公开(公告)号：US09731262B2

公开(公告)日：2017-08-15

申请号：US14413316

申请日：2013-07-04

申请人： IMRA EUROPE SAS

发明人： Stephane Bourdais ,  Christophe Chone ,  Yan Cuccaro

IPC分类号： B01F3/00 ,  B01F17/00 ,  B01J13/00 ,  C09K3/00 ,  B01F3/12 ,  B82Y30/00 ,  B82Y40/00 ,  H01L31/0224 ,  H01L31/0296 ,  H01L31/032 ,  H01L31/0368 ,  H01L31/18

CPC分类号： B01J13/0008 ,  B01J13/0013 ,  B01J13/0017 ,  B01J13/0026 ,  B01J13/0039 ,  B82Y30/00 ,  B82Y40/00 ,  H01L31/022425 ,  H01L31/0296 ,  H01L31/0326 ,  H01L31/0368 ,  H01L31/18 ,  H01L31/1828

摘要： The present invention relates to a method for preparing an aqueous or hydro-alcoholic colloidal solution of metal chalcogenide amorphous nanoparticles notably of the Cu2ZnSnS4 (CZTS) type and to the obtained colloidal solution.The present invention also relates to a method for manufacturing a film of large-grain crystallized semi-conducting metal chalcogenide film notably of CZTS obtained from an aqueous or hydro-alcoholic colloidal solution according to the invention, said film being useful as an absorption layer deposited on a substrate applied in a solid photovoltaic device.

公开(公告)号：US20060243943A1

公开(公告)日：2006-11-02

申请号：US11475868

申请日：2006-06-28

申请人： Masahiro Ohmori ,  Akihiko Kotera

发明人： Masahiro Ohmori ,  Akihiko Kotera

IPC分类号： H01L41/18 ,  C04B35/00 ,  B01J23/00 ,  B01J23/02

CPC分类号： B01J21/063 ,  B01J13/0017 ,  B01J13/0047 ,  B01J23/002 ,  B01J23/02 ,  B01J35/002 ,  B01J35/004 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/03 ,  B01J2523/00 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/006 ,  C01G23/0532 ,  C01G23/0536 ,  C01P2002/34 ,  C01P2004/64 ,  C01P2006/12 ,  C04B35/46 ,  C04B35/4682 ,  C04B35/47 ,  H01L41/1871 ,  H01L41/1875 ,  H01L41/317 ,  H01L41/43 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/31989 ,  Y10T428/31993 ,  B01J2523/25 ,  B01J2523/47 ,  B01J2523/24

摘要： A perovskite titanium-containing composite oxide particle has a composition represented by general formula (I), wherein the specific surface area is about 10 to about 200 m2/g, the specific surface area diameter D1 of the primary particles as defined by formula (II) is about 10 to about 100 nm, and the ratio D2/D1 of the average particle size D2 of the secondary particles to D1 is about 1 to about 10: M(TiO3)  (I) (wherein M is at least one of Ca, Sr, Ba, Pb, or Mg) D1=6/ρS  (II) (wherein ρ is the density of the particles, and S is the specific surface area of the particles.) The perovskite titanium-containing composite oxide particle of the present invention shows a small particle size and excellent dispersion properties, so that the particle is suitable for the application to functional materials such as a dielectric material and a piezoelectric material, a memory, and a photocatalyst.

摘要翻译： 钙钛矿型钛系复合氧化物粒子具有通式（I）所示的组成，其比表面积为约10〜约200m 2 / g，比表面积直径D _{1 <1>为约10至约100nm，平均值D 2的比值D 2 / D 1 N 二级颗粒至D 1 N的颗粒尺寸D 2 2为约1至约10：<？in-line-formula description =“In-line Formulas”end =“ 引线“> M（TiO 3）（I）<？在线公式描述=”在线公式“end =”tail“？>（其中M是Ca中的至少一种 ，Sr，Ba，Pb或Mg）<？in-line-formula description =“In-line Formulas”end =“lead”？> D <1> = 6 / rhoS（II） （其中rho是颗粒的密度，S是颗粒的比表面积）。钙钛矿含钛复合氧化物颗粒（“line-formula”）=“In-line Formulas”end =“tail” 的现在 显示出小的粒径和优异的分散性，使得该颗粒适用于功能材料如电介质材料和压电材料，记忆和光催化剂。}

