公开(公告)号：US20100307979A1

公开(公告)日：2010-12-09

申请号：US12669969

申请日：2008-07-10

Applicant: Reinhold Klipper ,  Michael Schelhaas ,  Stefan Neumann ,  Duilio Rossoni ,  Wolfgang Zarges

Inventor： Reinhold Klipper ,  Michael Schelhaas ,  Stefan Neumann ,  Duilio Rossoni ,  Wolfgang Zarges

IPC: B01D15/04 ,  B01J41/14 ,  B01D53/02

CPC classification number: C08F12/36 ,  B01D15/00 ,  B01D53/02 ,  B01D53/64 ,  B01D2251/90 ,  B01J13/10 ,  B01J20/26 ,  B01J20/261 ,  B01J20/265 ,  B01J41/14 ,  B01J45/00 ,  C02F1/42 ,  C02F1/683 ,  C02F2101/20 ,  C08F8/30 ,  C08F8/44 ,  C08F2800/20 ,  C22B3/42 ,  C22B7/006 ,  Y02P10/234 ,  C08F212/08

Abstract: The present application relates to novel chelate resins which contain, as a functional group, quaternary nitrogen atoms in structures of the general formula (I) in which at least one of the radicals R1 to R3 represents an optionally substituted radical of the series consisting of picolyl, methylquinoline or methylpiperidine, m represents an integer from 1 to 4 and M represents the polymer matrix and X represents a counterion of the series consisting of hydroxide OH−, halide, preferably Cl−, Br−, or sulphate SO42−, a process for their preparation and the use thereof, in particular the use of the novel chelate resins in hydrometallurgy and electroplating.

Abstract translation: 本申请涉及新的螯合树脂，其中含有作为官能团的通式（I）结构中的季氮原子，其中基团R 1至R 3中的至少一个表示任选取代的由吡啶甲基 ，甲基喹啉或甲基哌啶，m表示1至4的整数，M表示聚合物基体，X表示由氢氧化物OH-，卤化物，优选Cl-，Br-或硫酸盐SO 4 2-组成的系列的抗衡离子， 其制备及其用途，特别是新型螯合树脂在湿法冶金和电镀中的应用。

公开(公告)号：US20100252506A1

公开(公告)日：2010-10-07

申请号：US12669968

申请日：2008-07-11

Applicant: Reinhold Klipper ,  Michael Schelhaas

Inventor： Reinhold Klipper ,  Michael Schelhaas

IPC: B01J41/12 ,  C02F1/42 ,  C02F1/62 ,  B01D53/02

CPC classification number: B01J13/10 ,  B01D53/64 ,  B01D2251/90 ,  B01J41/14 ,  B01J45/00 ,  C02F1/42 ,  C02F1/683 ,  C02F2101/20 ,  C08F8/30 ,  C08F8/32 ,  C22B3/42 ,  C22B7/006 ,  Y02P10/234 ,  C08F220/14

Abstract: The present invention relates to a method of producing novel chelate resins based on crosslinked polymer beads starting with methacrylic compounds, containing aminomethyl groups and/or aminomethyl nitrogen heterocyclic groups as functional groups, that have a high uptake capacity for heavy metals and rapid kinetics.

Abstract translation: 本发明涉及以含有氨基甲基和/或氨基甲基氮杂环基作为官能团的甲基丙烯酸类化合物起始的交联聚合物珠粒生产新型螯合树脂的方法，其具有对重金属的高吸收能力和快速动力学。

公开(公告)号：US07754084B2

公开(公告)日：2010-07-13

申请号：US11899125

申请日：2007-09-04

Applicant: Pierre Vanhoorne ,  Wolfgang Podszun ,  Reinhold Klipper ,  Michael Schelhaas

Inventor： Pierre Vanhoorne ,  Wolfgang Podszun ,  Reinhold Klipper ,  Michael Schelhaas

IPC: C08J9/00

CPC classification number: B01J41/14 ,  B01J31/08 ,  C02F1/42 ,  C02F2001/422 ,  C02F2103/023

Abstract: The present invention relates to heat-stable anion exchangers based on at least one aromatic monomer and at least one crosslinker having structural elements of the general formula (I) where Ak, Ak′, Ak″ are in each case independently of one another identically or differently a C1-C18-alkyl radical, n is an even number between 5 and 18, x+y=2, where x is equal to 0 or 1, and X is Cl, Br, OH, HCO3, HSO4, ½ (SO4), ½ CO3, NO3, F, H2PO4, ½ HPO4, ⅓ PO4 with the result that these anion exchangers, preferably in the OH form, withstand a working temperature of at least 60° C., preferably of at least 80° C., over a relatively long time, a process for production thereof and also use thereof.

