FLEXIBLE PROCESS FOR TRANSFORMATION OF ETHANOL INTO MIDDLE DISTILLATES IMPLEMENTING A HOMOGENEOUS CATALYTIC SYSTEM AND A HETEROGENEOUS CATALYTIC SYSTEM
    23.
    发明申请
    FLEXIBLE PROCESS FOR TRANSFORMATION OF ETHANOL INTO MIDDLE DISTILLATES IMPLEMENTING A HOMOGENEOUS CATALYTIC SYSTEM AND A HETEROGENEOUS CATALYTIC SYSTEM 有权
    用于将乙醇转化成中等离子的柔性方法实现均相催化体系和异构催化体系

    公开(公告)号:US20110313221A1

    公开(公告)日:2011-12-22

    申请号:US13102384

    申请日:2011-05-06

    IPC分类号: C07C1/20

    摘要: The invention describes a process for the production of middle distillate hydrocarbon bases from an ethanol feedstock that is produced from a renewable source that is obtained from biomass, comprising a stage for purification of said feedstock, a stage for dehydration of said purified feedstock into an effluent that is for the most part ethylene and comprises water, at least one stage for separating water, a first stage for oligomerization of the effluent that is for the most part ethylene into at least one olefinic effluent that comprises at least 80% by weight of olefins that have four or more carbon atoms, in the presence of a homogeneous catalyst that comprises at least one bivalent nickel compound, whereby a second oligomerization stage produces middle distillate hydrocarbon bases in the presence of an amorphous or zeolitic catalyst that has at least pore openings that contain 10 or 12 oxygen atoms, producing middle distillate hydrocarbon bases, and a fractionation stage.

    摘要翻译: 本发明描述了从由生物质获得的可再生来源生产的乙醇原料生产中间馏分烃碱的方法,其包括用于纯化所述原料的阶段,将所述纯化原料脱水成流出物的步骤 大部分是乙烯并且包括水,至少一个用于分离水的阶段,用于将流出物低聚的第一阶段,其大部分是乙烯至少一种烯烃流出物,其包含至少80重量%的烯烃 在含有至少一种二价镍化合物的均相催化剂的存在下,其具有四个或更多个碳原子,由此第二低聚阶段在无定形或沸石催化剂存在下产生中间馏分烃基,其至少具有孔开口, 含有10或12个氧原子,产生中间馏分烃基和分馏阶段。

    PROCESS FOR THE PRODUCTION OF LIGHT OLEFINS FROM ETHANOL IN THE PRESENCE OF A MACROPOROUS CATALYST THAT COMES IN THE FORM OF BALLS
    24.
    发明申请
    PROCESS FOR THE PRODUCTION OF LIGHT OLEFINS FROM ETHANOL IN THE PRESENCE OF A MACROPOROUS CATALYST THAT COMES IN THE FORM OF BALLS 有权
    在出现爆炸形式的大面积催化剂存在下从乙醇生产轻质烯烃的方法

    公开(公告)号:US20110034750A1

    公开(公告)日:2011-02-10

    申请号:US12851861

    申请日:2010-08-06

    IPC分类号: C07C1/00

    摘要: A process for the production of C3-C6 light olefins from ethanol is described, and said process comprises at least the passage of a feedstock that contains ethanol into at least one reaction unit that is provided with at least one catalyst that comes in the form of spherical balls with a diameter of between 1 and 3 mm, each of said spherical balls comprising at least one zeolite and at least one alumina-based substrate and having a pore distribution such that the macropore volume that is measured by mercury porosimetry is between 0.10 and 0.20 ml/g and the mesopore volume that is measured by mercury porosimetry is between 0.25 and 0.35 ml/g.

