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    Process for the production of middle distillates by hydroisomerisation and hydrocracking feeds from the Fischer-Tropsch process
    33.
    发明授权
    Process for the production of middle distillates by hydroisomerisation and hydrocracking feeds from the Fischer-Tropsch process 有权
    通过费 - 托工艺的加氢异构化和加氢裂化原料生产中间馏分的方法

    公开(公告)号：US07404890B2

    公开(公告)日：2008-07-29

    申请号：US10189738

    申请日：2002-07-08

    申请人： Eric Benazzi ,  Christophe Gueret

    发明人： Eric Benazzi ,  Christophe Gueret

    IPC分类号： C10G47/00 ,  C10G45/58

    CPC分类号： C10G65/12 ,  C10G45/62 ,  C10G47/14 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/06 ,  C10G2400/08

    摘要： The invention concerns a process and apparatus wherein the paraffin effluent from the Fischer-Tropsch process is separated into a heavy fraction with an initial boiling point of 120-200° C., said heavy fraction then optionally being hydrotreated then brought into contact with an amorphous hydroisomerization/hydrocracking catalyst that converts at least 80% by weight of the 370° C.+ products into products with a boiling point of less than 370° C. After distilling the hydrocracked fraction obtained to separate middle distillates, the residual heavy fraction is recycled.

    摘要翻译： 本发明涉及一种方法和设备，其中将来自费 - 托法的石蜡流出物分离成初馏点为120-200℃的重馏分，然后任选加氢处理然后使其与非晶态物质接触 加氢异构化/加氢裂化催化剂，其将370℃+产物的至少80重量％转化成沸点小于370℃的产物。蒸馏得到的加氢裂化馏分分离中间馏分后，将残余重馏分循环 。

    Method for treating a hydrocarbon feedstock including resin removal
    35.
    发明授权
    Method for treating a hydrocarbon feedstock including resin removal 有权
    用于处理包括树脂去除的烃原料的方法

    公开(公告)号：US07582204B2

    公开(公告)日：2009-09-01

    申请号：US10584048

    申请日：2004-12-13

    申请人： Christophe Gueret ,  Raphaël Huyghe ,  Hugues Dulot ,  Patrick Euzen

    发明人： Christophe Gueret ,  Raphaël Huyghe ,  Hugues Dulot ,  Patrick Euzen

    IPC分类号： C10G7/00 ,  C10G21/00 ,  B01D3/00

    CPC分类号： C10G21/14 ,  C10G47/00 ,  C10G67/049 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/44

    摘要： The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage.

    摘要翻译： 本发明涉及一种方法，包括除去树脂，用于处理烃装料，其中至少80％的化合物具有高于或等于340℃的沸点，其中所述装料 送入分馏阶段，在此阶段，回收发生至少一个重馏分和至少一个轻馏分，至少部分重馏分被送至萃取阶段，在此阶段萃取所述重馏分中所含的树脂，以及 回收纯化的馏分，制备包含在萃取阶段获得的至少一部分纯化级分和在分馏阶段获得的至少一种轻馏分的混合物，将得到的混合物送入裂化 阶段。

    Process for the production of middle distillates by hydroisomerisation and hydrocracking feeds from the fischer-tropsch process
    36.
    发明授权
    Process for the production of middle distillates by hydroisomerisation and hydrocracking feeds from the fischer-tropsch process 有权
    通过加氢异构化生产中间馏分和从费 - 托方法加氢裂化原料的方法

    公开(公告)号：US07326331B2

    公开(公告)日：2008-02-05

    申请号：US10189736

    申请日：2002-07-08

    申请人： Eric Benazzi ,  Christophe Gueret

    发明人： Eric Benazzi ,  Christophe Gueret

    IPC分类号： G10G65/14 ,  G10G45/00

    CPC分类号： C10G65/14 ,  C10G65/00

    摘要： The invention concerns a process for producing middle distillates from effluents obtained from the Fischer-Tropsch process, comprising separating a heavy cut with an initial boiling point of 120-200° C., hydrotreating said cut and fractionating the hydrotreated cut to obtain at least one intermediate fraction and at least one fraction that is heavier than the intermediate fraction. The intermediate fraction boils between T1 and T2, T1 being in the range 120-200° C. and T2 being in the range 300-410° C. The heavy and intermediate fractions are treated over a hydrocracking/hydroisomerisation catalyst and the effluents obtained are distilled. The invention also concerns a unit.