公开(公告)号：US07030165B2

公开(公告)日：2006-04-18

申请号：US10815832

申请日：2004-04-02

申请人： Masahiro Ohmori ,  Akihiko Kotera

发明人： Masahiro Ohmori ,  Akihiko Kotera

IPC分类号： C01G23/00 ,  C01G21/00 ,  C01F11/00 ,  C01F5/00

CPC分类号： B01J21/063 ,  B01J13/0017 ,  B01J13/0047 ,  B01J23/002 ,  B01J23/02 ,  B01J35/002 ,  B01J35/004 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/03 ,  B01J2523/00 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/006 ,  C01G23/0532 ,  C01G23/0536 ,  C01P2002/34 ,  C01P2004/64 ,  C01P2006/12 ,  C04B35/46 ,  C04B35/4682 ,  C04B35/47 ,  H01L41/1871 ,  H01L41/1875 ,  H01L41/317 ,  H01L41/43 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/31989 ,  Y10T428/31993 ,  B01J2523/25 ,  B01J2523/47 ,  B01J2523/24

摘要： A perovskite titanium-containing composite oxide particle have a composition represented by general formula (I), where the specific surface area is about 10 to about 200 m2/g, the specific surface area diameter D1 of the primary particles defined by formula (II) is about 10 to about 100 nm, and a D2/D1 ratio of the average particle size D2 of secondary particles to D1 is about 1 to about 10: M(TiO3)  (I) wherein M is at least one of Ca, Sr, Ba, Pb, or Mg D1=6/ρS  (II) wherein ρ is the density of the particles, and S is the specific surface area of the particles is disclosed. The present invention has a small particle size and excellent dispersion properties, so that the particle is suitable for application to functional materials.

摘要翻译： 钙钛矿型钛系复合氧化物粒子具有通式（I）表示的组成，其比表面积为约10〜约200m 2 / g，比表面积直径D _{D <1> / 6 / rho S（II）<？ -formulae description =“In-line Formulas”end =“tail”？>其中rho是颗粒的密度，S是颗粒的比表面积。 本发明具有小的粒径和优异的分散性，使得该颗粒适用于功能材料。}

公开(公告)号：US20050025958A1

公开(公告)日：2005-02-03

申请号：US10919375

申请日：2004-08-17

申请人： Masahiro Ohmori ,  Akihiko Kotera

发明人： Masahiro Ohmori ,  Akihiko Kotera

IPC分类号： B01J13/00 ,  B01J21/06 ,  B01J23/00 ,  B01J23/02 ,  B01J35/00 ,  B01J37/03 ,  C01G23/00 ,  H01L41/24 ,  B32B5/16 ,  C04B35/46

CPC分类号： B01J21/063 ,  B01J13/0017 ,  B01J13/0047 ,  B01J23/002 ,  B01J23/02 ,  B01J35/002 ,  B01J35/004 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/03 ,  B01J2523/00 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/006 ,  C01G23/0532 ,  C01G23/0536 ,  C01P2002/34 ,  C01P2004/64 ,  C01P2006/12 ,  C04B35/46 ,  C04B35/4682 ,  C04B35/47 ,  H01L41/1871 ,  H01L41/1875 ,  H01L41/317 ,  H01L41/43 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/31989 ,  Y10T428/31993 ,  B01J2523/25 ,  B01J2523/47 ,  B01J2523/24

摘要： A perovskite titanium-containing composite oxide particle having a composition represented by general formula (I), where the specific surface area is about 10 to about 200 m2/g, the specific surface area diameter D1 of primary particles defined by formula (II) is about 10 to about 100 nm, and a D2/D1 ratio of the average particle size D2 of secondary particles to D1 is about 1 to about 10: M(TiO3)  (I) wherein M is at least one of Ca, Sr, Ba, Pb, or Mg, D1=6/ρS  (II) wherein ρ is the density of the particles, and S is the specific surface area of the particles is disclosed. The present invention has a small particle size and excellent dispersion properties, so that the particle is suitable for application to functional materials.

