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    Preparation of impact-resistant thermoplastic molding
    32.
    发明授权
    Preparation of impact-resistant thermoplastic molding 失效
    抗冲击热塑性塑料的制备

    公开(公告)号：US4780509A

    公开(公告)日：1988-10-25

    申请号：US43492

    申请日：1987-04-28

    申请人： Christof Taubitz ,  Erhard Seiler ,  Lothar Schlemmer

    发明人： Christof Taubitz ,  Erhard Seiler ,  Lothar Schlemmer

    IPC分类号： C08F285/00 ,  C08F257/02

    CPC分类号： C08F285/00

    摘要： Impact-resistant thermoplastic molding materials based on a resin A containing one or more vinylaromatic monomers are prepared by reacting the resin A (component A) with one or more monomers from the group consisting of the .alpha.,.beta.-unsaturated dicarbonyl compounds (component B) by a process in which the reaction is carried out in a melt of A in the presence of B and in the absence of initiators, and the resin A used is one which contains from 3 to 50% by weight, based on A, of one or more elastomers a.sub.1 (rubber) and has been prepared in a conventional manner by polymerizing one or more vinylaromatic monomers of 8 to 12 carbon atoms in the presence of the elastomer a.sub.1 are used for the production of moldings.

    摘要翻译： 基于含有一种或多种乙烯基芳族单体的树脂A的耐冲击热塑性成型材料通过使树脂A（组分A）与一种或多种来自α，β-不饱和二羰基化合物（组分B）的单体反应制备， 通过在B的存在下和不存在引发剂的情况下在A的熔体中进行反应的方法，所用的树脂A是含有基于A的3至50重量％的树脂A，其中A为 或更多的弹性体a1（橡胶），并且在弹性体a1的存在下通过聚合一种或多种具有8至12个碳原子的乙烯基芳族单体以常规方式制备，用于制备模制品。

    Reinforced thermoplastic molding materials based on polyphenylene ether
    34.
    发明授权
    Reinforced thermoplastic molding materials based on polyphenylene ether 失效
    基于聚苯醚的增强热塑性成型材料

    公开(公告)号：US4948832A

    公开(公告)日：1990-08-14

    申请号：US281755

    申请日：1988-12-09

    申请人： Bertram Ostermayer ,  Ehrenfried Baumgartner ,  Rainer Bueschl ,  Hermann Brandt ,  Klaus Boehlke ,  Erhard Seiler ,  Graham E. McKee

    发明人： Bertram Ostermayer ,  Ehrenfried Baumgartner ,  Rainer Bueschl ,  Hermann Brandt ,  Klaus Boehlke ,  Erhard Seiler ,  Graham E. McKee

    IPC分类号： C08L51/04 ,  C08L71/12 ,  C08L77/00

    CPC分类号： C08L51/04 ,  C08L71/123 ,  C08L77/00

    摘要： Reinforced thermoplastic molding materials containing, as essential components,(A) from 40 to 94 parts by weight of a polymer component of(a.sub.1) from 10 to 90% by weight of polyphenylene ether and(a.sub.2) from 10 to 90% by weight, based in each case on A, of a styrene polymer toughened with an acrylate rubber or with an unhydrogenated or hydrogenated polymer of a conjugated diene,(B) from 1 to 20 parts by weight of a copolymer of(b.sub.1) from 70 to 99.9% by weight of a monomer from the group consisting of styrene, .alpha.-methylstyrene and styrene alkylated in the nucleus or a mixture of these monomers,(b.sub.2) from 0.1 to 30% by weight of one or more compounds from the group consisting of tert-butyl acrylate and tert-butyl methacrylate, or one or more compounds from the group of compounds of the general formula I ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2, R.sup.3 and R.sup.4 are each an alkyl or alkoxy group of not more than 4 carbon atoms, or of the general formula II ##STR2## where n is an integer from 1 to 4 and R.sup.5, R.sup.6 and R.sup.7 are each one of the radicals stated for R.sup.2 or are each --O(CH.sub.2 --CH.sub.2 --O).sub.m R.sup.8, where R.sup.8 is C.sub.1 -C.sub.4 -alkyl and m is 1, 2, 3 or 4, and(b.sub.3) from 0 to 10% by weight, based on the copolymer, of a further ethylenically unsaturated monomer which is copolymerizable with b.sub.1 and b.sub.2, and(C) from 5 to 50 parts by weight of a reinforcing agent, the number of parts by weight being based on 100 parts by weight of the sum of A, B and C,are prepared and used for the production of moldings.

