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公开(公告)号：US4191705A
公开(公告)日：1980-03-04
申请号：US845174
申请日：1977-10-25
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
CPC分类号： C08G63/64 , C08G63/916
摘要： The present invention relates to a process for the preparation of carbonic acid esters of polyester-polyols by transesterifying the polyols with carbonic acid aryl esters at elevated temperatures under vacuum in the presence of a catalyst. The reaction conditions are controlled to avoid the formation of by-products and the chain extension of the polyester-polyols. The present invention is also concerned with the polyester carbonic acid esters so formed, their use in producing polycarbonate block copolymers and the copolymers so produced. The copolymers may be produced by transesterifying the polyester carbonic acid esters with bisphenols and subjecting the bis-hydroxyaryl carbonates so formed to normal polycarbonate synthesis such as interfacial or melt polycondensation.
摘要翻译： 本发明涉及一种通过在催化剂存在下在真空下在升高的温度下将多元醇与碳酸芳酯酯交换而制备聚酯多元醇的碳酸酯的方法。 控制反应条件以避免副产物的形成和聚酯多元醇的链延长。 本发明还涉及如此形成的聚酯碳酸酯，它们在生产聚碳酸酯嵌段共聚物中的用途以及如此制备的共聚物。 共聚物可以通过将聚酯碳酸酯与双酚酯交换并使如此形成的双羟基芳基碳酸酯进行正常的聚碳酸酯合成如界面或熔融缩聚来制备。
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32.发明授权Process for preparing acrylonitrile/vinyl chloride copolymers having an increased viscosity which comprises using anionic/non-ionic emulsifier blends 失效制备具有增加的粘度的丙烯腈/氯乙烯共聚物的方法，其包括使用阴离子/非离子乳化剂共混物
公开(公告)号：US4100339A
公开(公告)日：1978-07-11
申请号：US765307
申请日：1977-02-03
申请人： Joachim Konig , Carlhans Suling , Gunther Boehmke
发明人： Joachim Konig , Carlhans Suling , Gunther Boehmke
IPC分类号： C08F214/00 , C08F2/00 , C08F2/24 , C08F2/26 , C08F14/00 , C08F214/06 , C08F220/00 , C08F220/42
CPC分类号： C08F214/06
摘要： The invention relates to a process for the production of chemically uniform copolymers of acrylonitrile and vinyl chloride and, optionally, other copolymerizable ethylenically unsaturated compounds, by the method of emulsion polymerization in the presence of an anion active emulsifier and a non-ionic emulsifier.
摘要翻译： 本发明涉及通过在阴离子活性乳化剂和非离子乳化剂的存在下通过乳液聚合的方法生产丙烯腈和氯乙烯的化学均匀共聚物和任选的其它可共聚的烯属不饱和化合物的方法。
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公开(公告)号：US3936556A
公开(公告)日：1976-02-03
申请号：US442177
申请日：1974-02-13
IPC分类号： D02G3/00 , C08J7/12 , D01D11/00 , D03J1/06 , D04B35/36 , D04H13/00 , D06H1/00 , D06H1/02 , D06M15/285 , D06P1/12 , D06P1/44 , D06P3/00 , D06P5/13 , D06P5/24 , D21H21/40 , B41M3/14
CPC分类号： D06P5/003 , D06H1/00 , D06M15/285 , D06P1/12 , D06P5/138 , Y10T428/24802 , Y10T442/2779
摘要： A process for identifying manufactured articles in which a marking agent such as a homo- or copolymer of polymerizable ethylenically unsatured monomers is applied to the articles. Said homo- or copolymer contains at least one group which can be split off to form a low molecular weight compound such as an amine or phenol, which can be converted into dyes, said dyes being used to identify the manufactured articles.
摘要翻译： 一种用于识别制品的方法，其中将标记剂如可聚合烯属不饱和单体的均聚物或共聚物施用于制品。 所述均聚物或共聚物含有至少一个可被分离以形成低分子量化合物如胺或苯酚的基团，其可以转化为染料，所述染料用于鉴定制品。
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公开(公告)号：US4997873A
公开(公告)日：1991-03-05
申请号：US355727
申请日：1989-05-22
IPC分类号： B01F17/52 , C08F2/16 , C08F2/22 , C08F2/28 , C08F20/34 , C08F20/52 , C08F212/00 , C08F212/08 , C08F220/24 , C08F220/34 , C08F220/60 , C08F265/00 , C08F267/06 , D06M13/02 , D06M13/07 , D06M13/224 , D06M13/236 , D06M13/322 , D06M13/402 , D06M13/41 , D06M15/277 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/34
CPC分类号： C08F220/24 , C08F265/00 , D06M15/277
摘要： Aqueous dispersions of copolymers and graft copolymers which are formed from ethylenically unsaturated perfluoroalkyl monomers and ethylenically unsaturated monomers from from perfluoroalkyl groups and which are prepared in the presence of emulsifiers containing cationic groups are used for imparting a water-repellent and oleo-repellent finish to textiles, leather and paper.
