Control methodology for desulfurization process
    22.
    发明授权
    Control methodology for desulfurization process 有权
    脱硫工艺控制方法

    公开(公告)号:US07473350B2

    公开(公告)日:2009-01-06

    申请号:US11034796

    申请日:2005-01-13

    IPC分类号: C10G29/00 C10G45/00 C07C7/12

    CPC分类号: C10G45/22 C10G25/00

    摘要: A desulfurization system is operated in a manner which optimizes sulfur removal and octane retention. When the desulfurization reactor is operated at a specific ratio of total pressure to hydrogen partial pressure (PT/PH) and/or within a specific temperature range, optimum sulfur removal and octane retention are realized. The desulfurization reactor can be maintained at these optimized operating conditions by automatically adjusting one or more operating parameters of the desulfurization reactor in order to maintain a substantially constant hydrogen partial pressure (PH) in the reactor. Maintaining a relatively constant hydrogen partial pressure (PH) in the desulfurization reactor helps ensure a relatively consistent degree of desulfurization.

    摘要翻译: 脱硫系统以优化除硫和辛烷值保持的方式运行。 当脱硫反应器以总压力与氢气分压(PT / PH)和/或特定温度范围内的特定比例操作时,实现了最佳的硫去除和辛烷保持。 通过自动调节脱硫反应器的一个或多个操作参数以便在反应器中保持基本上恒定的氢分压(PH),可将脱硫反应器保持在这些优化的操作条件下。 在脱硫反应器中保持相对恒定的氢分压(PH)有助于确保相对一致的脱硫程度。

    Integrated catalytic cracking and desulfurization system
    23.
    发明授权
    Integrated catalytic cracking and desulfurization system 有权
    综合催化裂化脱硫系统

    公开(公告)号:US07449104B2

    公开(公告)日:2008-11-11

    申请号:US10190457

    申请日:2002-07-05

    摘要: An integrated fluid catalytic cracking (FCC) and desulfurization system for processing hydrocarbon-containing fluids. The integrated system employs a cracking/desulfurization unit having a reactor, a regenerator, and a reducer. A mixture of solid FCC catalyst particulates and solid sulfur sorbent particulates are circulated through the reactor, regenerator, and reducer to provide for substantially continuous cracking and desulfurization of the hydrocarbon-containing fluid, as well as substantially continuous regeneration of both the FCC catalyst and the sulfur sorbent.

    摘要翻译: 用于处理含烃流体的综合流化催化裂化(FCC)和脱硫系统。 集成系统采用具有反应器,再生器和还原剂的裂化/脱硫装置。 固体FCC催化剂颗粒和固体硫吸附剂颗粒的混合物循环通过反应器,再生器和还原剂,以提供含烃流体的基本上连续的裂化和脱硫,以及FCC催化剂和 硫吸附剂。

    Removal of naphthenic acids in crude oils and distillates
    27.
    发明授权
    Removal of naphthenic acids in crude oils and distillates 失效
    去除原油和馏出物中的环烷酸

    公开(公告)号:US6096196A

    公开(公告)日:2000-08-01

    申请号:US49465

    申请日:1998-03-27

    摘要: The instant invention is directed a process for extracting organic acids from a starting crude oil comprising the steps of: (a) treating the starting crude oil containing naphthenic acids with an amount of an alkoxylated amine and water under conditions and for a time and at a temperature sufficient to form a water-in-oil emulsion of amine salt wherein said alkoxylated amine is selected from the group consisting of alkoxylated amines having the following formulae (A) and (B): ##STR1## where m+n=5 to 50 and R=linear or branched alkyl group of C.sub.8 to C.sub.20.(B) H-(OCH.sub.2 CH.sub.2).sub.y -(CH.sub.2 CHCH.sub.3 O).sub.p -{NHCH.sub.2 CH.sub.2 NH}.sub.x -(CH.sub.2 CH.sub.2 O).sub.z -(CH.sub.2 CHCH.sub.3 O).sub.q -Hwhere x=1 to 3 and y+z=2 to 6, and wherein p+q=0 to 15, mixtures of formula (A) and mixtures of formula (B); wherein said starting crude oil is selected from the group consisting of crude oils, crude oil blends, and crude oil distillates; and (b) separating said emulsion of step (a) into a plurality of layers, wherein one of such layers contains a treated crude oil having decreased amounts of organic acids; (c) recovering said layer of step (b) containing said treated crude oil having a decreased amount of organic acid and layers containing water and alkoxylated amine salt.