    摘要翻译: 描述了从乙醇制备C3-C6轻质烯烃的方法,并且所述方法至少包含含有乙醇的原料通入至少一个反应单元,该反应单元中提供有至少一种催化剂,其形式为 每个所述球形球包含至少一种沸石和至少一种氧化铝基底,并且具有孔分布,使得通过水银孔率法测量的大孔体积在0.10至 0.20ml / g,通过水银孔率法测定的中孔体积为0.25〜0.35ml / g。

    Process for the preparation of magadiite from an organic structuring agent of quaternary diammonium type
    25.
    发明授权
    Process for the preparation of magadiite from an organic structuring agent of quaternary diammonium type 失效
    从季铵盐型有机结构剂制备麦草碱的方法

    公开(公告)号:US07691355B2

    公开(公告)日:2010-04-06

    申请号:US11956820

    申请日:2007-12-14

    IPC分类号: C01B33/26 C01B33/32

    CPC分类号: C01B33/38

    摘要: Described is a process for the preparation of a crystallised lamellar solid formed by magadiite consisting of implementing in a step (i) mixing of at least one silica source, at least one salt of N,N,N′,N′-tetramethyl-N,N′-dibenzyloctanediammonium, at least one alkali and/or alkaline earth metal M and water and then implementing in a step (ii) hydrothermal treatment of said mixture until said crystallised lamellar solid constituted by magadiite is formed.

    摘要翻译: 描述了制备由magadiite形成的结晶层状固体的方法,其包括在步骤(i)中混合至少一种二氧化硅源,至少一种N,N,N',N'-四甲基-N ,N'-二苄基辛烷基铵,至少一种碱金属和/或碱土金属M和水,然后在步骤(ii)中实施所述混合物的水热处理,直到形成由magadiite构成的所述结晶的层状固体。

    Method for synthesizing ZBM-30 zeolite from a mixture of amine compounds
    28.
    发明授权
    Method for synthesizing ZBM-30 zeolite from a mixture of amine compounds 失效
    从胺化合物的混合物合成ZBM-30沸石的方法

    公开(公告)号:US07544347B2

    公开(公告)日:2009-06-09

    申请号:US11337080

    申请日:2006-01-23

    CPC分类号: C01B39/48 B01J29/70

    摘要: The invention concerns a process for the synthesis of solid zeolitic ZBM-30, comprising: i) a mixing step, during which a mixture comprising at least one source of a tetravalent metal, at least one source of a trivalent metal, water and at least two amine compounds is prepared, resulting in the production of a gel; and ii) a crystallization step, during which said gel is maintained under conditions allowing the formation of a crystalline solid. The invention also concerns the zeolite ZBM-30 obtained by said process.

    摘要翻译: 本发明涉及一种合成固体沸石ZBM-30的方法,包括:i)混合步骤,在此期间,将包含至少一种四价金属源,至少一种三价金属源,水和至少 制备两种胺化合物,产生凝胶; 和ii)结晶步骤,其中所述凝胶保持在允许形成结晶固体的条件下。 本发明还涉及通过所述方法获得的沸石ZBM-30。

    Novel method for synthesizing ZBM-30 zeolite from a mixture of amine compounds
    29.
    发明申请
    Novel method for synthesizing ZBM-30 zeolite from a mixture of amine compounds 失效
    从胺化合物的混合物合成ZBM-30沸石的新方法

    公开(公告)号:US20060292070A1

    公开(公告)日:2006-12-28

    申请号:US11337080

    申请日:2006-01-23

    IPC分类号: C01B39/48 C01B39/00 C01B33/36

    CPC分类号: C01B39/48 B01J29/70

    摘要: The invention concerns a process for the synthesis of solid zeolitic ZBM-30, comprising: i) a mixing step, during which a mixture comprising at least one source of a tetravalent metal, at least one source of a trivalent metal, water and at least two amine compounds is prepared, resulting in the production of a gel; and ii) a crystallization step, during which said gel is maintained under conditions allowing the formation of a crystalline solid. The invention also concerns the zeolite ZBM-30 obtained by said process.

    摘要翻译: 本发明涉及一种合成固体沸石ZBM-30的方法,包括:i)混合步骤,在此期间,将包含至少一种四价金属源,至少一种三价金属源,水和至少 制备两种胺化合物,产生凝胶; 和ii)结晶步骤,其中所述凝胶保持在允许形成结晶固体的条件下。 本发明还涉及通过所述方法获得的沸石ZBM-30。