Method for Producing High-Purity Tungsten Powder
    371.
    发明申请
    Method for Producing High-Purity Tungsten Powder 有权
    高纯度钨粉生产方法

    公开(公告)号:US20120180600A1

    公开(公告)日:2012-07-19

    申请号:US13498252

    申请日:2010-09-28

    CPC classification number: B22F9/22 B22F2201/013 C22C27/04

    Abstract: Provided is a method for producing a high-purity tungsten powder having a phosphorus content of less than 1 wtppm; wherein an ammonium tungstate solution containing 1 wtppm or more of phosphorus as an impurity in terms of the inclusion in tungsten is used as a starting material, this solution is neutralized with hydrochloric acid at a temperature of 50° C. or less to adjust the pH at 4 or more and less than 7 so as to precipitate ammonium paratungstate undecahydrate crystals, the resulting solution is heated to 70 to 90° C. and filtered in a high-temperature state so as to obtain ammonium paratungstate pentahydrate crystals, the obtained crystals are calcined so as to form a tungsten oxide, and the tungsten oxide is subject to hydrogen reduction so as to obtain a high-purity tungsten powder. Additionally provided is a method for producing a high-purity tungsten powder having a phosphorus content of 0.4 wtppm or less; wherein the ammonium tungstate solution is neutralized with hydrochloric acid to adjust the pH at 4 or more and 6 or less, and this solution is subject to the same procedure as described above so as to obtain a high-purity tungsten powder. Consequently, the phosphorus content can be efficiently reduced.

    Abstract translation: 本发明提供磷含量小于1重量ppm的高纯度钨粉的制造方法, 其中以钨含量计含有1重量ppm或更多的磷作为杂质的钨酸钨溶液用作原料,该溶液在50℃或更低的温度下用盐酸中和以调节pH 在4以上且小于7以下,以使仲钨酸铵十一水合物晶体析出,将所得溶液加热至70〜90℃,并在高温状态下过滤,得到仲钨酸铵五水合物晶体,得到的晶体为 煅烧以形成氧化钨,并且将氧化钨进行氢还原以获得高纯度钨粉末。 另外提供了一种磷含量为0.4重量ppm以下的高纯度钨粉的制造方法, 其中钨酸铵溶液用盐酸中和以将pH调节至4以上且6以下,并且将该溶液按照与上述相同的方法进行,以获得高纯度的钨粉末。 因此,可以有效地降低磷含量。

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