公开(公告)号：US5260354A

公开(公告)日：1993-11-09

申请号：US847966

申请日：1992-03-06

申请人： Alan J. Kaylo ,  Jerome A. Seiner ,  Edward E. McEntire ,  V. Eswarakrishnan

发明人： Alan J. Kaylo ,  Jerome A. Seiner ,  Edward E. McEntire ,  V. Eswarakrishnan

IPC分类号： C09D5/44 ,  C09D7/12 ,  C09D163/00 ,  C25D13/06 ,  C25D13/10 ,  C08L63/00

CPC分类号： C09D5/4492

摘要： An additive for cationic electrodepositable coating compositions is disclosed which improves hiding ability, stability, rheology and oil spot resistance. The additive is present in amounts of between 0.5 to 40 weight percent and is prepared by polymerizing in aqueous medium, under free radically initiated conditions, an aqueous dispersion of a polymerizable, ethylenically unsaturated monomer composition in the presence of a cationic polymeric surface active substance. The coating composition additionally has between 60 to 99.5 weight percent of a cationic salt group containing film forming polymer. Also disclosed is a method for coating which includes electrodepositing the above composition on an electrically conductive cathode.

摘要翻译： 公开了用于阳离子电沉积涂料组合物的添加剂，其改进了遮盖能力，稳定性，流变性和耐油斑性。 该添加剂以0.5至40重量％的量存在，并且通过在自由基引发的条件下在水性介质中聚合，在阳离子聚合物表面活性物质存在下将可聚合的烯属不饱和单体组合物的水分散体制备。 涂料组合物另外具有60至99.5重量％的含阳离子盐基的成膜聚合物。 还公开了一种涂覆方法，其包括在导电阴极上电沉积上述组合物。

公开(公告)号：US5070119A

公开(公告)日：1991-12-03

申请号：US666951

申请日：1991-03-11

申请人： Richard M. Nugent, Jr. ,  Thomas A. Ward ,  Paul D. Greigger ,  Jerome A. Seiner

发明人： Richard M. Nugent, Jr. ,  Thomas A. Ward ,  Paul D. Greigger ,  Jerome A. Seiner

IPC分类号： C08K13/02 ,  C09D5/18 ,  C09K21/04 ,  C09K21/12

CPC分类号： C09K21/12 ,  C08K13/02 ,  C09D5/185 ,  C09K21/04 ,  Y10S521/907

摘要： Disclosed is an intumescent curable composition which contains as a resinous binder a flexible polyepoxide resin. The polyepoxide is cured with an appropriate curing agent adapted for the particular resin. An additive component is present which contains a mixture of materials which provide a source of(i) zinc,(ii) boron,(iii) phosphorus, and(iv) an expansion gas upon thermal decomposition. The composition is capable of forming a carbonaceous char upon exposure to heat or flame, with the proviso that the cured, unburned composition has sufficient flexibility that it passes at least 10 continuous cycles of a cold cycle test without cracking. The cold cycle test involves the following steps; the composition is applied at a thickness of 0.5 inch (12.7 millimeters) to a 10 inch (0.254 meter) section of a 4W13 I-beam having two thermocouples attached to the surface, allowed to cure at ambient temperature for 16 hours, force cured for 5 days at about 60.degree. C. an subjected to the cold cycle test. For one cycle, the beam is placed in a freezer operating at a temperature between about 0.degree. F. (-18.degree. C.) and about -10.degree. F. (-23.degree. C.) for sufficient time for the steel to reach a temperature between about 0.degree. F. (-18.degree. C.) and about (-10.degree. F.) -23.degree. C. as determined by the two thermocouples attached to the surface of the beam beneath the coating, removed from the freezer and a 50 square inch area 0.0323 square meter) of the surface warmed as shown in FIGS. 1 and 2 by passing a heat gun (Model No. HG 50146, Alpha Division of Loral Corp, 14 amp; minimum temperature at tip 500.degree. F. (260.degree. C.) a distance of 0.5 inch (12.7 millimeter) from the surface, uniformly over the surface until the surface temperature reaches 110.degree. F. (43.degree. C.) within a 3 minute period, as determined by a thermocouple moved about the surface and allowed to stand for at least 2 hours at ambient temperature.

