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    HIGH SEVERITY HYDROPROCESSING INTERSTITIAL METAL HYDRIDE CATALYSTS AND ASSOCIATED PROCESSES
    291.
    发明申请
    HIGH SEVERITY HYDROPROCESSING INTERSTITIAL METAL HYDRIDE CATALYSTS AND ASSOCIATED PROCESSES 审中-公开
    高含量水解间接金属氢化物催化剂及相关工艺

    公开(公告)号：US20110119993A1

    公开(公告)日：2011-05-26

    申请号：US12948595

    申请日：2010-11-17

    Applicant: Faiz Pourarian ,  Marc A. Portnoff ,  David A. Purta ,  Margaret A. Nasta ,  Jingfeng Zhang

    Inventor： Faiz Pourarian ,  Marc A. Portnoff ,  David A. Purta ,  Margaret A. Nasta ,  Jingfeng Zhang

    IPC: C10L1/00 ,  B01J21/06 ,  B01J21/08

    CPC classification number: B01J31/121 ,  B01J23/83 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/18 ,  C10G45/04 ,  C22C16/00 ,  C22C28/00

    Abstract: The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride containing catalyst and hydrogen at process conditions of at least 400 psig pressure and temperatures of at least 200° C. These processes use interstitial metal hydrides that possess significant hydrogen capacities and high hydrogen kinetics rate properties. The catalysts and processes of the present invention may be used with or without radio frequency or microwave energy and are preferably run under conditions of high hydrogen partial pressure above about 350 psia. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams as compared to processes of the prior art operated under similar conditions.

    Abstract translation: 本发明涉及在至少400psig压力和至少200℃的温度的工艺条件下，在含有间隙金属氢化物的催化剂和氢气存在下，含烃进料流的加工。这些方法使用间隙金属氢化物，其具有 显着的氢气容量和高氢动力学特性。 本发明的催化剂和方法可以使用或不使用射频或微波能量，并且优选在高于约350psia的高氢分压的条件下运行。 与在类似条件下操作的现有技术的方法相比，本发明的催化剂和方法可以改进烃类进料流中的总体氢化，产物转化以及硫的还原。

    IMMOBILIZED RESINS FOR ALGAL OIL EXTRACTION
    292.
    发明申请
    IMMOBILIZED RESINS FOR ALGAL OIL EXTRACTION 有权
    用于ALGAL油提取的固定树脂

    公开(公告)号：US20110083360A1

    公开(公告)日：2011-04-14

    申请号：US12903996

    申请日：2010-10-13

    Applicant: Martin Poenie ,  Jessica Jones ,  James Beach

    Inventor： Martin Poenie ,  Jessica Jones ,  James Beach

    IPC: C10L1/00 ,  C12N1/12 ,  C11B3/00

    CPC classification number: C10L1/026 ,  C10G2300/1014 ,  C10G2300/44 ,  C11B1/10 ,  C11B3/00 ,  C11C3/10 ,  C12P7/6463 ,  C12P7/649 ,  Y02E50/13 ,  Y02P30/20

    Abstract: A reverse phase extraction method for the recovery of triglycerides from aqueous slurries of algae is described herein. The present invention discloses the use of immobilized anion exchange and lipid binding resins. As the algae flows past the resin, triglycerides adhere while the bulk of the algae flows through. The lipids, useful for generating biofuels are then are eluted off the resin. The method of the present invention does not require prior drying of the algae, is inexpensive, and does not destroy the algal biomass which can be used for other purposes.

    Abstract translation: 本文描述了用于从藻类水溶液中回收甘油三酯的反相提取方法。 本发明公开了固定化阴离子交换和脂质结合树脂的用途。 当藻类流过树脂时，甘油三酯粘附，而大部分藻类流经。 然后可用于产生生物燃料的脂质从树脂上洗脱掉。 本发明的方法不需要先前干燥藻类，便宜，并且不破坏可用于其它目的的藻类生物质。

    Nanoparticle Catalyst Compounds and/or Volatile Organometallic Compounds and Method of Using the Same for Biomass Gasification
    295.
    发明申请
    Nanoparticle Catalyst Compounds and/or Volatile Organometallic Compounds and Method of Using the Same for Biomass Gasification 有权
    纳米粒子催化剂化合物和/或挥发性有机金属化合物及其使用方法用于生物质气化

    公开(公告)号：US20100299990A1

    公开(公告)日：2010-12-02

    申请号：US12685791

    申请日：2010-01-12

    Applicant: Allen Aradi ,  Joseph Roos ,  Tze-Chi Jao

    Inventor： Allen Aradi ,  Joseph Roos ,  Tze-Chi Jao

    IPC: C01B3/38 ,  B01J21/06 ,  B01J23/72 ,  B01J23/755 ,  C10L1/00

    CPC classification number: C10B53/02 ,  B01J23/755 ,  B01J23/83 ,  B01J31/2295 ,  B01J31/28 ,  B01J35/0013 ,  B01J2531/72 ,  C10B47/24 ,  C10B57/06 ,  C10G1/002 ,  C10G1/10 ,  C10G2300/1011 ,  C10J3/00 ,  C10J2300/0916 ,  C10J2300/0986 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P20/52 ,  Y02P30/20

