公开(公告)号：US6114269A

公开(公告)日：2000-09-05

申请号：US479822

申请日：2000-01-07

Applicant: Stephen Frederic Yates ,  Irene DeFilippi ,  Romulus Gaita ,  Abraham Clearfield ,  Lyudmila Bortun ,  Anatoly Bortun

Inventor： Stephen Frederic Yates ,  Irene DeFilippi ,  Romulus Gaita ,  Abraham Clearfield ,  Lyudmila Bortun ,  Anatoly Bortun

IPC: B01J20/12 ,  B01J39/02 ,  B01J39/08 ,  B01J39/14 ,  C01B33/42 ,  B01J21/16

CPC classification number: B01J39/085 ,  B01J20/12 ,  B01J39/02 ,  B01J39/14 ,  C01B33/42

Abstract: A chemically modified mica composite formed by heating a trioctahedral mica in an aqueous solution of sodium chloride having a concentration of at least 1 mole/liter at a temperature greater than 180 degrees Centigrade for at least 20 hours, thereby replacing exchangeable ions in the mica with sodium. Formation is accomplished at temperatures and pressures which are easily accessed by industrial equipment. The reagent employed is inexpensive and non-hazardous, and generates a precipitate which is readily separated from the modified mica.

Abstract translation: 一种经化学改性的云母复合材料，其通过在浓度至少为1摩尔/升的氯化钠水溶液中，在大于180摄氏度的温度下加热三八面体云母至少20小时而形成，从而用云母中的可交换离子代替云母中的可交换离子， 钠。 形成是在工业设备容易获得的温度和压力下完成的。 所使用的试剂是廉价且无危险的，并且产生容易与改性云母分离的沉淀物。

公开(公告)号：US5015448A

公开(公告)日：1991-05-14

申请号：US262836

申请日：1988-10-26

Applicant: Klaus-Dieter Vorlop ,  Michael Sell

Inventor： Klaus-Dieter Vorlop ,  Michael Sell

IPC: B01J13/14 ,  B01D20060101 ,  B01D15/00 ,  B01J20060101 ,  B01J13/02 ,  B01J20/08 ,  B01J20/10 ,  B01J20/12 ,  B01J20/16 ,  B01J20/26 ,  B01J20/30 ,  B01J39/08 ,  B01J45/00 ,  C02F20060101 ,  C02F1/42 ,  C02F1/58 ,  C22B3/00

CPC classification number: B01J45/00 ,  C22B3/42 ,  Y02P10/234

Abstract: The invention relates to particulate material for separation of metal cations from aqueous solutions. These particles contain complexing agents dispersed in a continuous aqueous phase which is embedded in or is a constituent of a hydrophilic gel and/or is encapsulated by a water-insoluble, ion-permeable shell.

Abstract translation: 本发明涉及用于从水溶液中分离金属阳离子的颗粒材料。 这些颗粒包含分散在连续水相中的络合剂，其嵌入或作为亲水性凝胶的组分和/或被不溶于水的离子可渗透的壳包封。

公开(公告)号：US4609484A

公开(公告)日：1986-09-02

申请号：US635407

申请日：1984-07-30

Applicant: Giulio Alberti ,  Francesco Bartoli ,  Umberto Costantino ,  Francesco Di Gregorio

Inventor： Giulio Alberti ,  Francesco Bartoli ,  Umberto Costantino ,  Francesco Di Gregorio

IPC: B01J39/10 ,  B01J39/08 ,  B01J39/12 ,  C01B25/16 ,  C01B25/37 ,  C01G28/02 ,  C09K3/00

CPC classification number: B01J39/085 ,  B01J39/12 ,  C01B25/16 ,  C01G28/02 ,  C01P2002/20 ,  C01P2002/72 ,  C01P2002/78

Abstract: Mixed phosphorous or arsenic salts of tetravalent metals are provided having the general formula M(HAO.sub.4).sub.2-x (HAO.sub.3).sub.x.nH.sub.2 O, where M is Zr, Ti or Hf, A is phosphorus or arsenic, x is between 0.05 and 1.95, and n is 0 to 6. The salts are highly stable and have wide potential application in the fields of ion exchange, catalysis, intercalation of molecules, solid electrolytes, and chromatography. The salts are prepared by reacting a halide, oxyhalide, nitrate, sulphate, phosphate or oxide of the tetravalent metal, preferably in an aqueous medium, with at least two oxygenated acids of phosphorus and/or arsenic.