    摘要翻译： 作为必要成分的增强热塑性成型材料含有（A）40〜94重量份聚合物成分（a1），10〜90重量％聚苯醚和（a2）10〜90重量％ 基于A的每种情况，使用丙烯酸酯橡胶或共轭二烯的未氢化或氢化的聚合物增韧的苯乙烯聚合物，（B）1至20重量份的（b1）70至99.9重量％的共聚物， 重量的来自于在核中烷基化的苯乙烯，α-甲基苯乙烯和苯乙烯的单体或这些单体的混合物，（b2）0.1-30％（重量）一种或多种下列化合物：叔 - 丙烯酸丁酯和甲基丙烯酸叔丁酯，或一种或多种通式Ⅰ化合物的化合物，其中R1是氢或甲基，R2，R3和R4分别是烷基或烷氧基不大于 4个碳原子，或通式II其中n是一个整数 1至4的取代基和R 5，R 6和R 7各自为R 2所示的基团之一或分别为-O（CH 2 -CH 2 -O）m R 8，其中R 8为C 1 -C 4 - 烷基且m为1,2,3 或（4）和（b3）0〜10重量％，基于共聚物，可与b1和b2共聚的另外的烯属不饱和单体和（C）5〜50重量份的增强剂， 制备基于100重量份的A，B和C之和的重量份数，并用于制造模制品。

    Fully aromatic thermotropic polyester imide
    36.
    发明授权
    Fully aromatic thermotropic polyester imide 失效
    全芳香热致聚酰亚胺

    公开(公告)号：US4801676A

    公开(公告)日：1989-01-31

    申请号：US78668

    申请日：1987-07-28

    申请人： Bernd Hisgen ,  Hans-Jakob Kock ,  Michael Portugall ,  Erhard Seiler ,  Gerd Blinne

    发明人： Bernd Hisgen ,  Hans-Jakob Kock ,  Michael Portugall ,  Erhard Seiler ,  Gerd Blinne

    IPC分类号： C08G63/68 ,  C08G63/19 ,  C08G63/685 ,  C08G63/688 ,  C08G73/16 ,  C09K19/38 ,  D01F6/84

    CPC分类号： C09K19/3823 ,  C08G63/685 ,  C08G63/688

    摘要： Fully aromatic thermotropic polyesters based on(A) from 30 to 60 mol % of 4-hydroxybenzoic acid,(B) from 20 to 35 mol % of a mixture of(B.sub.1) terephthalic acid,(B.sub.2) isophthalic acid and(B.sub.3) from 0.5 to 5 mol % of a dicarboxylic acid of the general formula I ##STR1## where X is --O--, --S--, --SO.sub.2 --, --CO--, --CH.sub.2 -- or --C(CH.sub.3).sub.2 --, n is 0 or 1 and the two imide nitrogen atoms are meta or para to X, or their C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, aryl, chlorine or bromine derivatives which are substituted in the nucleus,the molar ratio of B.sub.1 to B.sub.2 being from 1.04:1 to 19:1, and(C) from 20 to 35 mol % of a mixture of(C.sub.1) hydroquinone and(C.sub.2) 4,4'-dihydroxydiphenyl,the molar ratio of C.sub.1 to C.sub.2 being from 0.1:1 to 2.67:1 and the molar ratio of B to C being from 0.9:1 to 1.1:1.