    Abstract: A nanocatalyst, dual catalyst and methods for improving the efficiency and output of a biomass gasification process are provided where the catalysts comprise a volatile organometallic compound(s) and/or a nanoalloy catalyst. By the catalyst and method, a very high biomass gasification conversion efficiency of over 85% can be achieved. The subject nanocatalyst cracks and gasifies lignin, which is generally inert in conventional gasification, at relatively low gasification temperatures. The subject disclosure also provides a means to increase gas yields and lower lignin content in the resulting product relative to conventional gasification. Alternatively, oil production may be increased, if desired. Moreover, the resulting gas may achieve a Fischer-Tropsch reactor favorable H2:CO ratio of about 9:1. The energy input to the gasification is correspondingly reduced to reduce costs and the environmental impact associated with the gasification process.

    Abstract translation: 提供了一种纳米催化剂，双重催化剂和用于提高生物质气化方法的效率和产出的方法，其中催化剂包含挥发性有机金属化合物和/或纳米合金催化剂。 通过催化剂和方法，可以实现超过85％的非常高的生物质气化转化效率。 本发明的纳米催化剂在相对低的气化温度下裂化并气化常规气化中通常是惰性的木质素。 本发明还提供了相对于常规气化提高所得产物的气体产率和降低木质素含量的方法。 或者，如果需要，可以增加产油量。 此外，所得气体可以实现费 - 托反应器，优选约9:1的H 2 :CO比。 相应减少对气化的输入能量，以降低与气化过程相关的成本和环境影响。

    Method of converting animal waste into a multi-phase fuel
    297.
    发明授权
    Method of converting animal waste into a multi-phase fuel 有权
    将动物废物转化为多相燃料的方法

    公开(公告)号：US07753969B2

    公开(公告)日：2010-07-13

    申请号：US12217194

    申请日：2008-07-02

    Applicant: Alfred Herman Stiller ,  Laura Shannon Eddy

    Inventor： Alfred Herman Stiller ,  Laura Shannon Eddy

    IPC: C10L1/00

    CPC classification number: C10L1/00 ,  C10G1/02 ,  C10G1/04 ,  C10L5/42 ,  C10L9/086 ,  Y02E50/10 ,  Y02E50/30

    Abstract: A method of creating a multi-phase fuel wherein said fuel comprises a gas, a solid, a liquid solvent phase and an aqueous phase from animal waste comprising the combination of the animal waste, a solvent, and a water/alcohol solution into a fluid mixture, placing the mixture into a closed reactor, heating said reactor between about 245° C. and 385° C. for between about 5 and 70 minutes and cooling said resulting multi-phase fuel. The animal waste may be manure, mortalities, municipal waste, or chicken litter. The preferred solvent is petroleum with the preferred petroleum being diesel fuel. The final multi-phase fuel can be separated into four separate fuels: a solid fuel, an emulsified solid in the liquid solvent phase by blending the solid, the solvent and a surfactant, an aqueous phase, and the recovered liquid solvent phase. Petroleum is the preferred solvent and the separation may be any conventional means. The mixture preferably consists of 1 part by weight animal waste, about 1.5 parts by weight diesel and between about 0.11 to about 1.86 parts by weight a water/alcohol solution. The water/alcohol solution is between about 5% to about 85% alcohol before heating. Additionally, an alkali base may be added to increase waste solubility.

    Abstract translation: 一种产生多相燃料的方法，其中所述燃料包括来自动物废物的气体，固体，液体溶剂相和水相，其包括动物废物，溶剂和水/醇溶液的组合到流体 混合物，将混合物置于封闭的反应器中，在约245℃至385℃之间加热所述反应器约5至70分钟并冷却所得的多相燃料。 动物废物可能是粪便，死亡物，城市垃圾或鸡粪。 优选的溶剂是石油，优选的石油是柴油。 最终的多相燃料可以通过混合固体，溶剂和表面活性剂，水相和回收的液体溶剂相分离成四种分开的燃料：固体燃料，液体溶剂相中的乳化固体。 石油是优选的溶剂，分离可以是任何常规方法。 混合物优选由1重量份动物废物，约1.5重量份柴油和约0.11至约1.86重量份水/醇溶液组成。 在加热之前，水/醇溶液为约5％至约85％的醇。 此外，可以加入碱碱以增加废溶解性。

    Method and Facility for Treating Waste Drilling Mud
    298.
    发明申请
    Method and Facility for Treating Waste Drilling Mud 有权
    废物钻井泥浆处理方法与设备

