摘要:
The present invention relates to the preparation and use of novel polyurethane polyuretidione crosslinking agents in solvent and water borne coatings systems. These polyuretidione polyurethanes are characterized by their relatively low solution viscosity, and the ability to provide a relatively high crosslink density in the final, cured film, and thereby, coatings with the excellent physical properties and resistance to chemical and environmental exposure of known polyurethane systems without the potential for worker exposure to toxic isocyanates. This invention also relates to a process for the production of these polyuretidiones and their use in pseudo-one and two component coating compositions.
摘要:
High quality, consistent polyurethane froth foams, both filled and unfilled, are prepared by directing polyol, isocyanate, and optionally other polyurethane-forming ingredients to a high pressure mix head prior to introducing the mixture to a froth foaming head. Changes in stoichiometry may be made rapidly without shut-down. An in-line blender incorporated filler into the polyol stream minimizing density differentials normally encountered in the holding tank, maintaining low and reproducible viscosity, and allowing for greater amounts of filler than otherwise possible.
摘要:
Elastomers exhibiting decreased demold times and improved green strength are prepared by reacting a di- or polyisocyanate with a monodisperse polyoxypropylene diol having ultra-low unsaturation, and preferably prepared by the double metal cyanide.t-butyl alcohol catalyzed polymerization of propylene oxide. Further improved demold times and elevated elastomer physical properties are made possible by the use of multidisperse polyoxyalkylene polyether polyol blends having an overall unsaturation of less than 0.010 meq/g and a polydispersity of about 1.4 or greater.
摘要:
The present invention relates to the preparation and use of novel polyurethane polyuretidione crosslinking agents in solvent and water borne coatings systems. These polyuretidione polyurethanes are characterized by their relatively low solution viscosity, and the ability to provide a relatively high crosslink density in the final, cured film, and thereby, coatings with the excellent physical properties and resistance to chemical and environmental exposure of known polyurethane systems without the potential for worker exposure to toxic isocyanates. This invention also relates to a process for the production of these polyuretidiones and their use in pseudo-one and two component coating compositions.
摘要:
A process for alkoxylating phenols is disclosed. The process comprises reacting a carbonyl-functionalized phenol with an alkylene oxide in the presence of a substantially non-crystalline double metal cyanide (DMC) catalyst. The process offers fast reaction times at low catalyst levels, reduced problems with condensation side reactions, and low-color, low-viscosity, low-polydispersity alkoxylated phenols. The process enables efficient preparation of alkoxylated carbonyl-functonalized phenols that are especially valuable in the surfactant industry.
摘要:
An improved process for cell opening of cellular polyurethane molded foam using timed partial pressure release (TPPR) reduces pinch deformation and contour lines by releasing the internal mold pressure in a curing cellular molded polyurethane foam product in a controlled manner which allows gas to escape from the mold, but which prohibits relative movement of the mold sealing surfaces by more than an imperceptible amount.
摘要:
Substantially transition metal-free polyoxyalkylene polyethers may be prepared by double metal cyanide complex-catalyzed oxyalkylation of a suitable hydric oxyalkylation initiator molecule by employing 15 ppm or less of a double metal cyanide complex oxyalkylation catalyst having a propylene oxide polymerization rate greater than 5 g propylene oxide/minute. The induction periods associated with oxyalkylation employing double metal cyanide complex catalysts may be reduced by preparing preactivated master batches and by increasing the oxyalkylation reactor temperature during at least the induction period.
摘要:
Reduction of dinitrotoluene impurity in water is achieved by distillation in the presence of nitric acid. A suitable process for such reduction comprises (a) contacting said composition with nitric acid to provide a nitric acid-containing composition, (b) distilling at least a portion of said water in said nitric acid-containing composition to provide vaporized water containing a reduced concentration of said dinitrotoluene, and (c) separating said vaporized water from said nitric acid-containing composition.
摘要:
Close boiling hydrocarbon impurities are separated from acetone by extractive distillation using a C.sub.9 -C.sub.14 alkane and/or a C.sub.8 -C.sub.12 aromatic hydrocarbon extractive distillation solvent.
摘要:
A titanium-containing molecular sieve which has been used as an oxidation catalyst is regenerated to provide a level of performance comparable to that of freshly prepared catalyst by heating in the presence of a gas stream comprised of less than 5 volume percent molecular oxygen. The regeneration temperature may be in the range of from 150.degree. C. to 700.degree. C. The same batch of catalyst thus may be used over an extended period of time in a continuous epoxidation process by periodic practice of the aforedescribed reactivation method.