摘要翻译： 具有通式（I）表示的组成的钙钛矿含钛复合氧化物粒子，其比表面积为约10〜约200m 2 / g，由式（1）定义的一次粒子的比表面积直径D1 II）为约10〜约100nm，二次粒子与D1的平均粒径D2的D2 / D1比为约1〜约10:M（TiO 3）（I），其中M为Ca， Sr，Ba，Pb或Mg，D1 = 6 / rhoS（II）其中rho是颗粒的密度，S是颗粒的比表面积。 本发明具有小的粒径和优异的分散性，使得该颗粒适用于功能材料。

公开(公告)号：US4147605A

公开(公告)日：1979-04-03

申请号：US787314

申请日：1977-04-14

申请人： Barry A. Schenker ,  Thomas T. Sugano ,  Neil W. Stillman ,  Kevin J. O'Leary

发明人： Barry A. Schenker ,  Thomas T. Sugano ,  Neil W. Stillman ,  Kevin J. O'Leary

IPC分类号： B01D61/42 ,  B01D61/44 ,  B01D61/50 ,  B01D61/54 ,  B01D63/00 ,  B01D65/08 ,  B01J13/00 ,  B01J19/08 ,  C01B33/141 ,  C01G30/00 ,  C25B1/00 ,  C25D21/16 ,  C25D21/18 ,  B01D13/02

CPC分类号： B01D61/46 ,  B01J13/0017 ,  B82Y30/00 ,  C01B33/141 ,  C01G30/005 ,  B01D2311/18 ,  C01P2004/64

摘要： A method of producing a sol of an element selected from the group consisting silicon, aluminum, antimony, chromium, manganese, molybdenum, tin and tungsten comprising electrodialytically transferring alkali metal cations of an aqueous solution of a water soluble alkali metal salt of the oxide of the said element from an anode compartment of an electrolytic cell to a cathode compartment of the electrolytic cell while essentially preventing the migration of the metal oxide into the cathode compartment by positioning a cation permselective membrane between the anode compartment and the cathode compartment while carefully and continuously controlling the pH of the solution and removing the so-produced sol from the anode compartment of the electrolytic cell as well as a novel electrodialytic cell for sol formation.

摘要翻译： 制备选自硅，铝，锑，铬，锰，钼，锡和钨的元素的溶胶的方法，其包括电渗析转移碱金属阳离子的水溶性碱金属阳离子， 所述元件从电解池的阳极室到电解池的阴极室，同时基本上通过在阳极室和阴极室之间定位阳离子选择性选择膜，同时小心并连续地将金属氧化物迁移到阴极室 控制溶液的pH并从电解池的阳极室除去所产生的溶胶，以及用于溶胶形成的新型电渗析池。

公开(公告)号：US3864142A

公开(公告)日：1975-02-04

申请号：US32300673

申请日：1973-01-12

申请人： NALCO CHEMICAL CO

发明人： KOVARIK JAMES F

IPC分类号： B01J13/00 ,  B01J20/10 ,  B01J20/32 ,  B01J37/30 ,  C01B33/149 ,  C25D5/02 ,  D21H19/38 ,  D21H19/40 ,  D21H21/52

CPC分类号： D21H21/52 ,  B01J13/0017 ,  B01J20/0211 ,  B01J20/0218 ,  B01J20/0229 ,  B01J20/0248 ,  B01J20/0288 ,  B01J20/06 ,  B01J20/103 ,  B01J20/28004 ,  B01J20/28057 ,  B01J20/3204 ,  B01J20/3236 ,  B01J37/30 ,  C01B33/149 ,  C25D5/022 ,  D21H19/385 ,  D21H19/40 ,  Y10S516/928

摘要： A simple process for preparing metallic oxide coated silica sols and pure metallic oxide sols involves dispersing a metallic chloride and the sol, treating with an anion exchange resin, and recovering the product.