Abstract translation: 提供具有通式M（HAO4）2-x（HAO3）x.nH2O，其中M为Zr，Ti或Hf，A为磷或砷的x为0.05至1.95的四价金属的混合的磷或砷盐， 并且n为0至6.该盐是高度稳定的，并且在离子交换，催化，分子插入，固体电解质和色谱领域具有广泛的应用。 所述盐通过使四价金属的卤化物，卤氧化物，硝酸盐，硫酸盐，磷酸盐或氧化物优选在水性介质中与磷和/或砷的至少两种氧化酸反应来制备。

公开(公告)号：US4480060A

公开(公告)日：1984-10-30

申请号：US461572

申请日：1983-01-27

Applicant: Syed N. Hoda ,  Anthony R. Olszewski

Inventor： Syed N. Hoda ,  Anthony R. Olszewski

IPC: C08K3/00 ,  B01J39/08 ,  B01J47/00 ,  C04B14/20 ,  C04B26/10 ,  C08G59/00 ,  C08J5/22 ,  C08K7/00 ,  C08L63/00 ,  C08K3/34

CPC classification number: C04B14/206 ,  B01J39/085 ,  B01J47/007 ,  C08J5/22

Abstract: A composite material is disclosed which is composed essentially of an ion-exchanged, synthetic, crystalline mica and an organic resin, the mica constituting at least about 50% by weight of the composite, and the mechanical properties of the composite being superior to those of the mica pressed alone.

Abstract translation: 公开了一种复合材料，其主要由离子交换的，合成的结晶云母和有机树脂组成，云母构成复合材料的至少约50重量％，并且复合材料的机械性能优于 云母单独挤压。

公开(公告)号：US4381349A

公开(公告)日：1983-04-26

申请号：US95691

申请日：1979-11-19

Applicant: John M. Lee ,  William C. Bauman

Inventor： John M. Lee ,  William C. Bauman

IPC: B01J39/08 ,  B01J41/04 ,  B01J41/08 ,  B01J41/10 ,  C01D15/00 ,  C01F7/34 ,  B01J41/00 ,  B01J41/12

CPC classification number: B01J41/10 ,  B01J41/046 ,  B01J41/08 ,  C01D15/00 ,  C01F7/34 ,  C22B3/42 ,  C01P2002/72 ,  Y02P10/234

Abstract: Formation of hydrous alumina in the reticules of a weak-base anion exchange resin, wherein AlCl.sub.3 has been precipitated as hydrous alumina by reaction with ammonia, is improved by employing a subsequent treatment with HCl or with NH.sub.4 Cl and HCl to convert the exchange resin to the chloride form, thereby increasing the reticular volume of the resin, thus permitting subsequent precipitation of additional hydrous alumina therein.

Abstract translation: 弱碱阴离子交换树脂的网状物中的含水氧化铝的形成，其中AlCl 3通过与氨反应而作为含水氧化铝沉淀，通过采用随后的HCl或用NH 4 Cl和HCl处理将交换树脂转化为 氯化物形式，从而增加树脂的网状体积，从而允许其中附加的含水氧化铝沉淀。

公开(公告)号：US4380590A

公开(公告)日：1983-04-19

申请号：US943889

申请日：1978-09-19

Applicant: Berni P. Chong

Inventor： Berni P. Chong

IPC: C08F8/00 ,  B01J39/04 ,  B01J39/08 ,  B01J41/08 ,  B01J41/14 ,  B01J43/00 ,  B01J47/00 ,  C02F1/42 ,  C08F2/20 ,  C13B20/14 ,  C08F6/22 ,  C08F8/36

CPC classification number: B01J47/007 ,  B01J39/085 ,  B01J41/085 ,  Y10S977/773 ,  Y10S977/775 ,  Y10S977/788 ,  Y10S977/896

Abstract: Emulsion copolymer particles with diameters smaller than 1.5 micrometers and functionalized with cation exchange functional groups are prepared and suspended as emulsions in liquid media to form liquid cation exchange materials.

Abstract translation: 制备直径小于1.5微米并用阳离子交换官能团官能化的乳液共聚物颗粒，并将其作为乳液悬浮在液体介质中以形成液体阳离子交换材料。

公开(公告)号：US10092898B2

公开(公告)日：2018-10-09

申请号：US15675922

申请日：2017-08-14

Applicant: Ecolab USA Inc.

