Polyester polymer and copolymer compositions containing titanium nitride particles

    公开(公告)号:US07368523B2

    公开(公告)日:2008-05-06

    申请号:US11228672

    申请日:2005-09-16

    CPC classification number: C08K3/28 Y10T428/1321 Y10T428/1359 C08L67/00

    Abstract: Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles that provide one or more of the following advantages: improving the reheat properties of the compositions, improving the color of the compositions through reduced yellowness, and improving the UV-blocking properties of the compositions. Processes for making such compositions are also disclosed. The titanium nitride particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.

    METHOD FOR DETERMINING ADDENDUM AND BINDER SURFACES OF SPRINGBACK COMPENSATED STAMPING DIES
    24.
    发明申请
    METHOD FOR DETERMINING ADDENDUM AND BINDER SURFACES OF SPRINGBACK COMPENSATED STAMPING DIES 有权
    用于确定弹簧补偿冲压件的添加剂和粘合剂表面的方法

    公开(公告)号:US20070173964A1

    公开(公告)日:2007-07-26

    申请号:US11307189

    申请日:2006-01-26

    CPC classification number: G06F17/5018 G06F17/5095

    Abstract: A method for determining compensated addendum and binder surfaces as part of a springback compensated stamping die for producing a stamped part includes modeling of the existing addendum surface and binder surface of the stamping die. The addendum and binder surfaces are modified according to a number of compensatory surface displacements and in-plane rotations required for springback compensation of the finished stamped part. Following this modification, the stamped part may be separated from the addendum and binder without a loss of dimensional accuracy.

    Abstract translation: 用于确定补偿齿顶和粘合剂表面的方法,作为用于产生冲压部件的回弹补偿冲压模的一部分,包括对冲压模具的现有齿顶表面和粘合剂表面的建模。 根据补偿表面位移和成品冲压部件的回弹补偿所需的面内旋转数,修改齿顶和粘合剂表面。 在该修改之后,冲压部分可以与附件和粘合剂分离,而不会损失尺寸精度。

    Polyester polymer and copolymer compositions containing metallic molybdenum particles
    25.
    发明申请
    Polyester polymer and copolymer compositions containing metallic molybdenum particles 审中-公开
    含有金属钼颗粒的聚酯聚合物和共聚物组合物

    公开(公告)号:US20060051542A1

    公开(公告)日:2006-03-09

    申请号:US10996944

    申请日:2004-11-24

    CPC classification number: C08K3/08 Y10T428/1352 C08L67/00

    Abstract: Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein metallic molybdenum particles that improve the reheat properties of the compositions. Processes for making such compositions are also disclosed. The molybdenum particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable.

    Abstract translation: 公开了聚酯组合物,其包括其中掺入金属钼颗粒的聚酯聚合物或共聚物,其改善组合物的再加热性能。 还公开了制备这种组合物的方法。 可以通过熔融配混将钼颗粒引入聚酯中,或者可以在聚合的任何阶段例如在聚合的熔融相期间加入。 可以使用一定范围的粒度,以及一定范围的粒度分布。 聚酯组合物适用于由需要再热步骤的方法制成的包装。

    ALUMINUM/ALKYLINE OR ALKALI/TITANIUM CONTAINING POLYESTERS HAVING IMPROVED REHEAT, COLOR AND CLARITY
    27.
    发明申请
    ALUMINUM/ALKYLINE OR ALKALI/TITANIUM CONTAINING POLYESTERS HAVING IMPROVED REHEAT, COLOR AND CLARITY 有权
    含有改进的REHEAT,COLOR和CLARITY的聚酯的ALUMINUM / ALKYLINE或ALKALI / TITANIUM

    公开(公告)号:US20110281049A1

    公开(公告)日:2011-11-17

    申请号:US13149248

    申请日:2011-05-31

    Abstract: A polyester composition containing: a) aluminum atoms; and b) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; and c) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators/stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder. The polyester polymer composition can be made to high IV from the melt phase while avoiding solid state polymerization.