摘要翻译： 制备金属氧化物涂覆的硅溶胶和纯金属氧化物溶胶的简单方法包括分散金属氯化物和溶胶，用阴离子交换树脂处理，并回收产物。

公开(公告)号：USRE27697E

公开(公告)日：1973-07-17

申请号：US27697D

申请日：1967-01-05

IPC分类号： B01J13/00

CPC分类号： B01J13/0017 ,  B01J13/0047

摘要： THE INVENTION IS TO A METHOD OF PREPARING A METAL OXIDE CLAD SOL OF A HYDROUS OXIDE OF THORIA, URANIA, PLUTONIA, OR MIXTURES THEREOF, BY ADDING A MONOBASIC ACID SALT OF ZIRCONIUM OR TITANIUM TO AN AQUEOUS DISPERSION OF SAID HYDROUS OXIDE AND THEN CONCENTRATING THE SOLUTION AND PASSING IT THROUGH AN ION EXCHANGE MEMBRANE AND RECOVERING THE METAL OXIDE CLAD SOL.

公开(公告)号：US3715317A

公开(公告)日：1973-02-06

申请号：US3715317D

申请日：1971-06-02

申请人： ATOMIC ENERGY COMMISSION

发明人： LLOYD M ,  TALLENT O ,  LEUZE R

IPC分类号： B01J13/00 ,  C01G56/00

CPC分类号： C01G56/005 ,  B01J13/0017 ,  B01J13/0047 ,  C01P2002/60 ,  C01P2004/50 ,  C01P2006/40

摘要： LOW-NITRATE PLUTONIA SOLS HAVING A NO3/PU MOLE RATIO IN THE RANGE 0.1 TO 0.4 WITH AVERAGE CRYSTALLITE DIAMETERS OF 30 TO 80 A. CAN BE PRODUCED WHEN A SOL IS PREPARED BY SOLVENT EXTRACTION OF A PLUTONIUM NITRATE SEEDED WITH A PLUTONIA SOL. WHEN THE SEEDED SOL IS TAKEN TO DRYNESS AND HEATED FOR 10 TO 120 MINUTES AT A TEMPERATURE IN THE RANGE 190-230* C., NITRATE REMOVAL OCCURS WITH CONCOMITANT CRYSTALLITE GROWTH.

公开(公告)号：US3714056A

公开(公告)日：1973-01-30

申请号：US3714056D

申请日：1971-06-10

申请人： ATOMIC ENERGY COMMISSION

发明人： TALLENT O

IPC分类号： B01J13/00 ,  B01J19/06 ,  C01G56/00 ,  G21C3/62 ,  C01G43/02

CPC分类号： B01J13/0047 ,  B01J13/0017 ,  B01J19/06 ,  C01G56/004 ,  G21C3/623 ,  Y02E30/38

摘要： THE PRESENT INVENTION RELATES TO A METHOD FOR FORMING A STATIC AND DYNAMICALLY STABILIZED MIXED SOL OF PLUTONIA AND URANIA WHERE THE PLUTONIUM AND URANIUM ARE PRIMARILY IN THE +4 OXIDATION STATE AND WHERE THE SOLS ARE DERIVED FROM SOLVENT EXTRACTION OF AQUEOUS SOLUTION OF URANIUM NITRATE AND PLUTONIUM NITRATE WHICH COMPRISES HEATING THE URANIA SOL COMPONENT AT A TEMPERATURE AND FOR A PERIOD OF TIME SUFFICIENT TO PRODUCE URANIA CRYSTAL LITIES IN THE RANGE 55-100 ANGSTROMS AND THEN EXTRACTING NITRATE ION FROM THE MIXED SOL UNTIL A NITRATE/URANIUM + PLUTONIUM MOLE RATIO OF 0.08 TO 0.25 IS OBTAINED AND TO THE RESULTANT SOL.

公开(公告)号：US3256204A

公开(公告)日：1966-06-14

申请号：US25816263

申请日：1963-02-13

申请人： DIAMOND ALKALI CO

发明人： O'CONNOR THOMAS L

IPC分类号： B01J13/00

CPC分类号： B01J13/0047 ,  B01J13/0017 ,  Y10S264/19