摘要:
Improvements in the treatment of wells that penetrate subterranean formations are accomplished through the use of a polymer solution which includes a neutralized ionomeric polymer dissolved in an organic solvent and a polar cosolvent. The polymer has a backbone that is substantially soluble in the organic solvent and pendant ionomeric groups that are substantially insoluble in the organic solvent. The polar cosolvent solubilizes the pendant ionomeric groups such that the polymer solution upon introduction into the well has a viscosity less than about 20,000 centipoises and upon mixing with water the polar cosolvent is taken up by the water causing the polymer to aggregate and increase in viscosity sufficient to form a plug. The polymer solution may be used in well drilling operations, well completion operations, and secondary recovery operations.
摘要:
This invention relates to plasticized metal neutralized sulfonated EPDM terpolymers having at least 65 wt. % of ethylene in the backbone of the EPDM terpolymer and extended compositions of these metal neutralized sulfonated EPDM terpolymers having 100 parts of a neutralized sulfonated EPDM terpolymer; less than about 100 parts per hundred of a non-polar process oil; less than about 300 parts per hundred of a filler; and a preferential plasticizer at about less than 60 parts per hundred based on 100 parts of the sulfonated elastomeric polymer. These compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment, especially on low pressure injection molding and extrusion equipment into elastomeric articles having improved physical properties.
摘要:
A process is disclosed for fabricating a thermoplastic, which thermoplastic is either a thermoplastic ionomer or a multiphase graft or block copolymer of the ABA (AB).sub.n, or ##STR1## wherein n is greater than 1 and wherein the polymer blocks, A and B, are each thermoplastic resins having softening points substantially above room temperature with the B block being present in at least about 30 wt. % of the total polymer. The thermoplastic composition is first suspended in finely divided form in a liquid medium in a sufficient amount such that the solids content of the resulting suspension is in the range of from about 15 to about 75 wt. %. The liquid medium must be nonvolatile and must be capable of plasticizing the B block (or the backbone if the ionomer is employed) of the thermoplastic composition above the softening point of that block but must not be capable of plasticizing the A block to a substantial extent. The suspension is then applied as a coating to any desired surface, e.g., to wire, textiles, the interior of a mold, etc., and that surface is heated to a temperature at least 5.degree. above the softening point of either polymer block thereby solidifying the composition in the shape of said surface. The process is useful in wire coatings, coatings on textiles, preparation of leather-like upholstery, flexible sheets, toys, etc.
摘要:
A process is disclosed for fabricating a thermoplastic, which thermoplastic is either a thermoplastic ionomer or a multiphase graft or block copolymer of the ABA. (AB).sub.n, or ##STR1## wherein n is greater than 1 and wherein the polymer blocks, A and B, are each thermoplastic resins having softening points substantially above room temperature with the B block being present in at least about 30 wt. % of the total polymer. The thermoplastic composition is first suspended in finely divided form in a liquid medium in a sufficient amount such that the solids content of the resulting suspension is in the range of from about 15 to about 75 wt. %. The liquid medium must be nonvolatile and must be capable of plasticizing the B block (or the backbone if the ionomer is employed) of the thermoplastic composition above the softening point of that block but must not be capable of plasticizing the A block to a substantial extent. The suspension is then applied as a coating to any desired surface, e.g., to wire, textiles, the interior of a mold, etc., and that surface is heated to a temperature at least 5.degree. above the softening point of either polymer block thereby solidifying the composition in the shape of said surface. The process is useful in wire coatings, coatings on textiles, preparation of leather-like upholstery, flexible sheets, toys, etc.
摘要:
A process is disclosed for fabricating a thermoplastic, which thermoplastic is either a thermoplastic ionomer or a multiphase graft or block copolymer of the ABA, (AB).sub.n, or ##STR1## wherein n is greater than 1 and wherein the polymer blocks, A and B, are each thermoplastic resins having softening points substantially above room temperature with the B block being present in at least about 30 wt. % of the total polymer. The thermoplastic composition is first suspended in finely divided form in a liquid medium in a sufficient amount such that the solids content of the resulting suspension is in the range of from about 15 to about 75 wt. %. The liquid medium must be nonvolatile and must be capable of plasticizing the B block (or the backbone if the ionomer is employed) of the thermoplastic composition above the softening point of that block but must not be capable of plasticizing the A block to a substantial extent. The suspension is then applied as a coating to any desired surface, e.g., to wire, textiles, the interior of a mold, etc., and that surface is heated to a temperature at least 5.degree. above the softening point of either polymer block thereby solidifying the composition in the shape of said surface. The process is useful in wire coatings, coatings on textiles, preparation of leather-like upholstery, flexible sheets, toys, etc.
摘要:
This invention relates to blends of sulfonated elastomers with crystalline polyolefins. The sulfonated elastomer comprises from about 0.2 to about 20 mole percent sulfonate groups, at least 95% of which are combined with metal counter ions selected from the group consisting of Groups I and II of the Periodic Table of the Elements, aluminum, and lead; organic amines; and mixtures thereof. The crystalline polyolefin is preferably selected from the group consisting of polyethylene, including high and low density polyethylenes, and polypropylene. The crystalline polyolefin comprises a minor portion of said blends.
摘要:
Hydrocarbyl substituted C.sub.4 to C.sub.10 monounsaturated dicarboxylic acid, anhydrides or esters, e.g. polyisobutenyl succinic anhydride, preferably made by reacting polymer of C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 1500 to 5,000, preferably with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 1.05 to 1.25 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting materials are useful per se as oil additives, or may be further reacted with amines, alcohols, amino alcohols, boric acid, etc. to form dispersants.
摘要:
Novel dispersant mixtures are provided, having improved lubricating oil performance characteristics, comprising nitrogen or ester containing dispersants selected from the group consisting of oil soluble salts, amides, imides, oxazoline and esters or mixtures thereof, wherein a first dispersant comprises a long chain hydrocarbon substituted mono- and dicarboxylic acid or their anhydrides derived from polymers of C.sub.2 to C.sub.10 monoolefins wherein the polymer has a number average molecular weight of at least about 1300 and wherein the second dispersant component is derived from such polymers having a number average molecular weight of from about 700 to 1150. The relatively high molecular weight dispersant is provided with from about 1.05 to 1.25 moles per mole of polyolefin of an alpha or beta unsaturated C.sub.4 to C.sub.10 dicarboxylic acid or anhydride or ester thereof. The relatively lower molecular weight dispersant is provided with from about 1.2 to 2.0 moles per mole of polyolefin of an alpha or beta unsaturated C.sub.4 to C.sub.10 dicarboxylic acid, anhydride or ester thereof. It has been found that mixtures of such high molecular weight-low functionality dispersants and low molecular weight-high functionality dispersants provides a dispersant, suitable for use in oleaginous materials such as lubricating oils, which provide surprisingly improved engine performance properties.
摘要:
A succinimide dispersant, which is the reaction product of hydrocarbons or polymers functionalized by halogenation (e.g. chlorination), thermal "ene" reaction or free radical grafting and derivatized with a heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.
摘要:
EPDM elastomer is sulfonated and neutralized by a bulk process involving mechanical mixing at low temperatures in the sulfonating and neutralizing steps. The EPDM is discharged from the mixing process as finely divided particles having a low bulk density.