Abstract:
A capacitor including a dielectric structure, a lower electrode may be formed on a substrate. The dielectric structure may be formed on the lower electrode, and may include a first thin film, which may improve a morphology of the dielectric structure, and a second thin film, which may have at least one of an EOT larger than that of the first thin film and a dielectric constant higher than that of the first thin film. An upper electrode may be formed on the dielectric structure, and the dielectric structure may have an improved morphology and/or a higher dielectric constant.
Abstract:
A method of manufacturing a semiconductor device can include forming a tunnel oxide layer on a substrate, forming a floating gate on the tunnel oxide layer and forming a dielectric layer pattern on the floating gate using an ALD process. The dielectric layer pattern can include a metal precursor that includes zirconium and an oxidant. A control gate can be formed on the dielectric layer pattern. The semiconductor device can include the dielectric layer pattern provided herein.
Abstract:
A method of manufacturing a non-volatie memory device includes forming a tunnel insulating layer on a substrate, forming a conductive pattern on the tunnel insulating layer, forming a lower dielectric layer on the conductive pattern, performing a first heat treatment process to density the lower dielectric layer, and forming a middle dielectric layer having an energy band gap smaller than that of the lower dielectric layer on the first heat-treated lower dielectric layer. The method further includes forming an upper dielectric layer including a material substantially identical to that of the lower dielectric layer on the middle dielectric layer, performing a second heat treatment process to densify the middle dielectric layer and the upper dielectric layer and forming a conductive layer on the second heat-treated upper dielectric layer.
Abstract:
The present invention provides methods of forming metal thin films, lanthanum oxide films and high dielectric films. Compositions of metal thin films, lanthanum oxide films and high dielectric films are also provided. Further provided are semiconductor devices comprising the metal thin films, lanthanum oxide films and high dielectric films provided herein.
Abstract:
A thin film structure and a capacitor using the film structure and methods for forming the same. The thin film structure may include a first film formed on a substrate using a first reactant and an oxidant for oxidizing the first reactant. A second film may be formed on the first film to suppress crystallization of the first film. A capacitor may include a dielectric layer, which may further include the first thin film and the second thin film.
Abstract:
Disclosed is a method for forming metal oxide dielectric layers, more particularly HfO2 dielectric layers, using an atomic layer deposition (ALD) method in which a series of thin intermediate layers are formed and treated with one or more oxidizers and nitrogents before the next intermediate layer is formed on the substrate. The intermediate oxidation treatments reduce the number of organic contaminants incorporated into the metal oxide layer from the organometallic precursors to produce a dielectric layer having improved current leakage characteristics. The dielectric layers formed in this manner remain susceptible to crystallization if exposed to temperatures much above 550° C., so subsequent semiconductor manufacturing processes should be modified or eliminated to avoid such temperatures or limit the duration at such temperatures to maintain the performance of the dielectric materials.
Abstract:
A semiconductor memory device that includes a composite Al2O3/HfO2 dielectric layer with a layer thickness ratio greater than or equal to 1, and a method of manufacturing the capacitor are provided. The capacitor includes a lower electrode, a composite dielectric layer including an Al2O3 dielectric layer and an HfO2 dielectric layer sequentially formed on the lower electrode, the Al2O3 dielectric layer having a thickness greater than or equal to the HfO2 dielectric layer, and an upper electrode formed on the composite dielectric layer. The Al2O3 dielectric layer has a thickness of 30-60 Å. The HfO2 dielectric layer has a thickness of 40 Å or less.
Abstract translation:一种半导体存储器件,其包括层厚度比大于或等于1的复合Al 2 O 3 / HfO 2 sub>电介质层, 并提供一种制造该电容器的方法。 电容器包括下电极,复合电介质层,其包括依次形成在其上的Al 2 O 3 3电介质层和HfO 2 N 2介电层 下电极,具有大于或等于HfO 2 2电介质层的厚度的Al 2 O 3 3 sub>电介质层,以及形成的上电极 在复合介电层上。 Al 2 O 3介电层具有30-60埃的厚度。 HfO 2 2介电层的厚度为40以下。
Abstract:
A semiconductor memory device that includes a composite Al2O3HfO2 dielectric layer with a layer thickness ratio greater than or equal to 1, and a method of manufacturing the capacitor are provided. The capacitor includes a lower electrode, a composite dielectric layer including an Al2O3 dielectric layer and an HfO2 dielectric layer sequentially formed on the lower electrode, the Al2O3 dielectric layer having a thickness greater than or equal to the HfO2 dielectric layer, and an upper electrode formed on the composite dielectric layer. The Al2O3 dielectric layer has a thickness of 30-60 Å. The HfO2 dielectric layer has a thickness of 40 Å or less.
Abstract translation:一种半导体存储器件,其包括层厚度比大于或等于1的复合Al 2 O 3 HfO 2 sub>电介质层,以及 提供了制造电容器的方法。 电容器包括下电极,复合电介质层,其包括依次形成在其上的Al 2 O 3 3介电层和HfO 2 O 3介电层 下电极,具有大于或等于HfO 2 2电介质层的厚度的Al 2 O 3 3 sub>电介质层,以及形成的上电极 在复合介电层上。 Al 2 O 3介电层具有30-60埃的厚度。 HfO 2 2介电层的厚度为40以下。
Abstract:
A method for manufacturing a semiconductor device employing a dielectric layer for forming a conductive layer into a three-dimensional shape. The dielectric layer is formed on a substrate in such a manner as to provide an intrinsic etch rate within the layer which increases in the direction of the thickness or depth of the dielectric layer. This variable intrinsic etch rate within the dielectric layer is achieved by changing one of a plurality of deposition variables. Once formed, the dielectric layer is selectively etched to form a through hole to contact a conductive area underlying the dielectric layer. A conductive layer is formed in the through hole, which may be a storage node of a capacitor.
Abstract:
An electronic device may include a substrate, an oxide dielectric layer on the substrate, an interface layer on the oxide dielectric layer, and an electrode on the interface layer. The oxide dielectric layer may include an aluminum oxide layer between first and second zirconium oxide layers. The interface layer may have a first formation enthalpy, and the oxide dielectric layer may be between the substrate and the interface layer. The electrode may have a second formation enthalpy higher than the first formation enthalpy, and the interface layer may be between the oxide dielectric layer and the electrode.