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    Thermoplastic resin composition and injection molded article thereof
    24.
    发明授权
    Thermoplastic resin composition and injection molded article thereof 失效
    热塑性树脂组合物及其注塑制品

    公开(公告)号：US5723527A

    公开(公告)日：1998-03-03

    申请号：US637279

    申请日：1996-04-24

    申请人： Hajime Sadatoshi ,  Kenichi Ohkawa ,  Teruhiko Doi ,  Yuichi Miyake ,  Takao Nomura ,  Takeyoshi Nishio

    发明人： Hajime Sadatoshi ,  Kenichi Ohkawa ,  Teruhiko Doi ,  Yuichi Miyake ,  Takao Nomura ,  Takeyoshi Nishio

    IPC分类号： B29C45/00 ,  B29K23/00 ,  B29K96/04 ,  C08J5/00 ,  C08K3/30 ,  C08K3/32 ,  C08K3/34 ,  C08K7/00 ,  C08K7/04 ,  C08L23/00 ,  C08L23/12 ,  C08L53/00

    CPC分类号： C08L53/00

    摘要： A thermoplastic resin composition which has a melt flow rate of 20 to 30 g/10 min and a flexural modulus at 23.degree. C. of 30,000 kg/cm.sup.2 or more and which comprises (A) 60 to 75% by weight of a specific crystalline polypropylene in which the propylene homopolymer portion has a Q value of 3.0 to 5.0, an isotactic pentad fraction of 0.975 or more and an intrinsic viscosity �.eta.! of 0.95 to 1.15 dl/g as measured at 135.degree. C. in tetralin, (B) 2 to 8% by weight of an ethylene-butene-1 copolymer rubber, (C) 2 to 8% by weight of an ethylene-propylene copolymer rubber, (D) 10 to 20% by weight of talc having an average particle diameter of 4 .mu.m or less, and (E) 5 to 20% by weight of fibrous magnesium oxysulfate, and an injection molded article of the thermoplastic resin composition, said thermoplastic resin composition satisfying the impact strength and rigidity required as a material for an instrumental panel and having a short molding cycle and good surface quality.

    摘要翻译： 一种热塑性树脂组合物，其熔体流动速率为20至30g / 10min，在23℃下的弯曲模量为30,000kg / cm 2或更高，并且其包含（A）60至75重量％的特定结晶 其中丙烯均聚物部分的Q值为3.0-5.0，全同立构五单元组分数为0.975以上，特性粘度η为0.95-1.15dl / g，在135℃下在四氢化萘中测定，（B ）2〜8重量％的乙烯 - 丁烯-1共聚物橡胶，（C）2-8重量％的乙烯 - 丙烯共聚物橡胶，（D）10〜20重量％的平均粒径 （E）5〜20重量％的纤维状氧硫酸镁，以及热塑性树脂组合物的注塑制品，所述热塑性树脂组合物满足作为器具材料所需的冲击强度和刚性 具有短的成型周期和良好的表面质量。

    Propylene polymer composition
    25.
    发明授权
    Propylene polymer composition 失效
    丙烯聚合物组成

    公开(公告)号：US5567759A

    公开(公告)日：1996-10-22

    申请号：US427623

    申请日：1995-04-21

    申请人： Hiroshi Taniguchi ,  Akihiko Yamamoto ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

    发明人： Hiroshi Taniguchi ,  Akihiko Yamamoto ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

    IPC分类号： C08K3/34 ,  C08L53/00

    CPC分类号： C08L53/00 ,  C08K3/34

    摘要： Propylene polymer compositions of the present invention comprising a specific propylene block copolymer, specific ethylene-propylene copolymer rubber, specific ethylene-propylene-diene copolymer rubber, specific ethylene-butene-1 copolymer rubber, and talc in specific proportions are provided. The propylene polymer compositions of the invention are capable of providing therefrom molded products excellent in balance between stiffness and impact resistance, and having high surface hardness with excellent scratch resistance.