Inventor： Terrence P. Everson ,  Li Wen ,  Lylien Tan ,  Peter Voss ,  Mark Toetschinger

IPC: A47L15/42 ,  B01J39/05 ,  B01J39/07 ,  B01J39/08 ,  B01J39/20 ,  B01J49/06 ,  B01J49/53 ,  B01J49/75 ,  C02F1/42 ,  D06F39/00

Abstract: Methods and systems for an integrated acid regeneration of ion exchange resins are disclosed for use in cleaning applications. Acid resins designed for use in a variety of cleaning application using a treated, softened, acidic water source are disclosed. Various methods of using the softened acidic water generated by acid regenerate-able ion exchange resins within a cleaning application, e.g. ware wash machine, are disclosed to beneficially reduce spotting, filming and scale buildup on treated surfaces, reduce and/or eliminate the need for polymers, threshold reagents and/or rinse aids, and using protons generated in the acidic water effluent for triggering events useful in various cleaning applications.

公开(公告)号：US10052625B2

公开(公告)日：2018-08-21

申请号：US15257456

申请日：2016-09-06

Applicant: Ecolab USA Inc.

Inventor： Terrence P. Everson ,  Li Wen ,  Lylien Tan ,  Peter Voss ,  Mark Toetschinger

IPC: B01J49/75 ,  B01J39/20 ,  C02F1/42 ,  A47L15/42 ,  D06F39/00 ,  B01J39/05 ,  B01J39/07 ,  B01J47/15 ,  B01J49/06 ,  B01J49/53 ,  B01J39/08 ,  A47L15/24

CPC classification number: B01J49/53 ,  A47L15/241 ,  A47L15/4217 ,  A47L15/4229 ,  B01J39/05 ,  B01J39/07 ,  B01J39/08 ,  B01J39/19 ,  B01J39/20 ,  B01J47/15 ,  B01J49/06 ,  B01J49/75 ,  B08B3/04 ,  B08B3/14 ,  C02F1/42 ,  C02F2001/425 ,  C02F2209/00 ,  C02F2209/005 ,  C02F2209/06 ,  C02F2303/16 ,  D06F39/007

Abstract: Methods and systems for acid regeneration of ion exchange resins are disclosed. Acid resins designed for use in a variety of cleaning application using a water source use a treated, softened, acidic water source according to the invention. Various methods of using the softened acidic water generated by acid regenerate-able ion exchange resins are disclosed to beneficially reduce spotting, filming and scale buildup on treated surfaces, reduce and/or eliminate the need for polymers, threshold reagents and/or rinse aids, and using protons generated in the acidic water effluent for triggering events useful in various cleaning applications.

公开(公告)号：US09126195B2

公开(公告)日：2015-09-08

申请号：US13660185

申请日：2012-10-25

Applicant: Rohm and Haas Company

Inventor： Shintaro Tsuzuki

IPC: B01J39/08 ,  B01J39/16 ,  B01J47/00 ,  B01J47/04 ,  C02F1/42

CPC classification number: B01J39/08 ,  B01J39/16 ,  B01J47/016 ,  B01J47/04 ,  C02F1/42 ,  C02F2001/425 ,  C02F2001/427

Abstract: The present invention provides cationic exchange resin that maintains a high exchange speed of polyvalent ions in addition to monovalent ions without agglomeration occurring in spite of surface coating even when mixed bed ion-exchange resin is used.

Abstract translation: 本发明提供即使在使用混合床离子交换树脂的情况下，尽管表面涂层，除了一价离子之外，还保持了多价离子的高交换速度，而没有发生凝聚。

公开(公告)号：US20080287670A1

公开(公告)日：2008-11-20

申请号：US11804538

申请日：2007-05-18

Applicant: Gregory Scott ,  Avelino Sanchez ,  Krishnamohanrao S. Kallury

Inventor： Gregory Scott ,  Avelino Sanchez ,  Krishnamohanrao S. Kallury

IPC: C07H21/04 ,  B01J39/08 ,  C07H21/02

CPC classification number: C07H21/02 ,  B01D15/12 ,  B01D15/325 ,  C07H21/04

Abstract: Chromatographic loading solutions for use in the purification of trityl-on oligonucleotides. The solutions comprise an antichaotropic ion, a chaotropic ion, an alkaline salt, and a polar protic solvent, all at particular concentrations. The solution is useful in purifying oligodeoxyribonucleotides and oligoribonucleotides having either ACE or TBDMS protective caps. Also, methods and systems for purifying trityl-on oligonucleotides comprising the chromatographic loading solution, a reversed-phase sorbent, and the oligonucleotides to be purified.

Abstract translation: 用于纯化三苯甲基寡核苷酸的色谱加载溶液。 该溶液包括反向离子，离液序列离子，碱性盐和极性质子溶剂，全部以特定的浓度。 该溶液可用于纯化具有ACE或TBDMS保护帽的寡脱氧核糖核苷酸和寡核糖核苷酸。 另外，用于纯化三苯甲基寡核苷酸的方法和系统包括色谱加载溶液，反相吸附剂和待纯化的寡核苷酸。