摘要翻译： 由烯属不饱和全氟烷基单体和烯属不饱和单体由全氟烷基形成并且在含有阳离子基团的乳化剂存在下制备的共聚物和接枝共聚物的水分散体用于赋予纺织品拒水拒油 ，皮革和纸张。
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公开(公告)号：US4879402A
公开(公告)日：1989-11-07
申请号：US072467
申请日：1987-07-10
IPC分类号： A61K6/08 , A61K6/083 , A61K6/09 , C07C67/00 , C07C239/00 , C07C269/02 , C07C271/16 , C07C271/20 , C07C271/24 , C07C271/26 , C08F20/10 , C08F20/34 , C08F20/36 , C08G18/67
CPC分类号： A61K6/0017 , A61K6/09 , C08F20/36 , C08G18/673 , Y10S525/92
摘要： The new (meth)acrylic acid derivatives containing urethane groups can be prepared by reaction of a (meth)acrylic acid ester with diisocyanates and subsequent reaction with polyols. The compounds can be used for dental materials.
摘要翻译： 含有氨基甲酸酯基的新的（甲基）丙烯酸衍生物可以通过（甲基）丙烯酸酯与二异氰酸酯反应并随后与多元醇反应来制备。 这些化合物可用于牙科材料。
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公开(公告)号：US4752338A
公开(公告)日：1988-06-21
申请号：US858402
申请日：1986-05-01
申请人： Jurgen Reiners , Jens Winkel , Erich Klauke , Carlhans Suling , Wolfgang Podszun
发明人： Jurgen Reiners , Jens Winkel , Erich Klauke , Carlhans Suling , Wolfgang Podszun
IPC分类号： C08F20/00 , A61K6/083 , C07C67/00 , C07C239/00 , C07C269/00 , C07C275/32 , C08F20/10 , C08F20/34 , C08F20/36 , C09K3/00 , A61K5/01
摘要： (Meth)-acrylic acid esters of the formula ##STR1## in which R.sup.1 and R.sup.2 are each independently hydrogen, chlorine, fluorine or a C.sub.1 - to C.sub.4 -alkyl radical andR.sup.3 and R.sup.4 are identical or different and represent the group ##STR2## wherein Y is a divalent bridge member from the group ##STR3## and Z is a straight-chain or branched hydrocarbon chain which has 2 to 10 carbon atoms, can optionally contain oxygen bridges and is optionally substituted by 1 to 4 acrylate or methacrylate radicals,whereinR.sup.5 represents hydrogen or methyl andR.sup.6 represents hydrogen, C.sub.1 -C.sub.6 - alkyl or phenyl,which are useful as dental materials.
摘要翻译： （甲基）丙烯酸酯，其中R 1和R 2各自独立地为氢，氯，氟或C 1〜C 4 - 烷基，R 3和R 4相同或不同，表示
其中Y是来自基团的二价桥连构件，Z是具有2至10个碳原子的直链或支链烃链，可以任选地含有氧桥，并且任选被1至4个丙烯酸酯或甲基丙烯酸酯基团取代， 其中R 5表示氢或甲基，R 6表示氢，可用作牙科材料的C 1 -C 6烷基或苯基。 -
公开(公告)号：US4744827A
公开(公告)日：1988-05-17
申请号：US870609
申请日：1986-06-04
申请人： Jens Winkel , Bruno Bomer , Robert Schmitz-Josten , Gerhard Klein , Carlhans Suling , Dieter Arlt
发明人： Jens Winkel , Bruno Bomer , Robert Schmitz-Josten , Gerhard Klein , Carlhans Suling , Dieter Arlt
IPC分类号： C08F20/00 , A61K6/083 , A61K6/09 , C07C67/00 , C07C239/00 , C07C271/16 , C07C275/04 , C08F20/34 , C08F20/36 , C08G18/81 , A61K6/02 , C07C69/52 , C07C125/06
CPC分类号： C08G18/8116 , A61K6/083 , A61K6/09 , C07C271/16 , C08F20/36
摘要： (Meth)-acrylic acid derivatives of tricyclodecanes of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and denote hydrogen, lower alkyl, lower alkoxy, halogen or trifluoromethyl and R.sup.3 and R.sup.4 are identical or different and represent the group ##STR2## wherein X denotes a divalent bridge member from the group ##STR3## and Y denotes a divalent bridge member from the group ##STR4## and wherein R.sup.5 represents hydrogen or methyl and R.sup.6 represents lower alkyl or phenyl, have been found. Dental compositions in which the present (meth)-acrylic acid derivatives of tricyclodecanes are used, exhibit considerably less polymerization shrinkage.
