摘要:
A semiconductor device and method of making the same includes a first metallization level, a first etch stop layer, a dielectric layer and an opening extending through the dielectric layer and the first etch stop layer. The first etch stop layer is disposed over the first metallization level. Metal within the opening forms a second metal feature, and the metal can comprise copper or a copper alloy. Dopants are introduced into the metal and are activated by laser thermal annealing. A concentration of the dopants within the metal in a lower portion of the second metal feature proximate the first metal feature is greater than a concentration of dopants in a central portion of the second metal feature, and a concentration of the dopants within the metal in an upper portion of the second metal feature is greater than a concentration of dopants in the central portion of the second metal feature.
摘要:
Reliable Cu interconnects are formed by filling an opening in a dielectric layer with Cu and then laser thermal annealing in NH3 to reduce copper oxide and to reflow the deposited Cu, thereby eliminating voids and reducing contact resistance. Embodiments include laser thermal annealing employing an NH3 flow rate of about 200 to about 2,000 sccn.
摘要:
The adhesion of a diffusion barrier or capping layer to a Cu or Cu alloy interconnect member is significantly enhanced by treating the exposed surface of the Cu or Cu alloy interconnect member: (a) under plasma conditions with ammonia and silane or dichlorosilane to form a copper silicide layer thereon; or (b) with an ammonia plasma followed by reaction with silane or dichlorosilane to form a copper silicide layer thereon. The diffusion barrier layer is then deposited on the copper silicide layer. Embodiments include electroplating or electroless plating Cu or a Cu alloy to fill a damascene opening in a dielectric interlayer, chemical mechanical polishing, then treating the exposed surface of the Cu/Cu alloy interconnect to form the copper silicide layer thereon, and depositing a silicon nitride diffusion barrier layer on the copper silicide layer.
摘要:
A method of forming ultra-shallow junctions in a semiconductor wafer forms the gate and source/drain junctions having upper surfaces at first metal suicide regions on the gate and source/drain junctions. These first metal silicide regions have a higher resistivity. Amorphous silicon is deposited on the first metal suicide regions by plasma enhanced chemical vapor deposition (PECVD). The PECVD process may be a lower pressure deposition process, performed at multiple stations to form the amorphous silicon layer in multiple layers. This creates a more uniform amorphous silicon layer across the wafer and different patterning densities, thereby improving device performance and characteristics. Annealing is then performed to form second metal silicide regions of a lower resistivity, by diffusion reaction of the first metal silicide regions and the amorphous silicon that was deposited by the PECVD process.
摘要:
A method of making organic memory cells made of two electrodes with a controllably conductivce media between the two electrodes is disclosed. The controllably conductive media contains an organic semiconductor layer and passive layer. The organic semiconductor layer is formed using spin-on techniques with the assistance of certain solvents.
摘要:
Reliable contacts/vias are formed by sputter etching to flare exposed edges of an opening formed in a dielectric layer, depositing a composite barrier layer and then filling the opening with tungsten at a low deposition rate. The resulting contact/via exhibits significantly reduced porosity and contact resistance. Embodiments include sputter etching to incline the edges of an opening formed in an oxide dielectric layer, e.g., a silicon oxide derived from TEOS or BPSG, at an angle of about 83° to about 86°, depositing a thin layer of Ti, e.g., at a thickness of about 250 Å to about 350 Å, depositing at least one layer of titanium nitride, e.g., three layers of titanium nitride, at a total thickness of about 130 Å to about 170 Å, and then depositing tungsten at a deposition rate of about 1,900 to about 2,300 Å/min to fill the opening.
摘要:
Bridging between nickel silicide layers on a gate electrode and source/drain regions along silicon nitride sidewall spacers is prevented by forming a relatively thick silicon oxide liner on the side surfaces of the gate electrode and adjacent surface of the semiconductor substrate before forming the silicon nitride sidewall spacers thereon. Embodiments include forming a silicon dioxide liner at a thickness of about 200 Å to about 600 Å prior to forming the silicon nitride sidewall spacers thereon.
摘要:
A method for making 0.25-micron semiconductor chips includes annealing the metal interconnect lines prior to depositing an inter-layer dielectric (ILD) between the lines. During annealing, an alloy of aluminum and titanium forms, which subsequently volumetrically contracts, with the contraction being absorbed by the aluminum. Because the alloy is reacted prior to ILD deposition, however, the aluminum is not constrained by the ILD when it attempts to absorb the contraction of the alloy. Consequently, the likelihood of undesirable void formation. in the interconnect lines is reduced. The likelihood of undesirable void formation is still further reduced during the subsequent ILD gapfill deposition process by using relatively low bias power to reduce vapor deposition temperature. and by using relatively low source gas deposition flow rates to reduce flow-induced compressive stress on the interconnect lines during ILD formation.
摘要:
Cu diffusion between Cu and Cu alloy interconnect members, e.g., lines, in a silicon oxide inter-layer dielectric is avoided or substantially reduced by converting an upper portion of the silicon oxide inter-layer dielectric between neighboring lines to silicon oxynitride and then depositing a capping layer. Embodiments include filling damascene trenches in a silicon oxide inter-layer dielectric with Cu or a Cu alloy, CMP to effect planarization such that the upper surfaces of the lines are substantially coplanar with the upper surface of the inter-layer dielectric and treating the exposed surfaces with a high strength ammonia plasma to ion bombard the exposed inter line silicon oxide with nitrogen atoms, thereby converting the upper portion to silicon oxynitride, while simultaneously removing or substantially reducing surface oxides on the lines. A silicon nitride capping layer is then deposited.
摘要:
An integrated circuit and manufacturing method therefor is provided having a semiconductor substrate with a semiconductor device. A dielectric layer formed over the semiconductor substrate has an opening provided therein. The dielectric layer is of non-barrier dielectric material capable of being changed into a barrier dielectric material. The dielectric layer around the opening is changed into the barrier dielectric material and the conductor core material is deposited to fill the opening. The conductor core is processed to form a channel for the integrated circuit.