公开(公告)号：US20130030135A1

公开(公告)日：2013-01-31

申请号：US13629323

申请日：2012-09-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： John R. Hagadorn ,  Patrick Brant ,  Robbert Duchateau ,  Rafael Sablong

IPC: C08F2/00 ,  C08F10/06 ,  C08F4/76

CPC classification number: C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F299/00 ,  C08F2410/01 ,  C08F4/7042 ,  C08F4/64193 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/02

Abstract: Vinyl-terminated macromonomer oligomerization, namely, a process to produce polymacromonomers comprising contacting a vinyl-terminated macromonomer with a catalyst system capable of oligomerizing vinyl-terminated macromonomer, in the presence of an aluminum containing compound, a zinc containing compound, or a combination thereof, under polymerization conditions to produce a polymacromonomer, and polymacromonomers produced thereby. Also, polymacromonomers having a degree of polymerization greater than 10, a glass transition temperature Tg of less than 60° C., and an Mn of greater than or equal to about 5000 Da.

Abstract translation: 乙烯基封端的大分子单体低聚，即生产聚异氰酸酯的方法，包括使乙烯基封端的大分子单体与能够使乙烯基封端的大分子单体低聚的催化剂体系在含铝化合物，含锌化合物或其组合的存在下接触 在聚合条件下制备聚共聚单体，由此制备聚异戊烯。 此外，聚合度大于10，玻璃化转变温度Tg小于60℃，Mn大于或等于约5000Da的聚异氰酸共聚单体。

公开(公告)号：US10882925B2

公开(公告)日：2021-01-05

申请号：US16192654

申请日：2018-11-15

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Jian Yang ,  Gregory J. Karahalis ,  John R. Hagadorn ,  Timothy M. Boller ,  Evan J. Morris ,  Patrick Brant

IPC: C07F17/00 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/659 ,  C08F10/02 ,  C08J5/18 ,  B32B27/08 ,  C08F2/34

Abstract: The present disclosure relates to ansa-metallocene catalyst compounds that include (1) a first indenyl ligand substituted at the 3-position with a substituted or unsubstituted C4-C40 hydrocarbyl group, wherein the hydrocarbyl group is branched at the β-position, and (2) a second indenyl ligand substituted at its 3-position with a substituted or unsubstituted alkyl group or a β-branched alkyl group. Catalyst systems prepared with the catalyst compounds, polymerization methods using such catalyst systems, and polyolefins made using the polymerization methods are also described.

公开(公告)号：US20200308384A1

公开(公告)日：2020-10-01

申请号：US16829833

申请日：2020-03-25

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Maksim Shivokhin ,  Patrick Brant

IPC: C08L23/12 ,  C08L23/14 ,  C08L33/08

Abstract: This invention relates to a composition can include a propylene polymer and up to about 60 wt % of an ethylene-acrylate copolymer, based on a weight of the propylene polymer and the ethylene-acrylate copolymer. The composition can have a strain hardening ratio of greater than 1 to about 15, where the extensional viscosity is measured at a Hencky strain rate of 1 s−1 and at a temperature of 190° C. The ethylene-acrylate copolymer can include units derived from ethylene and at least 5 mol % of units derived from a C1-C4 alkyl acrylate.

公开(公告)号：US10570219B2

公开(公告)日：2020-02-25

申请号：US15570822

申请日：2016-05-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Lubin Luo ,  Jeanette M. Diop ,  Jian Yang ,  Sudhin Datta ,  Patrick Brant

IPC: C08F210/06 ,  C08F4/6592 ,  C08L23/16 ,  C08F2/34 ,  C08L23/14 ,  C08F110/06 ,  C08F210/16 ,  C08L23/12 ,  C08L23/06 ,  C08F2/01 ,  C08F2/12 ,  C08F4/659 ,  C08F110/02 ,  C08F210/02

Abstract: Methods for the production of heterophasic polymers in gas and slurry phase polymerization processes, and polymer compositions made therefrom, are disclosed herein.