摘要翻译： 其中R1和R2相同或不同并表示氢，低级烷基，低级烷氧基，卤素或三氟甲基的三环癸烷的（甲基） - 丙烯酸衍生物，R 3和R 4相同或不同， 其中X表示来自基团的二价桥连构件，Y表示来自基团+ TR图像的二价桥结构，其中R 5表示氢或甲基，R 6表示低级烷基或苯基， 发现。 使用三环癸烷的本发明（甲基）丙烯酸衍生物的牙科组合物显示出较低的聚合收缩率。
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38.发明授权Cellulose ester-aliphatic polycarbonate thermoplastic moulding compositions 失效纤维素酯 - 脂族聚碳酸酯热塑性成型组合物
公开(公告)号：US4506045A
公开(公告)日：1985-03-19
申请号：US532238
申请日：1983-09-14
CPC分类号： C08L1/10 , C08L69/00 , Y10S525/932
摘要： Thermoplastic moulding compositions consisting of from 1 to 99% by weight of at least one cellulose ester or cellulose mixed ester, from 99 to 1% by weight of an aliphatic polyester or polyether containing carbonate groups and, optionally, standard auxiliaries and additives.
摘要翻译： 由1至99重量％的至少一种纤维素酯或纤维素混合酯，99至1重量％的含有碳酸酯基团的脂族聚酯或聚醚或任选的标准助剂和添加剂组成的热塑性模塑组合物。
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39.发明授权Process for the continuous production of acrylonitrile-vinyl chloride copolymers 失效连续生产丙烯腈 - 氯乙烯共聚物的方法
公开(公告)号：US4446291A
公开(公告)日：1984-05-01
申请号：US818598
申请日：1977-07-25
IPC分类号： C08F214/00 , C08F2/00 , C08F2/22 , C08F2/24 , C08F4/00 , C08F4/40 , C08F14/00 , C08F214/06 , C08F220/00 , C08F220/42 , C08F220/44
CPC分类号： C08F214/06
摘要： The invention relates to a process for the continuous production of a chemically uniform copolymer comprising 15 to 50% by weight of acrylonitrile and from 85 to 50% by weight of vinyl chloride and, optionally, up to 4% by weight of at least one other copolymerized ethylenically unsaturated comonomer containing acid groups by emulsion polymerization, wherein the copolymerization reaction is carried out with a monomer ratio of acrylonitrile to vinyl chloride of from 0.02 to 0.5, in the presence of a redox catalyst and in an acidic medium.
摘要翻译： 本发明涉及一种连续生产化学均匀共聚物的方法，该共聚物包含15至50重量％的丙烯腈和85至50重量％的氯乙烯和任选至多4重量％的至少一种其它 通过乳液聚合共聚的含有烯基的不饱和共聚单体，其中在氧化还原催化剂和酸性介质的存在下，共聚反应以丙烯腈与氯乙烯的单体比为0.02至0.5进行。
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40.发明授权
公开(公告)号：US4369296A
公开(公告)日：1983-01-18
申请号：US243877
申请日：1981-03-16
IPC分类号： C08F2/00 , C08F2/38 , C08F20/14 , C08F120/18
CPC分类号： C08F20/14
摘要： A process for the polymerization of methyl methacrylate or mixtures thereof with up to 25%, by weight, based on total monomer, of vinyl monomers copolymerizable therewith, wherein polymerization is carried out in the presence of from 0.01 to 10%, by weight, based on total monomer, of one or more enol ethers derived from aliphatic or cycloaliphatic aldehydes or ketones.
摘要翻译： 一种聚合甲基丙烯酸甲酯或其混合物的方法，其具有至多25重量％的基于总单体的可与其共聚的乙烯基单体，其中聚合在0.01至10重量％的基础上进行，基于 在一个或多个衍生自脂族或脂环族醛或酮的烯醇醚的总单体上。
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