    摘要翻译： 本发明涉及从费 - 托方法得到的流出物生产中间馏分的方法，包括分离初馏点为120-200℃的重馏分，加氢处理所述馏分并分馏加氢处理的馏分以获得至少一种 中间馏分和至少一个比中间馏分重的馏分。 中间馏分在T 1和T 2之间沸腾，T 1在120-200℃的范围内，T 2在300-410℃的范围内。重质和中间馏分经加氢裂化/加氢异构化催化剂处理， 所得的流出液被蒸馏。 本发明还涉及一个单元。

    Integrated SDA and ebullated-bed process
    37.
    发明授权
    Integrated SDA and ebullated-bed process 有权
    综合SDA和沸腾床过程

    公开(公告)号：US07279090B2

    公开(公告)日：2007-10-09

    申请号：US11005062

    申请日：2004-12-06

    申请人： James J. Colyar ,  Stéphane Kressmann ,  Christophe Gueret

    发明人： James J. Colyar ,  Stéphane Kressmann ,  Christophe Gueret

    IPC分类号： C10G47/00 ,  C10C3/00

    CPC分类号： C10G67/00 ,  C10G67/0463 ,  C10G67/049 ,  C10G69/02 ,  C10G2400/02 ,  C10G2400/04

    摘要： This invention relates to a novel integrated method for economically processing vacuum residue from heavy crude oils. This is accomplished by utilizing a solvent deasphalter (SDA) in the first step of the process with a C3/C4/C5 solvent such that the DAO product can thereafter be processed in a classic fixed-bed hydrotreater or hydrocracker. The SDA feed also includes recycled stripper bottoms containing unconverted residue/asphaltenes from a downstream steam stripper unit.The asphaltenes from the SDA are sent to an ebullated-bed reactor for conversion of the residue and asphaltenes. Residue conversion in the range of 60-80% is achieved and asphaltene conversion is in the range of 50-70%. The overall residue conversion, with the DAO product considered non-residue, is in the range of 80 W %-90 W % and significantly higher than could be achieved without utilizing the present invention.

    摘要翻译： 本发明涉及一种用于从重质原油经济处理减压渣油的新型综合方法。 这是通过在第一步中使用溶剂脱沥青（SDA）与C 3 N 3 C 4 C 5 C 5溶剂 使得DAO产品此后可以在经典的固定床加氢处理器或加氢裂化器中加工。 SDA进料还包括来自下游蒸汽汽提塔单元的含有未转化的残余物/沥青质的再循环汽提塔底物。 来自SDA的沥青质被送入沸腾床反应器以转化残渣和沥青质。 实现了60-80％范围内的残渣转化率，沥青质转化率在50-70％的范围内。 考虑到非残留物的DAO产物的总残留物转化率在80W％-90W％的范围内，并且显着高于在不利用本发明的情况下可以实现的。

    Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process
    38.
    发明申请
    Process for producing middle distillates by hydroisomerizing and hydrocracking feeds from the Fischer-Tropsch process 有权
    通过费 - 托工艺的加氢异构化和加氢裂化原料生产中间馏分的方法

    公开(公告)号：US20070118008A1

    公开(公告)日：2007-05-24

    申请号：US11638399

    申请日：2006-12-14

    申请人： Patric Euzen ,  Christophe Gueret

    发明人： Patric Euzen ,  Christophe Gueret

    IPC分类号： C07C5/13 ,  B01J21/00 ,  C07C4/08

    CPC分类号： B01J21/12 ,  B01J23/24 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/74 ,  B01J23/85 ,  B01J23/888 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/0093 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/10 ,  B01J37/28 ,  C10G45/00 ,  C10G65/00 ,  C10G65/12 ,  C10G65/18 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2400/06 ,  C10G2400/08

