷三硫化物的时间。