公开(公告)号：US20180258195A1

公开(公告)日：2018-09-13

申请号：US15570822

申请日：2016-05-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Lubin Luo ,  Jeanette M. Diop ,  Jian Yang ,  Sudhin Datta ,  Patrick Brant

IPC: C08F2/34 ,  C08F210/16 ,  C08F2/12 ,  C08F4/659 ,  C08F4/6592 ,  C08F110/02 ,  C08L23/16 ,  C08L23/12 ,  C08L23/06 ,  C08F2/01 ,  C08F210/06 ,  C08F210/02 ,  C08F110/06

CPC classification number: C08F2/34 ,  C08F2/01 ,  C08F2/12 ,  C08F4/65916 ,  C08F4/65927 ,  C08F110/02 ,  C08F110/06 ,  C08F210/02 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/05 ,  C08F2500/16 ,  C08L23/06 ,  C08L23/12 ,  C08L23/14 ,  C08L23/16 ,  C08L2205/02 ,  C08L2207/02 ,  C08L2314/06

Abstract: Methods for the production of heterophasic polymers in gas and slurry phase polymerization processes, and polymer compositions made therefrom, are disclosed herein.

公开(公告)号：US10017708B2

公开(公告)日：2018-07-10

申请号：US14017651

申请日：2013-09-04

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Abhimanyu Onkar Patil ,  John W. Chu ,  Satish Bodige ,  Liehpao Oscar Farng ,  Donna Jean Crowther ,  Man Kit Ng ,  Patrick Brant ,  Kathryn L. Peretti

IPC: B01D19/04 ,  C10M133/06 ,  C10M171/00 ,  B21B45/02 ,  C07C263/00 ,  C10M149/04 ,  C10L1/185 ,  C10L1/228 ,  C10M145/04 ,  C10M133/54 ,  C10M159/12

CPC classification number: C10M149/04 ,  C10L1/1857 ,  C10L1/2283 ,  C10M133/54 ,  C10M145/04 ,  C10M159/12 ,  C10M2205/0285 ,  C10M2215/26 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/10 ,  C10N2240/10

Abstract: This disclosure relates to a composition for use as an additive for fuels and lubricants including a reductive amination product of a vinyl terminated macromonomer (VTM) based aldehyde. Optionally aldehyde is reacted with the amino compound under condensation conditions sufficient to give an imine intermediate, and the imine intermediate is reacted under hydrogenation conditions sufficient to give the composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde. A reductive amination method for making a composition for use as an additive for fuels and lubricants. The method includes reacting a VTM based aldehyde with an amino compound containing at least one —NH— group under condensation conditions sufficient to give an imine intermediate, and reacting the imine intermediate under hydrogenation conditions sufficient to give said composition. The aldehyde is formed by reacting a VTM under hydroformylation conditions sufficient to form the aldehyde.

公开(公告)号：US09284387B2

公开(公告)日：2016-03-15

申请号：US14033560

申请日：2013-09-23

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Donna J. Crowther ,  Man Kit Ng ,  Patrick Brant ,  Hong Cheng

IPC: C08F10/06 ,  C08F8/32

CPC classification number: C08F10/06 ,  C08F8/00 ,  C08F8/04 ,  C08F8/32 ,  C08F8/48 ,  C08F2810/40 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/03 ,  C08F110/06 ,  C08F4/65922 ,  C08F210/14 ,  C08F210/08

Abstract: This invention relates to a polyolefin composition comprising one or more of the following formulae: wherein the PO is the residual portion of a vinyl terminated macromonomer (VTM) having had a terminal unsaturated carbon of an allylic chain and a vinyl carbon adjacent to the terminal unsaturated carbon; R1 is a hydrogen atom, an aryl group, or an alkyl group, wherein the aryl group or alkyl group can include one or more heteroatoms, an alkyl or aryl amino group, a polyalkylamino group; wherein the VTM is a vinyl terminated macromonomer.

Abstract translation: 本发明涉及包含一种或多种下列通式的聚烯烃组合物：其中PO是具有烯键的末端不饱和碳和邻近末端不饱和的乙烯基碳的乙烯基封端的大分子单体（VTM）的残余部分 碳; R 1是氢原子，芳基或烷基，其中芳基或烷基可以包括一个或多个杂原子，烷基或芳基氨基，多烷基氨基; 其中VTM是乙烯基封端的大分子单体。

公开(公告)号：US20140088265A1

公开(公告)日：2014-03-27

申请号：US14033636

申请日：2013-09-23

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Donna J. Crowther ,  Patrick Brant

IPC: C08F4/76 ,  C08F4/52

CPC classification number: C08F4/76 ,  C08F4/52 ,  C08F8/00 ,  C08F10/02 ,  C08F110/02 ,  C08F2500/03 ,  C08F2500/09 ,  C08F210/16 ,  C08F210/14 ,  C08F10/00 ,  C08F4/65927

Abstract: This invention relates to processes to produce vinyl terminated polyethylene involving contacting ethylene with a supported metallocene catalyst system; wherein the supported catalyst system comprises a support material; an alumoxane activator; and a metallocene compound. A supported metallocene catalyst system is also disclosed. Processes to produce ethylene copolymers are also disclosed.