    摘要翻译: 本发明涉及一种从起始原油中提取有机酸的方法,包括以下步骤:(a)在条件和时间和时间内用一定量的烷氧基化胺和水处理含有环烷酸的起始原油 温度足以形成胺盐的油包水乳液,其中所述烷氧基化胺选自具有下式(A)和(B)的烷氧基​​化胺:其中m + n = 5-50且R = (B)H-(OCH 2 CH 2)y - (CH 2 CHCH 3 O)对{(NHCH 2 CH 2 NH)x - (CH 2 CH 2 O)z - (CH 2 CH 3 O)q-H,其中x = 1至3,y + z = 2至6,并且其中p + q = 0至15,式(A)和式(B)的混合物的混合物; 其中所述起始原油选自原油,原油混合物和原油馏出物; 和(b)将步骤(a)的所述乳液分离成多个层,其中这些层之一含有具有降低量的有机酸的经处理的原油; (c)回收所述含有所述经处理的原油的步骤(b)的层具有减少量的有机酸和含有水和烷氧基化胺盐的层。

    Desulfurization process utilizing an oxidizing agent, carbonyl compound,
and hydroxide
    28.
    发明授权
    Desulfurization process utilizing an oxidizing agent, carbonyl compound, and hydroxide 失效
    使用氧化剂,羰基化合物和氢氧化物的脱硫方法

    公开(公告)号:US5961820A

    公开(公告)日:1999-10-05

    申请号:US85478

    申请日:1998-05-27

    CPC分类号: C10L9/06 C10G27/12

    摘要: Sulfur-containing carbonaceous materials are desulfurized by reaction with a mixture of an oxidizing agent and a carbonyl compound under alkaline conditions at a temperature ranging from ambient temperature to about 250.degree. F. and a pressure of about 1 atmosphere to 2 atmospheres. The products of the reaction are a desulfurized carbonaceous material in which the sulfur content is less than about 1%, and gaseous sulfur compounds. The carbonyl compound can be recovered and reused.

    摘要翻译: 在碱性条件下,在环境温度至约250°F的压力和约1大气压至2大气压的压力下,通过与氧化剂和羰基化合物的混合物反应,将含硫的碳质材料脱硫。 反应的产物是其中硫含量小于约1%的脱硫碳质材料和气态硫化合物。 羰基化合物可以回收再利用。

    Settling aids for solids in hydrocarbons
    29.
    发明授权
    Settling aids for solids in hydrocarbons 失效
    沉淀碳氢化合物固体助剂

    公开(公告)号:US5681451A

    公开(公告)日:1997-10-28

    申请号:US594221

    申请日:1996-01-31

    申请人: Paul R. Hart

    发明人: Paul R. Hart

    IPC分类号: C10G29/24 C10G31/00 C10G29/00

    CPC分类号: C10G29/24 C10G31/00

    摘要: Disclosed are methods for accelerating the settling of finely divided, oil-and-water-insoluble solids in hydrocarbon fluids using an effective amount of an alkylphenol-formaldehyde resin alkoxylate having a molecular weight of about 500 to about 5,000. Preferably, the hydrocarbon is a fluid catalytic cracker slurry containing spent catalyst fines.

    摘要翻译: 公开了使用有效量的分子量为约500至约5,000的烷基酚 - 甲醛树脂烷氧基化物来加速细分的油和水不溶性固体在烃流体中沉降的方法。 优选地,烃是含有废催化剂细粉的流化催化裂化浆。

    Abatement of hydrolyzable cations in crude oil
    30.
    发明授权
    Abatement of hydrolyzable cations in crude oil 失效
    在原油中降解可水解的阳离子

    公开(公告)号:US5660717A

    公开(公告)日:1997-08-26

    申请号:US411374

    申请日:1995-03-27

    申请人: Paul M. Lindemuth

    发明人: Paul M. Lindemuth

    CPC分类号: C10G31/08 C10G29/06

    摘要: Hydrolyzable cations contained in crude oil are removed from crude oil by treatment of the crude oil with an aqueous solution containing 100 to 5000 ppm of a water soluble anionic polymer containing at least 20 mole percent mer groups from the group consisting of acrylic acid, methacrylic acid, sulfomethylated polyacrylamide, aminomethanephosphonic acid modified acrylic acid and their water soluble alkali metal and ammonium salts. By removing the hydrolyzable cations, corrosion occurring on metal surfaces in contact with the treated oil during subsequent refining is reduced.

    摘要翻译: 通过用含有100-5000ppm水溶性阴离子聚合物的水溶液处理原油,从原油中除去原油中含有的可水解的阳离子,所述水溶性阴离子聚合物含有至少20摩尔%的mer基团,所述聚合物组由丙烯酸,甲基丙烯酸 ,磺甲基化聚丙烯酰胺,氨基甲烷膦酸改性丙烯酸及其水溶性碱金属和铵盐。 通过除去可水解的阳离子,在随后的精制过程中,与经处理的油接触的金属表面上发生的腐蚀减少。