    摘要： The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises 0.2% to 2.5% by weight of an oxide of a doping element selected from boron, phosphorus, silicon, at least one hydrodehydrogenating element selected from the group formed by noble elements from group VIII of the periodic table, a non-zeolitic support based on silica-alumina containing more than 5% by weight and 95% by weight or less of silica (SiO2), a mean pore diameter, measured by mercury porosimetry, in the range 20 to 140 Å, a total pore volume, measured by mercury porosimetry, in the range 0.1 ml/g to 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, in the range 0.1 ml/g to 0.6 ml/g, a BET specific surface area in the range 100 to 550 m2/g, a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 140 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 160 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 200 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, included in pores with a diameter of more than 500 Å, of less than 0.1 ml/g, and with an X ray diffraction diagram which contains at least the characteristic principal peaks of at least one of the transition aluminas included in the group composed of alpha, rho, khi, eta, gamma, kappa, theta and delta aluminas.

    摘要翻译： 本发明涉及一种使用加氢裂化/加氢异构化催化剂由费 - 托合成生产的石蜡原料生产中间馏分的方法，该加氢裂化/加氢异构化催化剂包含0.2-2.5重量％的选自硼，磷，硅， 至少一种选自元素周期表第VIII族的贵金属形成的脱氢元素，基于二氧化硅 - 氧化铝的非沸石载体，其含有多于5重量％和95重量％以下的二氧化硅（SiO 2） 通过水银孔率法测定的平均孔径在20〜140范围内，通过水银孔率法测定的总孔体积在0.1ml / g至0.6ml / g的范围内， 通过氮气孔率法测量的总孔体积为0.1ml / g至0.6ml / g，BET比表面积为100至550m 2 / g，孔体积， 通过水银孔率法测量，包括在直径大于140埃的孔中 通过水银孔率法测量的孔体积为0.1ml / g，包含在直径大于160埃的孔中小于0.1ml / g，通过水银孔率法测量的孔体积，包括在具有直径的孔中 超过200埃，小于0.1ml / g的孔体积，通过水银孔率法测量，包含在直径大于500埃的小于0.1ml / g的孔中，并具有X射线衍射图 其至少包含由α，rho，khi，eta，γ，κ，θ和δ氧化铝组成的组中的至少一种过渡氧化铝的特征主峰。

    Method for the valorization of heavy charges by bubbling-bed deasphalting and hydrocracking
    40.
    发明授权
    Method for the valorization of heavy charges by bubbling-bed deasphalting and hydrocracking 有权
    通过鼓泡床脱沥青和加氢裂化来提高重质荷重的方法

    公开(公告)号：US08636896B2

    公开(公告)日：2014-01-28

    申请号：US12900987

    申请日：2010-10-08

    申请人： Christophe Gueret ,  Stéphane Kressmann ,  Jan Verstraete

    发明人： Christophe Gueret ,  Stéphane Kressmann ,  Jan Verstraete

    IPC分类号： C10G47/02 ,  C10G69/04 ,  C10G69/06

    CPC分类号： C10G69/04 ,  C10G2300/107

    摘要： The invention relates to a method for treating a hydrocarbons charge comprising the following stages, in which: a) the charge is brought into contact with a solvent in order to obtain a deasphalted effluent having a content of asphaltenes below 3000 ppm by weight, b) the deasphalted effluent is cracked in the presence of hydrogen and a hydrocracking catalyst, in a bubbling-bed reactor, so as to convert at least 50 wt. % of the fraction of the deasphalted effluent boiling above 500° C. to compounds having a boiling point below 500° C., c) the effluent from stage b) is fractionated to recover gasolines, kerosene, gas oils and a first residue, and d) at least a portion of this first residue is cracked so as to obtain an effluent comprising gasolines, kerosene, gas oils and a second residue.

    摘要翻译： 本发明涉及一种用于处理含有以下阶段的烃装料的方法，其中：a）使电荷与溶剂接触，以获得沥青质含量低于3000重量ppm的脱沥青流出物，b） 在氢气和加氢裂化催化剂的存在下，在鼓泡床反应器中将脱沥青的流出物裂化，以便将至少50wt。 沸点高于500℃的脱沥青流出物的百分比达到沸点低于500℃的化合物，c）将来自阶段b）的流出物分馏以回收汽油，煤油，瓦斯油和第一残渣，以及 d）该第一残留物的至少一部分被裂化，以获得包含汽油，煤油，瓦斯油和第二残余物的流出物。