    摘要翻译： 基于（A）30至60mol％的4-羟基苯甲酸的全芳族热致聚酯，（B）20至35mol％的（B1）对苯二甲酸，（B2）间苯二甲酸和（B3）的混合物 0.5〜5mol％的通式I的二羧酸，其中X是-O - ， - S - ， - SO 2 - ， - CO - ， - CH 2 - 或-C（CH 3）2 - ，n是 0或1，并且两个酰亚胺氮原子是X或其在核中被取代的C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基，芳基，氯或溴衍生物的间位或对位，B1与B2的摩尔比 为1.04:1〜19:1，（C）20〜35摩尔％（C1）氢醌与（C2）4,4'-二羟基二苯基的混合物，C1与C2的摩尔比为0.1： 1〜2.67:1，B与C的摩尔比为0.9:1〜1.1:1。

    Graft polymers of polyphenylene ethers
    37.
    发明授权
    Graft polymers of polyphenylene ethers 失效
    聚苯醚接枝聚合物

    公开(公告)号：US4797453A

    公开(公告)日：1989-01-10

    申请号：US63687

    申请日：1987-06-19

    申请人： Christof Taubitz ,  Hermann Gausepohl ,  Erhard Seiler ,  Lothar Schlemmer

    发明人： Christof Taubitz ,  Hermann Gausepohl ,  Erhard Seiler ,  Lothar Schlemmer

    IPC分类号： C08F283/06 ,  C08F283/08 ,  C09D151/08 ,  C08L71/02

    CPC分类号： C09D151/08 ,  C08F283/08

    摘要： Graft polymers of(A) a polyphenylene ether as a base polymer and(B) a half ester of an unsaturated dicarboxylic acid of the general formula ##STR1## as a graft monomer, where R.sup.1 is C.sub.1 -C.sub.25 -alkyl, C.sub.2 -C.sub.25 -alkylene or aryl, R.sup.2 and R.sup.3 are each H, Br, Cl or one of the radicals R.sup.1, and Q is H or an alkali metal, an alkaline earth metal or an ammonium cation,with or without(C) further olefinically unsaturated monomers,and their preparation.

    摘要翻译： （A）聚苯醚作为基础聚合物的接枝聚合物和（B）作为接枝单体的通式为不饱和二羧酸的半酯，其中R 1是C 1 -C 25烷基，C 2 -C 25 - 亚烷基或芳基，R 2和R 3各自为H，Br，Cl或基团R 1中的一个，Q为H或碱金属，碱土金属或铵阳离子，具有或不具有（C）另外的烯属不饱和单体 ，及其准备。

    Fully aromatic thermotropic polyesters
    38.
    发明授权
    Fully aromatic thermotropic polyesters 失效
    全芳香族热致聚酯

    公开(公告)号：US4748229A

    公开(公告)日：1988-05-31

    申请号：US077281

    申请日：1987-07-24

    申请人： Bernd Hisgen ,  Hans-Jakob Kock ,  Michael Portugall ,  Erhard Seiler ,  Gerd Blinne

    发明人： Bernd Hisgen ,  Hans-Jakob Kock ,  Michael Portugall ,  Erhard Seiler ,  Gerd Blinne

    IPC分类号： C08G63/60 ,  C08G63/66 ,  C08G63/672 ,  C08G63/68 ,  C08G63/685 ,  C08G63/688 ,  C09K19/38 ,  C08G63/54 ,  C08G69/44

    CPC分类号： C08G63/672 ,  C08G63/605 ,  C08G63/685 ,  C08G63/688 ,  C09K19/3809

    摘要： Fully aromatic thermotropic polyesters are based on(A) from 30 to 60 mol % of 4-hydroxybenzoic acid,(b) from 20 to 35 mol % of a mixture of(B.sub.1) terephthalic acid and(B.sub.2) isophthalic acid, the molar ratio of B.sub.1 to B.sub.2 being from 1.04:1 to 19:1, and(C) from 20 to 35 mol % of a mixture of(C.sub.1) hydroquinone,(C.sub.2) 4,4'-dihydroxydiphenyl and(C.sub.3) from 0.5 to 5 mol % of(C.sub.31) 2,7-dihydroxynaphthalene and/or(C.sub.32) 1,3-dihydroxybenzene and/or(C.sub.33) and aromatic dihydroxy compound of the general formula I ##STR1## where X is --CH.sub.2 --, --C(CH.sub.3).sub.2 --, --S--, --SO.sub.2 --, --O-- or --CO--, and/or(C.sub.34) a compound of the general formula II ##STR2## where Y is NH.sub.2 or OH, the molar ratio of C.sub.1 to C.sub.2 being from 0.1:1 to 2.67:1 and the molar ratio of B to C being from 0.9:1 to 1.1:1.