    摘要翻译： 提供了包含特定丙烯嵌段共聚物，特定乙烯 - 丙烯共聚物橡胶，特定乙烯 - 丙烯 - 二烯共聚物橡胶，特定乙烯 - 丁烯-1共聚物橡胶和特定比例的滑石的本发明丙烯聚合物组合物。 本发明的丙烯聚合物组合物能够提供刚性和抗冲击性之间的平衡优异的模塑制品，并且具有高的表面硬度和优异的耐擦伤性。

    Polypropylene resin composition
    26.
    发明授权
    Polypropylene resin composition 失效
    聚丙烯树脂组合物

    公开(公告)号：US5308908A

    公开(公告)日：1994-05-03

    申请号：US936389

    申请日：1992-08-28

    申请人： Osamu Fukui ,  Kouhei Ueno ,  Yoshifumi Nakano ,  Ikunori Sakai ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

    发明人： Osamu Fukui ,  Kouhei Ueno ,  Yoshifumi Nakano ,  Ikunori Sakai ,  Takao Nomura ,  Takeyoshi Nishio ,  Hisayuki Iwai

    IPC分类号： C08K3/34 ,  C08L23/08 ,  C08L23/16 ,  C08L53/00 ,  C08L23/04

    CPC分类号： C08K3/34 ,  C08L53/00 ,  C08L2205/02 ,  C08L23/0815 ,  C08L23/16

    摘要： A polypropylene resin composition comprising:(A) 45 to 70% by weight of an ethylene-propylene block copolymer synthesized under the process comprising the steps of;(a) polymerizing propylene with a Ziegler-Natta catalyst to obtain a highly crystalline polypropylene that contain not less than 97% by weight of a fraction insoluble in boiling n-heptane, and(b) copolymerizing ethylene with the polypropylene (a), and which(a) contains 0.5 to 10% by weight of ethylene,(b) contains 5 to 20% by weight of a fraction being soluble in p-xylene at room temperature and having an intrinsic viscosity value of not less than 2 (measured in decalin at 135.degree. C.),(c) has a melt-flow index value of 30 to 100 g/10 min., and,(d) has a value of flexural modulus of not less than 18,000 kg/cm.sup.2,(B) 10 to 20% by weight of an amorphous ethylene-propylene copolymer having(a) an ethylene content of 70 to 90% by weight,(b) a Mooney viscosity value (ML.sub.1+4 at 100.degree. C.) of 5 to 70,(C) 5 to 15% by weight of an ethylene-.alpha.-olefin copolymer having(a) an .alpha.-olefin content of 5 to 15% by mole,(b) a value of gravity of not more than 0.91, and(c) a melt-flow index value of 2.2 to 50 g/10 min. at 230.degree. C.,(D) 1 to 10% by weight of an amorphous ethylene-butene copolymer having(a) a butene content of 10 to 25% by weight, and(b) a Mooney viscosity value (ML.sub.1+4, at 100.degree. C.) of 5 to 20,(E) not more than 15% by weight of a talc that(a) has an average diameter D50 of from 1.0 to 3.0 .mu.m, and(b) does not contain a particle having a diameter of 10 .mu.m or more,wherein the component (B) is rubber reinforced by lamellae of components (C) and (D).

    摘要翻译： 一种聚丙烯树脂组合物，其包含：（A）45至70重量％的在包括以下步骤的方法中合成的乙烯 - 丙烯嵌段共聚物： （a）用齐格勒 - 纳塔催化剂聚合丙烯以获得含有不少于97重量％不溶于沸腾正庚烷的馏分的高度结晶的聚丙烯，和（b）使乙烯与聚丙烯（a）共聚，和 （a）含有0.5〜10重量％的乙烯，（b）在室温下含有5〜20重量％的可溶于对二甲苯的馏分，其特性粘度值不小于2（以 十氢萘在135℃），（c）的熔体流动指数值为30〜100g / 10分钟，（d）弯曲弹性模量值不小于18,000kg / cm 2，（B ）10〜20重量％的（a）乙烯含量为70〜90重量％，（b）门尼粘度值（100℃时ML1 + 4）为5〜70的无定形乙烯 - 丙烯共聚物 ，（C）5〜15重量％的（a）α-烯烃含量为5〜15摩尔％的乙烯-α-烯烃共聚物，（b）重力值不大于0.91，（ c）熔体流动inde x值为2.2〜50g / 10min。 （D）1〜10重量％的（a）丁烯含量为10〜25重量％的无定形乙烯 - 丁烯共聚物，（b）门尼粘度值（ML1 + 4， 在100℃下为5〜20，（E）不超过15重量％的滑石，（a）平均直径D50为1.0〜3.0μm，（b）不含有颗粒 其直径为10μm以上，其中，成分（B）由成分（C）和（D）的薄片橡胶增强。