公开(公告)号：US4760111A

公开(公告)日：1988-07-26

申请号：US119124

申请日：1987-11-10

申请人： Ronald R. Ambrose ,  Delano R. Eslinger ,  Jerome A. Seiner

发明人： Ronald R. Ambrose ,  Delano R. Eslinger ,  Jerome A. Seiner

IPC分类号： C08G18/67 ,  C08G18/68 ,  C09D175/14

CPC分类号： C08G18/6715 ,  C08G18/675 ,  C08G18/68 ,  C09D175/14

摘要： Disclosed herein are allylether-functional unsaturated polyester-urethanes and curable compositions containing the same.

摘要翻译： 本文公开的是烯丙基醚官能的不饱和聚酯 - 聚氨酯和含有它们的可固化组合物。

公开(公告)号：US4572869A

公开(公告)日：1986-02-25

申请号：US488099

申请日：1974-07-12

申请人： Marco Wismer ,  Jerome A. Seiner

发明人： Marco Wismer ,  Jerome A. Seiner

IPC分类号： B01J13/02 ,  C08L101/00 ,  C09C3/00 ,  C09D7/00 ,  C09D5/00

CPC分类号： C09D7/005 ,  B01J13/025 ,  C08L101/00 ,  Y10S521/92 ,  Y10T428/2989

摘要： Air-containing microcapsular opacifiers, optionally containing pigment particles incorporated in the microcapsular structure, have substantially continuous, organic polymeric solid walls and a particle diameter of about 0.5 micron to about 10 microns, e.g., less than 1 or 2 microns. The opacifiers are produced by heating precursor microcapsules containing a liquid core material to a temperature sufficient to substantially drive off the core material from the precursor microcapsules and replace it with air.

摘要翻译： 任选含有掺入微胶囊结构中的颜料颗粒的含空气微胶囊遮光剂具有基本上连续的有机聚合物固体壁和约0.5微米至约10微米，例如小于1微米或2微米的粒径。 通过将含有液体核心材料的前体微胶囊加热到足以基本上从前体微胶囊驱除核心材料的温度并用空气替代来制造遮光剂。

公开(公告)号：US4526910A

公开(公告)日：1985-07-02

申请号：US529312

申请日：1983-09-06

申请人： Suryya K. Das ,  Paul P. Greigger ,  William G. Boberski ,  James E. Jones ,  Raymond F. Schappert ,  Jerome A. Seiner

发明人： Suryya K. Das ,  Paul P. Greigger ,  William G. Boberski ,  James E. Jones ,  Raymond F. Schappert ,  Jerome A. Seiner

IPC分类号： C09D7/12 ,  C08K3/36

CPC分类号： C09D7/1266 ,  C09D7/1225 ,  C08K3/36

摘要： Disclosed is an essentially solvent-based, organic, high-solids coating composition containing (A) a film-forming binder system containing a crosslinkable resin having a weight average molecular weight of from about 500 to about 10,000; (B) substantially colorless, substantially inorganic microparticles stably dispersed in the coating composition; and (C) a solvent system for the crosslinkable resin. The substantially inorganic microparticles prior to incorporation in the coating composition range in size from about 1 to about 150 nanometers and are in the form of a sol of the microparticles in which the surface of the inorganic microparticles is essentially free of carbon-containing molecules chemically bonded to the inorganic microparticles.

摘要翻译： 公开了一种基本上溶剂的有机高固含量涂料组合物，其包含（A）含有重均分子量为约500至约10,000的交联性树脂的成膜粘合剂体系; （B）稳定分散在涂料组合物中的基本上无色的，基本上无机的微粒; 和（C）可交联树脂的溶剂体系。 在掺入涂料组合物中之前，基本上无机微粒的尺寸范围为约1至约150纳米，并且为微粒溶胶的形式，其中无机微粒的表面基本上不含化学键合的含碳分子 到无机微粒。