Abstract translation: 本发明涉及基于至少一种芳族单体和至少一种具有通式（I）结构单元的交联剂的热稳定阴离子交换剂，其中Ak，Ak'，Ak“在每种情况下彼此独立地相同或相同 不同的是C 1 -C 18烷基，n是5和18之间的偶数，x + y = 2，其中x等于0或1，X是Cl，Br，OH，HCO 3，HSO 4，½（SO 4 ），½CO 3，NO 3，F，H 2 PO 4，½HPO 4，1 PO 4，结果这些阴离子交换剂优选为OH形式，耐受至少60℃，优选至少80℃的工作温度。 在相当长的时间内，其生产方法及其用途。

公开(公告)号：US07553906B2

公开(公告)日：2009-06-30

申请号：US10738879

申请日：2003-12-17

Applicant: Jan Weikard ,  Christoph Gürtler ,  Wolfgang Fischer ,  Diethelm Rappen ,  Michael Schelhaas

Inventor： Jan Weikard ,  Christoph Gürtler ,  Wolfgang Fischer ,  Diethelm Rappen ,  Michael Schelhaas

IPC: C08G18/80 ,  C08G18/81 ,  C08L75/14 ,  C07C233/57 ,  C07C263/00

CPC classification number: C08G18/672 ,  C08G18/8048 ,  C08G18/8093 ,  C08G18/8096 ,  C08G18/8175 ,  C08L75/16 ,  C09D175/16 ,  Y10T428/31551 ,  C08G18/62 ,  C08L2666/20

Abstract: An organic polyisocyanate with at least one unsaturated functional group is capable of copolymerizing when exposed to actinic radiation. The polyisocyanate comprises structural units with the formula (1): wherein: X is an electron-attracting group; R1, and R2 are hydrogen atoms, a saturated or unsaturated aliphatic or cycloaliphatic radical, or an aromatic or araliphatic radical; and n is an integer from 0 to 5. A process for producing this polyisocyanate is also disclosed.

Abstract translation: 具有至少一个不饱和官能团的有机多异氰酸酯在暴露于光化辐射时能够共聚。 多异氰酸酯包括具有式（1）的结构单元：其中：X是吸电子基团; R1和R2是氢原子，饱和或不饱和的脂族或脂环族基团，或芳族或芳脂族基团; 并且n为0至5的整数。还公开了制备该多异氰酸酯的方法。

公开(公告)号：US20090158896A1

公开(公告)日：2009-06-25

申请号：US12087632

申请日：2007-01-26

Applicant: Duilio Rossoni ,  Reinhold Klipper ,  Bruno Hees ,  Rudolf Wagner ,  Stefan Neumann ,  Olaf Halle ,  Wolfgang Podszun ,  Michael Schelhaas

Inventor： Duilio Rossoni ,  Reinhold Klipper ,  Bruno Hees ,  Rudolf Wagner ,  Stefan Neumann ,  Olaf Halle ,  Wolfgang Podszun ,  Michael Schelhaas

IPC: C22B11/00 ,  C22B5/00 ,  C08F8/32

CPC classification number: C22B3/42 ,  B01J45/00 ,  C22B3/24 ,  C22B23/0453 ,  Y02P10/234

Abstract: The present invention relates to the use of monodisperse, macroporous chelating resins in the recovery of metals in hydrometallurgical processes, in particular in resin-in-pulp processes.