    摘要翻译： 全芳香族热致聚酯基于（A）30〜60摩尔％的4-羟基苯甲酸，（b）20〜35摩尔％的（B1）对苯二甲酸和（B2）间苯二甲酸的混合物，摩尔比 的B1〜B2为1.04:1〜19:1，（C）20〜35摩尔％的（C1）氢醌，（C2）4,4'-二羟基联苯和（C3）的混合物为0.5〜5 （C31）2,7-二羟基萘和/或（C32）1,3-二羟基苯和/或（C33）和通式I的芳族二羟基化合物（I）的摩尔％，其中X是-CH 2 - -C（CH 3）2 - ， - S-，-SO 2 - ， - O-或-CO-，和/或（C 34）通式II的化合物其中Y是NH 2或OH， C1与C2的摩尔比为0.1：1至2.67：1，B与C的摩尔比为0.9：1至1.1：1。

    Self-extinguishing thermoplastic polyester molding materials
    39.
    发明授权
    Self-extinguishing thermoplastic polyester molding materials 失效
    自熄性热塑性聚酯成型材料

    公开(公告)号：US4672086A

    公开(公告)日：1987-06-09

    申请号：US803585

    申请日：1985-12-02

    申请人： Erhard Seiler ,  Juergen Hambrecht ,  Gerhard Heinz

    发明人： Erhard Seiler ,  Juergen Hambrecht ,  Gerhard Heinz

    IPC分类号： C08K3/32 ,  C08K13/02 ,  C08L67/02 ,  C08K5/53 ,  C08K5/52

    CPC分类号： C08K3/32 ,  C08K13/02 ,  C08L67/02

    摘要： Self-extinguishing thermoplastic polyester molding materials containing linear aromatic polyesters, polyphenylene ethers and additives containA. from 20 to 50% by weight of polyethylene terephthalate and/or polybutylene terephthalate, as much as 20 mol % of which may be modified with other dicarboxylic acids and/or diols,B. from 10 to 40% by weight of one or more polyphenylene ethers,C. from 5 to 15% by weight of one or more alkali metal or alkaline earth metal phosphates, high-boiling phosphoric acid esters, phosphorous acid esters, phosphinic acid esters or phosphonous acid esters or organic phosphine oxides,D. from 5 to 30% by weight of framework-forming fillers,E. from 0 to 30% by weight of one or more aromatic polycarbonates,F. from 0 to 30% by weight of glass fibers,G. from 0 to 20% by weight of one or more elastomeric polymers,H. from 0 to 20% by weight of one or more styrene polymers, the percentages of components A to H summing to 100, andI. if required, additives in effective amounts.

    摘要翻译： 含有线性芳族聚酯，聚苯醚和添加剂的自熄性热塑性聚酯成型材料含有A.20至50重量％的聚对苯二甲酸乙二醇酯和/或聚对苯二甲酸丁二醇酯，多达20摩尔％可用其它二羧酸改性 和/或二醇，B。10至40重量％的一种或多种聚苯醚，C.5至15重量％的一种或多种碱金属或碱土金属磷酸盐，高沸点磷酸酯，磷 酸酯，次膦酸酯或膦酸酯或有机膦氧化物，D为5至30重量％的骨架形成填料，E为0至30重量％的一种或多种芳族聚碳酸酯，F为0 至30重量％的玻璃纤维，G.0.0至20重量％的一种或多种弹性体聚合物，H为0至20重量％的一种或多种苯乙烯聚合物，组分A至H的百分比相对于 100和I.如果需要，添加剂 有效量。