公开(公告)号：US4501821A

公开(公告)日：1985-02-26

申请号：US518161

申请日：1983-07-28

申请人： Robert B. Hodek ,  Jerome A. Seiner

发明人： Robert B. Hodek ,  Jerome A. Seiner

IPC分类号： C08G18/12 ,  C08G69/20 ,  C08F4/50

CPC分类号： C08G69/20 ,  C08G18/12

摘要： A catalyst and initiator composition for lactam polymerization is composed of a Grignard catalyst for lactam polymerization and initiator system containing(a) at least one material represented by the following structural formula: ##STR1## (b) at least one material represented by the following structural formula: ##STR2## wherein q and v are independently an integer of at least 1; Z and W are independently selected from a compound or polymeric material, said compound being composed of at least two elements in chemical combination which contain up to two repeating structural units, said polymeric material being a macromolecule formed by the chemical union of at least two coreactants and having at least three repeating structural units; with the proviso that at least a portion of either or both of the materials (a) or (b) is a polymeric material. In the above formulas, R, R', R", R'" are independently hydrogen, a C.sub.1 to C.sub.10 aliphatic radical, C.sub.3 to C.sub.10 cycloaliphatic radical, C.sub.6 to C.sub.10 aryl or alkaryl radical, and independently R and R" and the carbon to which each is attached are included as part of a cycloaliphatic or aromatic ring; and Y is an alkylene group having from 3 to 12 carbon atoms or an alkylene group having from 3 to 12 carbon atoms interrupted by a heteroatom. In addition the equivalent ratio of ##STR3## to th magnesium of the Grignard catalyst is within the range of from 0.3 to 1 to 4 to 1, and at least 10 percent of the initiator groups of initiator system are of the (a) type.

摘要翻译： 用于内酰胺聚合的催化剂和引发剂组合物由用于内酰胺聚合的格利雅催化剂和引发剂体系组成，其包含（a）由以下结构式表示的至少一种材料：（b）至少一种由以下结构 式：其中q和v独立地为至少1的整数; Z和W独立地选自化合物或聚合物材料，所述化合物由至少两种化学组合元素组成，其中含有至多两个重复结构单元，所述聚合物材料是由至少两种共反应物的化学结合形成的大分子 并具有至少三个重复结构单元; 条件是材料（a）或（b）中的一种或两种的至少一部分是聚合材料。 在上式中，R，R'，R“，R”'独立地为氢，C1至C10脂族基，C3至C10脂环族基，C6至C10芳基或烷芳基，独立地R和R“ 并且每个所连接的碳被包括作为脂环族或芳香环的一部分; Y为碳原子数3〜12的亚烷基或碳原子数为3〜12的亚烷基，被杂原子间隔开。 此外，格氏催化剂的与镁的当量比在0.3至1至4至1的范围内，并且至少10％的引发剂体系的引发剂基团为（a）型。

公开(公告)号：US4383866A

公开(公告)日：1983-05-17

申请号：US407021

申请日：1982-08-11

申请人： Peter M. Nowakowski ,  William G. Boberski ,  Jerome A. Seiner

发明人： Peter M. Nowakowski ,  William G. Boberski ,  Jerome A. Seiner

IPC分类号： C04B20/10 ,  C04B22/16 ,  C09D1/02 ,  C09C3/06

CPC分类号： C04B20/1055 ,  C04B22/16 ,  C09D1/02 ,  Y10T428/2991

摘要： Disclosed is a metal condensed phosphate comprising a core of metal condensed phosphate and a coating on the core comprising a reaction product of a metallate and acid. The amount of the reaction product comprising the coating generally ranges from about 0.1 percent to about 50 percent by weight based on the combined weight of the metal condensed phosphate and the reaction product.Also disclosed is a method of preparing a coated, metal condensed phosphate comprising combining an aqueous slurry of metal condensed phosphate with an aqueous metallate while maintaining the pH of the slurry in a range of from about 4 to about 10.