Abstract translation: 本发明涉及单分散大孔螯合树脂在湿法冶金方法中回收金属的用途，特别是在树脂 - 纸浆法中。

公开(公告)号：US20080272055A1

公开(公告)日：2008-11-06

申请号：US11810520

申请日：2007-06-06

Applicant: Reinhold Klipper ,  Michael Schelhaas ,  Stefan Neumann ,  Jens Stoll

Inventor： Reinhold Klipper ,  Michael Schelhaas ,  Stefan Neumann ,  Jens Stoll

IPC: B01J41/08 ,  B01J41/02 ,  B01J41/10 ,  C02F1/42

CPC classification number: C02F1/42 ,  B01J41/10 ,  B01J45/00 ,  B01J47/016 ,  C02F2101/103 ,  C02F2101/105 ,  C02F2101/20 ,  C02F2101/203 ,  C02F2101/206

Abstract: The present invention relates to the use of inorganic salts for increasing the adsorption of oxoanions and/or thioanalogues thereof to metal-doped ion exchangers, preferably to iron oxide/iron oxyhydroxide-containing ion exchangers, preferably from water or aqueous solutions, and also the conditioning of these metal-doped ion exchangers having increased adsorption behaviour toward oxoanions and/or thioanalogues thereof by using inorganic salts with the exception of amphoteric ion exchangers which have both acidic and basic groups as functional groups.

Abstract translation: 本发明涉及无机盐用于增加氧化亚氨基和/或其硫代分子对金属掺杂的离子交换剂，优选氧化铁/含羟基氧化铁的离子交换剂，优选水或水溶液的吸附，以及 通过使用无机盐除了具有酸性和碱性基团作为官能团的两性离子交换剂之外，这些金属掺杂的离子交换剂的调理具有增加的吸附行为向氧阴离子和/或硫代分子的吸附行为。

公开(公告)号：US20080234398A1

公开(公告)日：2008-09-25

申请号：US12070442

申请日：2008-02-19

Applicant: Reinhold Klipper ,  Wolfgang Podszun ,  Michael Schelhaas ,  Pierre Vanhoorne ,  Hans-Karl Soest ,  Ulrich Litzinger

Inventor： Reinhold Klipper ,  Wolfgang Podszun ,  Michael Schelhaas ,  Pierre Vanhoorne ,  Hans-Karl Soest ,  Ulrich Litzinger

IPC: B01J39/20

CPC classification number: C08J5/20 ,  B01J39/20 ,  C02F2001/425 ,  C08F20/06 ,  C08F220/02

Abstract: The present invention relates to a process for producing novel monodisperse cation exchangers of the poly(meth)acrylic acid type, the ion exchangers themselves, and also use thereof and to the use of intermediate products as supports for enzymes and the systems resulting therefrom as enzyme catalysts for the preparation of fuels and in transesterification reactions and esterification reactions.

Abstract translation: 本发明涉及一种生产聚（甲基）丙烯酸类型的新型单分散阳离子交换剂，离子交换剂本身及其用途的方法以及作为酶的载体的中间产物的使用以及由此产生的体系作为酶 用于制备燃料和酯交换反应和酯化反应的催化剂。

公开(公告)号：US20070241056A1

公开(公告)日：2007-10-18

申请号：US11732970

申请日：2007-04-05

Applicant: Reinhold Klipper ,  Wolfgang Podszun ,  Stefan Neumann ,  Michael Schelhaas ,  Holger Schafer ,  Thomas Linn ,  Wolfgang Zarges

Inventor： Reinhold Klipper ,  Wolfgang Podszun ,  Stefan Neumann ,  Michael Schelhaas ,  Holger Schafer ,  Thomas Linn ,  Wolfgang Zarges

IPC: B01D15/00

CPC classification number: C02F1/42 ,  B01J20/28085 ,  B01J43/00 ,  B01J47/016 ,  B01J49/45 ,  C02F1/281 ,  C02F2303/16

Abstract: The present invention relates to the use of amphoteric ion exchangers for adsorbing oxo anions, preferably to the use of iron oxide/iron oxyhydroxide-containing amphoteric ion exchangers for removing oxo anions from water and aqueous solutions, and to the preparation of these amphoteric iron oxide/iron oxyhydroxide-containing ion exchangers.

