摘要:
A combustion system having a furnace arranged and disposed to receive solid fuel and oxygen and combust the solid fuel and oxygen to form a flue gas. The system includes a heat exchanger arrangement arranged and disposed to receive heat from the flue gas, where the heat exchanger arrangement has a predetermined heat exchange capacity. A water injection arrangement is arranged and disposed to provide water to the flue gas to controllably adjust the flue gas mass flow rate and temperature to provide the predetermined heat exchange capacity.
摘要:
Sulfur dioxide (SO2) is removed from a carbon dioxide feed gas by maintaining the feed gas at elevated pressure(s) in the presence of oxygen (O2), water and NOx for a period of time sufficient to convert SO2 to sulfuric acid and NOx to nitric acid and produce SO2-depleted, NOx-lean carbon dioxide gas. The invention resides in separating the sulfuric and nitric acids from said SO2-depleted, NOx-lean carbon dioxide gas, and then neutralizing the acids by reaction with an alkaline sorbent in an acid/sorbent reactor system to produce sorbent-derive sulfate. The method has particular application in the removal of SO2 and NOx from flue gas produced by oxyfuel combustion of a carbonaceous fuel.
摘要:
A feed gas comprising CO2, H2S and H2 is treated to produce an H2-enriched product and a CO2 product. The feed gas is separated by pressure swing adsorption to provide a stream of the H2-enriched product, and two streams of sour gas depleted in H2 and enriched in H2S and CO2 relative to the feed gas. One of the streams of sour gas is processed in an H2S to elemental sulfur conversion system, in which H2S in the sour gas is converted to elemental sulfur order to obtain a stream of sweetened gas, from which the CO2 product is formed. The other of said streams of sour gas is processed in an oxidation system, in which H2S in the sour gas is oxidized to SOx (SO2 and SO3), the SO2 from the oxidation effluent or sulfuric/sulfurous acid obtained therefrom being introduced into the H2S to elemental sulfur conversion system as a reagent.
摘要:
A gaseous mixture, comprising CO2, H2, H2S and optionally CO, is separated into an H2 or H2 and CO product stream (H2/CO product stream), and a CO2 enriched stream containing at least one combustible component selected from H2S, H2, CO and any additional combustible components present in the gaseous mixture. A support fuel stream, comprising one or more combustible components, is combusted to form a stable flame, and the CO2 enriched stream and flame are contacted in the presence of sufficient O2 to combust all or substantially all of the combustible component(s) present in said CO2 enriched stream. A CO2 product stream is formed from said combustion effluent. The support fuel stream may be generated from the process of generating or separating the gaseous mixture or from the H2/CO product stream. Where the CO2 enriched stream contains H2S, the support fuel stream may also be a stream obtained off-site that comprises H2S.
摘要:
Sulfur dioxide (SO2) is removed from carbon dioxide feed gas comprising SO2 as a contaminant by maintaining the carbon dioxide feed gas at an elevated pressure in contact with an alkaline sorbent for a period of time sufficient to react said alkaline sorbent with SO2. Where NOx, oxygen (O2) and water are also present, not only is the rate of reaction with the sorbent increased, but also additional SO2 is removed by conversion to sulfuric acid, and NOx is removed as nitric acid. The method has particular application in the removal of SO2 and NOx from flue gas produced by oxyfuel combustion of a hydrocarbon or carbonaceous fuel.
摘要:
A combustion system having a furnace arranged and disposed to receive solid fuel and oxygen and combust the solid fuel and oxygen to form a flue gas. The system includes a heat exchanger arrangement arranged and disposed to receive heat from the flue gas, where the heat exchanger arrangement has a predetermined heat exchange capacity. A water injection arrangement is arranged and disposed to provide water to the flue gas to controllably adjust the flue gas mass flow rate and temperature to provide the predetermined heat exchange capacity.
摘要:
A combustion system and method for operating a combustion system, such as a furnace or boiler. The method includes providing a burner system having one or more burner elements configured to combust solid fuel and one or more oxygen providing devices configured to introduce oxygen into the near burner zone of one or more burner flames. A sensor is provided and arranged and disposed to measure a flame parameter in the near burner zone of the burner flame associated with one or more the burner elements. The flame parameter is measured with the sensor and an oxygen flow is determined in response to the measured flame parameter. Oxygen flow is introduced to one or more locations in the combustion system with the one or more oxygen providing devices.
摘要:
A process for adiabatically prereforming a feedstock, includes: providing an adiabatic reactor; providing a catalyst containing 1-20 wt. % nickel and 0.4-5 wt. % potassium, wherein the catalyst has an overall catalyst porosity of 25-50% with 20-80% of the overall catalyst porosity contributed by pores having pore diameters of at least 500 Å; providing the feedstock containing natural gas and steam, wherein the natural gas contains an initial concentration of higher hydrocarbons, and a ratio of steam to natural gas in the feedstock is from 1.5:1 to 5:1; preheating the feedstock to a temperature of 300-700° C. to provide a heated feedstock; providing the heated feedstock to the reactor; and producing a product containing hydrogen, carbon monoxide, carbon dioxide, unreacted methane, and steam, wherein said product contains a reduced concentration of higher hydrocarbons less than the initial concentration of higher hydrocarbons, to prereform the feedstock.
摘要:
A process and apparatus for producing hydrogen from a gaseous mixture of hydrocarbons and steam are disclosed. The process includes first reacting the hydrocarbon gas and steam in the presence of a precious metal catalyst on a structural support and then reacting the resulting gas mixture in the presence of a non-precious metal catalyst. The apparatus includes a vessel having an inlet and an outlet. The precious metal catalyst is supported on the structural support positioned at the inlet. The non-precious metal catalyst is supported on a support medium positioned between the structural support and the outlet. The support medium may be a granular medium or a structural support.
摘要:
A system for detecting fine liquid, e.g., oil, particles in a gas system having a high pressure compressor and at least two gas handling devices, e.g., a coalescer and at least one adsorber. The detection system uses plural sensors and a monitor unit to detect the presence of such fine liquid particles in various portions of the gas system and to provide alert signals in response thereto. The alert signals can be used by associated valves to control the gas system.