    Thermoplastic resin composition
    27.
    发明授权
    Thermoplastic resin composition 失效
    热塑性树脂组合物

    公开(公告)号：US5206284A

    公开(公告)日：1993-04-27

    申请号：US728285

    申请日：1991-07-11

    申请人： Osamu Fukui ,  Kiyoshi Tsutsui ,  Tomohiko Akagawa ,  Ikunori Sakai ,  Takao Nomura ,  Takeyoshi Nishio ,  Toshio Yokoi ,  Nobuya Kawamura

    发明人： Osamu Fukui ,  Kiyoshi Tsutsui ,  Tomohiko Akagawa ,  Ikunori Sakai ,  Takao Nomura ,  Takeyoshi Nishio ,  Toshio Yokoi ,  Nobuya Kawamura

    IPC分类号： C08K3/34 ,  C08L51/00 ,  C08L51/06 ,  C08L53/00 ,  C08L53/02 ,  C08L77/00

    CPC分类号： C08L51/006 ,  C08K3/346 ,  C08L51/06 ,  C08L53/005 ,  C08L53/025 ,  C08L77/00

    摘要： A polypropylene thermoplastic resin composition comprising (a) a modified crystalline polypropylene of a crystalline polypropylene comprising said modified crystalline polypropylene and (b) a modified polyamide obtained by partially or wholly grafting a polyamide with a clay mineral. A polypropylene thermoplastic resin composition comprising, in addition to the above polypropylene thermoplastic resin composition comprising the components (a) and (b), one or any combination of the following components (c), (d) and (e): (c) an ethylene-.alpha.-olefin copolymer rubber or a modified ethylene-.alpha.-olefin copolymer rubber, (d) a block copolymer between a monovinyl-substituted aromatic hydrocarbon and a conjugated diene, a hydrogenation product of said block copolymer, or a modification product of said block copolymer, and (e) an inorganic filler. The modified polyamide as the component (b), obtained by modifying a polyamide with a clay mineral has good compatibility with or good dispersibility in the component (a), i.e. the modified crystalline polypropylene or the crystalline polypropylene comprising the modified crystalline polypropylene. Therefore, the polypropylene thermoplastic resin composition comprising these components (a) and (b) has excellent heat resistance and excellent impact resistance.

    摘要翻译： 一种聚丙烯热塑性树脂组合物，其包含（a）包含所述改性结晶聚丙烯的结晶聚丙烯的改性结晶聚丙烯和（b）通过部分或全部用粘土矿物接枝聚酰胺获得的改性聚酰胺。 一种聚丙烯热塑性树脂组合物，除了包含组分（a）和（b）的上述聚丙烯热塑性树脂组合物外，还包含以下组分（c），（d）和（e）中的一种或任意组合：（c） 乙烯-α-烯烃共聚物橡胶或改性乙烯-α-烯烃共聚物橡胶，（d）单乙烯基取代的芳烃和共轭二烯之间的嵌段共聚物，所述嵌段共聚物的氢化产物或 所述嵌段共聚物，和（e）无机填料。 通过用粘土矿物改性聚酰胺获得的作为组分（b）的改性聚酰胺与组分（a），即改性结晶聚丙烯或包含改性结晶聚丙烯的结晶聚丙烯具有良好的相容性或良好的分散性。 因此，包含这些组分（a）和（b）的聚丙烯热塑性树脂组合物具有优异的耐热性和优异的耐冲击性。

    Glass fiber-reinforced thermoplastic resin composition
    29.
    发明授权
    Glass fiber-reinforced thermoplastic resin composition 失效
    玻璃纤维增​​强热塑性树脂组合物

    公开(公告)号：US5811491A

    公开(公告)日：1998-09-22

    申请号：US468625

    申请日：1995-06-06

    申请人： Yasutoshi Jagawa ,  Takeyoshi Nishio ,  Kiyoshi Ogura ,  Mikio Hirai

    发明人： Yasutoshi Jagawa ,  Takeyoshi Nishio ,  Kiyoshi Ogura ,  Mikio Hirai

    IPC分类号： C08F255/02 ,  C08F255/04 ,  C08F255/08 ,  C08F297/02 ,  C08K7/14 ,  C08L25/12 ,  C08L33/24 ,  C08L51/04 ,  C08L51/06 ,  C08L55/02