摘要翻译： 公开了一种金属缩合磷酸盐，其包含金属缩合磷酸盐的核心和核心上的包衣，其包含金属盐和酸的反应产物。 基于金属缩合磷酸盐和反应产物的总重量，包含涂层的反应产物的量通常为约0.1重量％至约50重量％。 还公开了一种制备涂覆的金属缩合磷酸盐的方法，包括将金属缩合磷酸盐的水性浆料与含水金属盐组合，同时将浆料的pH保持在约4至约10的范围内。

公开(公告)号：US4327008A

公开(公告)日：1982-04-27

申请号：US221146

申请日：1980-12-29

申请人： Karl F. Schimmel ,  Jerome A. Seiner ,  Roger M. Christenson ,  Rostyslaw Dowbenko

发明人： Karl F. Schimmel ,  Jerome A. Seiner ,  Roger M. Christenson ,  Rostyslaw Dowbenko

IPC分类号： C08G18/28 ,  C08G18/30 ,  C08G18/66 ,  C08G18/71 ,  C08G18/72 ,  C09D7/00 ,  C08G18/12 ,  C08G18/48

CPC分类号： C08G18/6666 ,  C08G18/2805 ,  C08G18/302 ,  C08G18/6677 ,  C08G18/71 ,  C08G18/721 ,  C09D7/002 ,  C08L75/04

摘要： Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate, water and a monofunctional active hydrogen-containing compound or monoisocyanate. The modifiers are characterized by having a branched structure, urea linkages and terminal hydrophobic groups.

摘要翻译： 可用于水基和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能材料，二异氰酸酯，水和单官能活性氢化合物或单异氰酸酯的反应。 改性剂的特征在于具有支链结构，脲键和末端疏水基团。

公开(公告)号：US4298511A

公开(公告)日：1981-11-03

申请号：US174479

申请日：1980-08-01

申请人： Karl F. Schimmel ,  Jerome A. Seiner ,  Rostyslaw Dowbenko ,  Roger M. Christenson

发明人： Karl F. Schimmel ,  Jerome A. Seiner ,  Rostyslaw Dowbenko ,  Roger M. Christenson

IPC分类号： C09K3/00 ,  B01F17/52 ,  C08G18/00 ,  C08G18/30 ,  C08G18/65 ,  C08G18/66 ,  C08G18/72 ,  C09D7/00 ,  C09D7/12 ,  C08G18/48

CPC分类号： C09D7/002 ,  C08G18/302 ,  C08G18/6666 ,  C08G18/6677 ,  C08G18/721 ,  C08L75/04

摘要： Rheology modifiers useful in water-and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate and water. The modifiers are characterized by having a branched structure and containing substantially no terminal hydrophobic groups.

摘要翻译： 用于水和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能物质，二异氰酸酯和水的反应。 改性剂的特征在于具有支链结构并且基本上不含末端疏水基团。

公开(公告)号：US3951899A

公开(公告)日：1976-04-20

申请号：US151735

申请日：1971-06-10

申请人： Jerome A. Seiner

发明人： Jerome A. Seiner

IPC分类号： C08J9/28 ,  C09D5/02 ,  C09D157/00 ,  C08L9/10 ,  C08L13/02

CPC分类号： C09D5/02 ,  C08J9/28 ,  C09D157/00 ,  C08J2201/048 ,  C08J2201/05 ,  C08J2201/0546

摘要： The disclosed invention relates to films from a novel latex mixture which are non-porous, microcellular and opaque in the absence of an opacifying agent. The preparation of the films of the disclosed invention comprises providing control techniques for entrapping a sufficient amount of a liquid non-solvent for the polymer in the polymer matrix of a latex after the continuous phase removal, so that upon evaporation of the non-solvent from a coalesced and tack-free polymer matrix, a resulting opaque and continuous, non-porous film is produced which will have minute, discrete and substantially closed voids and which is opaque in the absence of an opacifying agent such as pigment.The disclosed invention also relates to opaque films with enhanced optical properties produced by the inclusion of pigments, fluorescent materials and optical brighteners in the opaque films in such a manner as to maximize their effectiveness therein.

摘要翻译： 所公开的发明涉及在不存在不透明剂的情况下来自无孔，微孔和不透明的新型胶乳混合物的膜。 所公开的发明的膜的制备包括提供控制技术，用于在连续除去之后将聚合物的足够量的液体非溶剂包封在胶乳的聚合物基质中，使得当非溶剂从 产生聚结和无粘性的聚合物基质，产生不透明和连续的非多孔膜，其将具有微小的，离散的和基本上闭合的空隙，并且在不存在不透明剂如颜料的情况下是不透明的。