Abstract translation: 本发明涉及生产乙烯基封端聚乙烯的方法，包括使乙烯与负载的茂金属催化剂体系接触; 其中所述载体催化剂体系包含载体材料; 铝氧烷激活剂; 和茂金属化合物。 还公开了负载型金属茂催化剂体系。 还公开了生产乙烯共聚物的方法。

公开(公告)号：US20140088264A1

公开(公告)日：2014-03-27

申请号：US14033560

申请日：2013-09-23

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Donna J. Crowther ,  Man Kit Ng ,  Patrick Brant ,  Hong Cheng

IPC: C08F10/06 ,  C08F8/32

CPC classification number: C08F10/06 ,  C08F8/00 ,  C08F8/04 ,  C08F8/32 ,  C08F8/48 ,  C08F2810/40 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/03 ,  C08F110/06 ,  C08F4/65922 ,  C08F210/14 ,  C08F210/08

Abstract: This invention relates to a polyolefin composition comprising one or more of the following formulae: wherein the PO is the residual portion of a vinyl terminated macromonomer (VTM) having had a terminal unsaturated carbon of an allylic chain and a vinyl carbon adjacent to the terminal unsaturated carbon; R1 is a hydrogen atom, an aryl group, or an alkyl group, wherein the aryl group or alkyl group can include one or more heteroatoms, an alkyl or aryl amino group, a polyalkylamino group; wherein the VTM is a vinyl terminated macromonomer.

Abstract translation: 本发明涉及包含一种或多种下列通式的聚烯烃组合物：其中PO是具有烯键的末端不饱和碳和邻近末端不饱和的乙烯基碳的乙烯基封端的大分子单体（VTM）的残余部分 碳; R 1是氢原子，芳基或烷基，其中芳基或烷基可以包括一个或多个杂原子，烷基或芳基氨基，多烷基氨基; 其中VTM是乙烯基封端的大分子单体。

公开(公告)号：US20140088217A1

公开(公告)日：2014-03-27

申请号：US14031898

申请日：2013-09-19

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Man Kit Ng ,  Donna J. Crowther ,  Hong Cheng ,  Patrick Brant

IPC: C08F8/34

CPC classification number: C08F8/34 ,  C08F8/42 ,  C08F2810/40 ,  C08L23/20 ,  C08F110/06 ,  C08L23/12 ,  C08F110/10

Abstract: This invention relates to a polyolefin composition comprising one or more of the following formulae: wherein the PO is the residual portion of a vinyl terminated macromonomer (VTM) having had a terminal unsaturated carbon of an allylic chain and a vinyl carbon adjacent to the terminal unsaturated carbon; wherein X is one of a trialkoxysilane, carboxylic acid, carboxylic ester, carboxylic acid salt, carboxamide, carbonate, carbamate, phosphonic acid, phosphonic ester, phosphonic acid salt, sulfonic acid, sulfonic ester, sulfonic acid salt, nitrile, hydroxyl, an amino (primary, secondary, or tertiary, e.g., quaternized), an alkyl ether, an aryl ether, a thioether, an arylthioether, boronic acid, boronic ester, boronic acid salt, or halogen; and R1 is an aryl, heteroaryl, or alkyl group.

Abstract translation: 本发明涉及包含一种或多种下列通式的聚烯烃组合物：其中PO是具有烯键的末端不饱和碳和邻近末端不饱和的乙烯基碳的乙烯基封端的大分子单体（VTM）的残余部分 碳; 其中X是三烷氧基硅烷，羧酸，羧酸酯，羧酸盐，甲酰胺，碳酸酯，氨基甲酸酯，膦酸，膦酸酯，膦酸盐，磺酸，磺酸酯，磺酸盐，腈，羟基，氨基 （伯，仲或叔，例如季铵化），烷基醚，芳基醚，硫醚，芳基硫醚，硼酸，硼酸酯，硼酸盐或卤素; 并且R 1是芳基，杂芳基或烷基。