    CPC分类号： C08L51/04 ,  C08F255/02 ,  C08F255/04 ,  C08F255/08 ,  C08F297/02 ,  C08K7/14 ,  C08L25/12 ,  C08L33/24 ,  C08L51/06 ,  C08L55/02

    摘要： A glass fiber-reinforced thermoplastic resin excellent in providing a balance between processability, tapping strength and heat resistance. The composition comprising (A) 10 to 60% by weight of a terpolymer which comprises N-phenylmaleimide, styrene and acrylonitrile, (B) 5 to 20% by weight of a graft polymer which comprises at least one rubber selected from the group consisting of a conjugated diene rubber, an ethylene-propylene rubber and an ethylene-butylene rubber comprising ethylene and butylene, to which rubber styrene and acrylonitrile are graft polymerized, (C) 10 to 80% by weight of a copolymer which comprises styrene and acrylonitrile, and (D) 5 to 35% by weight of glass fiber, wherein (a) the terpolymer has an intrinsic viscosity of 0.20 dl/g to 0.70 dl/g, (b) the copolymer has an intrinsic viscosity of 0.40 dl/g to 1.00 dl/g, (c) the intrinsic viscosity of terpolymer is equal to or smaller than that of the copolymer, and (d) a styrene content in the copolymer minus a styrene content in the terpolymer is from +20 to -5% by weight.

    摘要翻译： 玻璃纤维增​​强热塑性树脂在加工性，攻丝强度和耐热性之间提供优异的平衡。 包含（A）10至60重量％的包含N-苯基马来酰亚胺，苯乙烯和丙烯腈的三元共聚物，（B）5至20重量％的接枝聚合物，其包含至少一种选自以下的橡胶： 共轭二烯橡胶，乙烯 - 丙烯橡胶和包含乙烯和丁烯的乙烯 - 丁烯橡胶，其中橡胶苯乙烯和丙烯腈接枝聚合，（C）10至80重量％的包含苯乙烯和丙烯腈的共聚物，以及 （D）5〜35重量％的玻璃纤维，其中（a）三元共聚物的特性粘度为0.20dl / g〜0.70dl / g，（b）共聚物的特性粘度为0.40dl / g〜1.00 dl / g，（c）三元共聚物的特性粘度等于或小于共聚物的特性粘度，（d）共聚物中的苯乙烯含量减去三元共聚物中的苯乙烯含量为+20至-5重量％ 。

    Process for preparing a polyamide composite material
    30.
    发明授权
    Process for preparing a polyamide composite material 失效
    制备聚酰胺复合材料的方法

    公开(公告)号：US5248720A

    公开(公告)日：1993-09-28

    申请号：US831005

    申请日：1992-02-06

    申请人： Ryuichi Deguchi ,  Takeyoshi Nishio ,  Akane Okada

    发明人： Ryuichi Deguchi ,  Takeyoshi Nishio ,  Akane Okada

    IPC分类号： C08K3/34

    CPC分类号： C08K3/34

    摘要： A process for preparing a polyamide composite material comprising (1) contacting a layered silicate having a cation exchange capacity of 50 to 200 milliequivalents/100 g with an organic cation of a lactam which is a swelling agent in a dispersing medium, thereby obtaining a composite having the organic cation of the lactam adsorbed onto the layered silicate, and mixing the composite with a polyamide monomer; or (2) mixing a layered silicate having a cation exchange capacity of 50 to 200 milliequivalents/100 g with a compound which becomes a swelling agent through the action of an acid, a polyamide monomer and acid with pKa value of 0 to 3 in a dispersing medium. The mixture containing the polyamide monomer is polymerized to prepare the polyamide composite material.

    摘要翻译： 一种制备聚酰胺复合材料的方法，包括（1）使阳离子交换容量为50-200毫当量/ 100g的层状硅酸盐与分散介质中作为溶胀剂的内酰胺的有机阳离子接触，从而获得复合材料 将内酰胺的有机阳离子吸附到层状硅酸盐上，并将该复合物与聚酰胺单体混合; 或（2）将阳离子交换容量为50〜200毫当量/ 100g的层状硅酸盐与通过酸，聚酰胺单体和pKa值为0〜3的酸成为溶胀剂的化合物混合， 分散介质。 将含有聚酰胺单体的混合物聚合以制备聚酰胺复合材料。