    公开(公告)号：US20100130387A1

    公开(公告)日：2010-05-27

    申请号：US12609939

    申请日：2009-10-30

    Applicant: Richard T. Davis ,  Thomas P. Jones ,  Charles R. Richesin

    Inventor： Richard T. Davis ,  Thomas P. Jones ,  Charles R. Richesin

    IPC: C09K8/02 ,  C10L1/00 ,  B01D35/00

    CPC classification number: E21B21/063 ,  C10G33/00 ,  C10G2300/1003

    Abstract: A method is provided of recycling and decontaminating oil-based waste drilling mud and cuttings contaminated with oil-based waste drilling mud. A facility for performing the method is also provided. The method includes removing the coarse solids from the mud, breaking the emulsion, and separating the hydrophobic phase from the water phase and the solid phase. The solids may then be treated by either or both of two approaches. One approach involves vaporizing all residual oil and water from the solids, and burning off the vaporized oil. Another approach involves at least partially vaporizing the residual oil from the solids and recondensing the oil. The method produces a solid “soil” product that is free from oil contamination (or is sufficiently decontaminated to allow reuse), an oil product that is fit for reuse, and clean air emissions. A thermal desorber or a soil dryer can be used to efficiently vaporize the oil at low temperature. Optionally the water fraction of the mud can be vaporized, solutes and salts can be captured as evaporite and then be mixed with the soil product. The method has the unique advantage of producing no persistent hazardous waste. The method has the further advantage of requiring no external input of energy if the reclaimed oil is used to provide energy for the process. The method has the further advantage of recycling portions of the drilling mud that would otherwise be subject to disposal.

    Abstract translation: 提供了一种回收和净化油基废钻井泥浆和被油基废钻井泥浆污染的切屑的方法。 还提供了用于执行该方法的设备。 该方法包括从泥浆中除去粗固体，破碎乳液，并将疏水相与水相和固相分离。 然后可以通过两种方法中的一种或两种来处理固体。 一种方法包括从固体中蒸发所有残留的油和水，并将蒸发的油燃烧。 另一方法涉及至少部分地蒸发来自固体的残留油并重新冷凝油。 该方法产生一种不含油污染（或足够净化以允许再利用）的固体“土壤”产品，适合再利用的油品，并清洁空气排放物。 热解吸器或土壤干燥器可用于在低温下有效地蒸发油。 任选地，泥浆的水分可以蒸发，溶质和盐可以作为蒸发岩被捕获，然后与土壤产物混合。 该方法具有不产生持续危险废物的独特优点。 如果再生油用于为该过程提供能量，该方法具有不需要外部输入能量的进一步优点。 该方法的另一个优点是回收了否则将被处置的钻井泥浆的部分。

    Chemical synthesis methods using electro-catalysis
    299.
    发明授权
    Chemical synthesis methods using electro-catalysis 失效
    使用电催化的化学合成方法

    公开(公告)号：US07695534B2

    公开(公告)日：2010-04-13

    申请号：US11132938

    申请日：2005-05-19

    Applicant: J. Alan Lawson ,  Ahmed A. Baosman

    Inventor： J. Alan Lawson ,  Ahmed A. Baosman

    IPC: C10L1/00 ,  C10L1/19 ,  C10L1/04 ,  C25B3/00

    CPC classification number: C10G32/02 ,  A61L2/03 ,  B01J19/087 ,  B01J2219/00006 ,  B01J2219/0004 ,  B01J2219/0877 ,  C10L1/026 ,  Y02E50/13

    Abstract: Synthesis methods are provided using electro-chemical catalysis. In one method, diesel fuel is made by (1) flowing a mixture of a triglyceride source and an alcohol through a high voltage electrical field, effective to convert the triglyceride into saturated mono alkyl esters; and (2) adding the saturated mono alkyl esters to a petroleum-derived diesel fuel to form a diesel fuel blend. In another method, a high temperature, oxidatively stable lubricant is made by (1) flowing a renewable oil including unsaturated fatty acids through a high voltage electrical field effective to convert the unsaturated fatty acids into saturated fatty acids; and (2) adding one or more functional additives to the saturated fatty acid-containing renewable oil to form a synthetic lubricant. In another method, ethanol is made by flowing a liquid which comprises a simple sugar through a high voltage electrical field effective to convert the sugar into ethanol without fermentation.

    Abstract translation: 使用电化学催化提供合成方法。 在一种方法中，柴油燃料是通过（1）使甘油三酯源和醇的混合物流过高电压电场来制备的，有效地将甘油三酯转化为饱和单烷基酯; 和（2）将饱和单烷基酯加入到石油衍生的柴油燃料中以形成柴油混合物。 在另一种方法中，通过（1）通过有效将不饱和脂肪酸转化为饱和脂肪酸的高电压电场使包含不饱和脂肪酸的可再生油流动，制得高温氧化稳定的润滑剂; 和（2）向含饱和脂肪酸的可再生油中加入一种或多种功能添加剂以形成合成润滑剂。 在另一种方法中，乙醇通过使含有简单糖的液体通过高压电场流动而有效地将糖转化为乙醇而不发酵来制备。

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