    Abstract translation: 一种聚酯组合物,其含有:a)铝原子; 和b)碱土金属原子或碱金属原子或碱金属化合物残基如锂原子; 和c)包含钛,锆,钒,铌,铪,钽,铬,钨,钼,铁或镍原子或其组合的颗粒,其中颗粒改善了聚酯组合物的再热速率。 聚酯聚合物组合物还可以含有磷催化剂失活剂/稳定剂。 聚酯组合物和由诸如瓶子预成型件和拉伸吹塑成型瓶的组合物制成的制品具有改善的再加热速率,同时保持低雾度,高L *,低于3的b *,并且具有低水平的乙醛。 在制备聚酯聚合物的过程中,聚合物熔体在a)和b)存在下缩聚,颗粒c)以熔融相方式加入,或者在注射成型机或挤出机中加入到聚合物中。 聚酯聚合物组合物可以从熔融相制成高IV,同时避免固态聚合。

    Photovoltaic Module Failure Detection Devices and Methods
    28.
    发明申请
    Photovoltaic Module Failure Detection Devices and Methods 审中-公开
    光伏组件故障检测设备和方法

    公开(公告)号:US20110088744A1

    公开(公告)日:2011-04-21

    申请号:US12908953

    申请日:2010-10-21

    CPC classification number: H02S50/10 Y10T29/49355

    Abstract: Photovoltaic module failure detection devices and methods provide reliable, low cost, and effective solutions with visual indication of a temperature of diodes during installation, commissioning, operation, and/or maintenance. Indication of diode temperatures and/or detection of diode failures assures proper installation, improves output, expedites maintenance, increases safety, and/or raises reliability. A photovoltaic module for converting light into electricity includes one or more solar cells, and a transparent front sheet disposed over the one or more solar cells. The photovoltaic module includes a back sheet opposite the transparent front sheet, and one or more electrical circuits with one or more diodes connected to at least a portion of the one or more solar cells. The module includes one or more temperature indication devices in communication with at least a portion of the one or more diodes and disposed between the transparent front sheet and the back sheet.

    Abstract translation: 光伏模块故障检测装置和方法提供可靠,低成本和有效的解决方案,可在安装,调试,运行和/或维护期间直观地指示二极管的温度。 指示二极管温度和/或二极管故障检测确保正确的安装,提高产量,加快维护,提高安全性和/或提高可靠性。 用于将光转换为电的光伏模块包括一个或多个太阳能电池,以及设置在所述一个或多个太阳能电池上的透明前片。 光伏模块包括与透明前片相对的背片,以及一个或多个电路,其中一个或多个二极管连接到一个或多个太阳能电池的至少一部分。 该模块包括与一个或多个二极管的至少一部分连通并且设置在透明前片和背片之间的一个或多个温度指示装置。

    Polyester polymer and copolymer compositions containing particles of titanium nitride and carbon-coated iron
    29.
    发明授权
    Polyester polymer and copolymer compositions containing particles of titanium nitride and carbon-coated iron 有权
    含有氮化钛和碳涂层铁颗粒的聚酯聚合物和共聚物组合物

    公开(公告)号:US07776942B2

    公开(公告)日:2010-08-17

    申请号:US11228733

    申请日:2005-09-16

    Abstract: Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles and carbon-coated iron particles to improve the reheat properties of the compositions. The compositions may also exhibit reduced yellowness, and improved resistance to the effects of UV light. Processes for making such compositions are also disclosed. The particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.

    Abstract translation: 公开了聚酯组合物,其包括其中并入有氮化钛颗粒和碳包覆的铁颗粒的聚酯聚合物或共聚物,以改善组合物的再加热性能。 组合物还可以显示出降低的黄度,并且改善了对UV光的影响的抗性。 还公开了制备这种组合物的方法。 可以通过熔融混合将颗粒引入聚酯中,或者可以在聚合的任何阶段,例如在聚合的熔融相期间加入。 可以使用一定范围的粒度,以及一定范围的粒度分布。 聚酯组合物适用于由期望再热步骤或期望减少黄色的方法制成的包装或期望提高对紫外光效果的耐受性,或上述任何组合。

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