Silicoaluminophosphates having an AEL structure
    31.
    发明授权
    Silicoaluminophosphates having an AEL structure 失效
    具有AEL结构的硅铝磷酸盐

    公开(公告)号:US06294493B1

    公开(公告)日:2001-09-25

    申请号:US09315416

    申请日:1999-05-20

    IPC分类号: B01J2906

    摘要: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions and high catalytic cracking activity, a method for their preparation and their use as FCC catalysts. More particularly, the new SAPOs have a high silica:alumina ratio and favorable Si atom distribution. The new SAPOs may have a small crystal size and may be synthesized from a single- phase synthesis solution.

    摘要翻译: 公开了具有独特硅分布和高催化裂解活性的硅铝磷酸盐(SAPO),其制备方法及其作为FCC催化剂的用途。 更具体地说,新的SAPO具有高的二氧化硅:氧化铝比和有利的Si原子分布。 新的SAPO可能具有小的晶体尺寸,并且可以由单相合成溶液合成。

    Synthesis of and composition of ECR-40, large pore aluminophosphate
    32.
    发明授权
    Synthesis of and composition of ECR-40, large pore aluminophosphate 有权
    ECR-40,大孔磷酸铝的合成和组成

    公开(公告)号:US5976491A

    公开(公告)日:1999-11-02

    申请号:US169653

    申请日:1998-10-09

    摘要: The present invention is a large-pore aluminophosphate or substituted aluminophosphate comprising a compositionaR:(M.sub.x Al.sub.y P.sub.z)O.sub.2wherein R represents an organic templating agent, and a=0 to 0.4, X=0 to 0.4, y=0.35 to 0.5, and Z=0.25 to 0.5 and characterized by the diffraction pattern of Table 1 and M may be Si, Ga, Ge, Co, Ni, Zn, Fe, V, Ti and mixtures thereof.

    摘要翻译: 本发明是包含组成aR(MxAlyPz)O 2的大孔磷酸铝或取代的磷酸铝,其中R表示有机模板剂,a = 0至0.4,X = 0至0.4,y = 0.35至0.5,Z = 0.25〜0.5,其特征在于表1的衍射图,M可以是Si,Ga,Ge,Co,Ni,Zn,Fe,V,Ti及其混合物。

    Crystalline zeolite ECR-35 and a method for producing same
    36.
    发明授权
    Crystalline zeolite ECR-35 and a method for producing same 失效
    结晶沸石ECR-35及其制备方法

    公开(公告)号:US5116590A

    公开(公告)日:1992-05-26

    申请号:US727202

    申请日:1991-07-09

    IPC分类号: B01J29/70 C01B39/20 C01B39/48

    摘要: A synthetic large pore crystalline metalsilicate zeolite composition, designated as ECR-35, having the formula, expressed in term of mole ratio of oxides: ##STR1## where T is an organic cation selected from the group consisting of tetraethylammonium and methyltriethyl ammonium, and mixtures thereof and X is Al or Ga; wherein the composition consists of an X-ray diffraction pattern having the line intensities:______________________________________ Line # d(.ANG.) Intensity ______________________________________ (1) 15.00 .+-. 0.2 weak to very strong (2) 14.20 .+-. 0.2 very strong (3) 13.40 .+-. 0.2 weak to medium (4) 8.70 .+-. 0.2 medium (5) 8.03 .+-. 0.2 zero to medium (6) 7.40 .+-. 0.15 medium (7) 5.65 .+-. 0.15 medium-strong ______________________________________ and wherein the intensity of line (2) is greater than line (1) which is substantially greater than the intensity of line (3); and wherein the intensity of line (4) is substantially greater than the intensity of line (6) which is greater than the intensity of line (5) and a method for preparing same.

    Composition and process for preparing ECR-30
    38.
    发明授权
    Composition and process for preparing ECR-30 失效
    制备ECR-30的组成和工艺

    公开(公告)号:US4879103A

    公开(公告)日:1989-11-07

    申请号:US249754

    申请日:1988-09-27

    IPC分类号: C01B39/20

    CPC分类号: C01B39/205 Y10S423/21

    摘要: A zeolite characterized by having an x-ray diffraction pattern as shown in Table 1, a silica to alumina mole ratio of at least six, and containing triethyl methyl ammonium, wherein said organic ammonium templates are within the super cages of said aluminosilicate, said zeolite having a hexagonal unit cell.

    摘要翻译: 一种沸石,其特征在于具有如表1所示的x射线衍射图,二氧化硅与氧化铝的摩尔比为至少6,并含有三乙基甲基铵,其中所述有机铵模板位于所述硅铝酸盐的超级笼内,所述沸石 具有六边形单元电池。

    Method for producing open framework zeolites
    39.
    发明授权
    Method for producing open framework zeolites 失效
    开放式框架沸石的制备方法

    公开(公告)号:US3947482A

    公开(公告)日:1976-03-30

    申请号:US452734

    申请日:1974-03-20

    摘要: High purity synthetic zeolites having open frameworks, such as offretite, uncontaminated with detectable traces of other zeolites, can be synthesized by the hydrothermal reaction of a silica source, alumina source, sodium hydroxide and/or potassium hydroxide in the presence of a zeolite nucleation slurry synthesized from a mixture of a silica source, alumina source, sodium hydroxide and/or potassium hydroxide and an organic template agent. The preferred organic template agents are the quaternary compounds wherein the central element is one from Group 5A of the Periodic Table and various conjugated aromatic compounds. The zeolite synthesis mixture itself does not contain any organic ion template agent. With this organic template agent not being required, the nucleation slurry is used to promote crystallization of the synthesis mixture to the open framework type of zeolite.

    摘要翻译: 具有开放骨架的高纯度合成沸石,例如未知的痕量的其它沸石,可以通过二氧化硅源,氧化铝源,氢氧化钠和/或氢氧化钾的水热反应在沸石成核浆液 由二氧化硅源,氧化铝源,氢氧化钠和/或氢氧化钾与有机模板剂的混合物合成。 优选的有机模板剂是其中中心元素是周期表的5A族和各种共轭芳族化合物的季铵化合物。 沸石合成混合物本身不含任何有机离子模板剂。 在不需要这种有机模板剂的情况下,成核浆用于促进合成混合物结晶到开放骨架型沸石。