Abstract translation: 本发明涉及两性离子交换剂用于吸附氧阴离子的用途，优选使用含氧化铁/含羟基氧化铁的两性离子交换剂来除去水和水溶液中的氧阴离子，以及制备这些两性氧化铁 /含羟基氧化铁的离子交换剂。

公开(公告)号：US20060069225A1

公开(公告)日：2006-03-30

申请号：US11219396

申请日：2005-09-02

Applicant: Matthias Wintermantel ,  Christoph Gurtler ,  Michael Schelhaas ,  Rainer Trinks ,  Walter Meckel

Inventor： Matthias Wintermantel ,  Christoph Gurtler ,  Michael Schelhaas ,  Rainer Trinks ,  Walter Meckel

IPC: C08G18/00

CPC classification number: C09J175/12 ,  C08G18/10 ,  C08G18/8093 ,  C09J175/04 ,  C08G18/3271

Abstract: The present invention relates to reactive compositions containing A) one or more blocked polyurethane prepolymers which have a content of blocked isocyanate groups (calculated as NCO) of 0.1 to 20 wt. % and are prepared from i) at least one aromatic, aliphatic, araliphatic and/or cycloaliphatic diisocyanate having a content of free NCO groups of 5 to 60 wt. %, ii) a polyol component containing at least one polyester polyol, and/or at least one polyether polyol and/or at least one polycarbonate polyol, iii) CH-acidic cyclic ketones corresponding to formula (I) as blocking agents wherein X represents an electron-attracting group, R1 and R2 independently of one another represent the radicals H, C1-C20 (cyclo)alkyl, C6-C24 aryl, C1-C20 (cyclo)alkyl ester or amide, C6-C24 aryl ester or amide, mixed aliphatic/aromatic radicals with 1 to 24 carbon atoms that can also be part of a 4- to 8-membered ring, n is an integer from 0 to 5, and B) one or more OH-functional compounds in which the OH component undergoes activation by a deposition amine component. The present invention also relates to a composite system containing two adherends bonded together with the reactive composition according to the invention.

Abstract translation: 本发明涉及含有A）一种或多种封端聚氨酯预聚物的反应性组合物，其中封端异氰酸酯基团（以NCO计算）为0.1-20wt。 ％，并且由i）至少一种芳族，脂族，芳脂族和/或脂环族二异氰酸酯制备，其中游离NCO基团含量为5-60wt。 ％，ii）含有至少一种聚酯多元醇的多元醇组分和/或至少一种聚醚多元醇和/或至少一种聚碳酸酯聚

公开(公告)号：US06706924B2

公开(公告)日：2004-03-16

申请号：US10028892

申请日：2001-12-18

Applicant: Michael Schelhaas ,  Katrin Joschek ,  Manfred Jautelat ,  Joachim Zechlin ,  Dietmar Wastian

Inventor： Michael Schelhaas ,  Katrin Joschek ,  Manfred Jautelat ,  Joachim Zechlin ,  Dietmar Wastian

IPC: C07C21158

CPC classification number: C07C251/20 ,  C07C201/12 ,  C07C205/45 ,  C07C209/28 ,  C07C209/36 ,  C07C209/48 ,  C07C209/60 ,  C07C209/68 ,  C07C211/60 ,  C07C221/00 ,  C07C233/11 ,  C07C249/02 ,  C07C253/30 ,  C07C255/42 ,  C07C2602/10 ,  C07C225/22 ,  C07C211/58 ,  C07C255/35 ,  C07C211/48

Abstract: The invention relates to a process for the production of 1,5-naphthalenediamine and to the intermediates 4-(2-nitrophenyl)butyronitrile, 5-nitro-3,4-dihydro-1(2H)-naphthyl-imine, 5-nitroso-1-naphthylamine, 5-nitro-1-naphthylamine, 4-(2-aminophenyl)-butyronitrile, 5-amino-3,4-dihydro-1(2H)-naphthalene imine, 4-(2-nitrophenyl)ethyl butyrate and 4-(2-nitrophenyl)butyramide obtainable during the process.

Abstract translation: 本发明涉及一种生产1,5-萘二胺的方法和中间体4-（2-硝基苯基）丁腈，5-硝基-3,4-二氢-1（2H） - 萘基亚胺，5-亚硝基 1-萘胺，5-硝基-1-萘胺，4-（2-氨基苯基） - 丁腈，5-氨基-3,4-二氢-1（2H） - 萘亚胺，4-（2-硝基苯基）丁酸乙酯 和4-（2-硝基苯基）丁酰胺。