IRON SALT CATALYST REGENERATION
    33.
    发明公开

    公开(公告)号:US20240150266A1

    公开(公告)日:2024-05-09

    申请号:US18507882

    申请日:2023-11-13

    申请人: Randolph Belter

    发明人: Randolph Belter

    IPC分类号: C07C17/02 B01J31/16 B01J37/04

    摘要: Chemical processes are disclosed that react iron tetracarbonyl dichloride with an alkyl phosphate producing carbon monoxide and a compound represented by the formula FeCl2—(O═P(OR)3)n where n is an integer. Simultaneously or subsequently an alkene with carbon tetrachloride may be reacted in the presence of the compound represented by the formula FeCl2—(O═P(OR)3)n where n is an integer to produce a chlorinated hydrocarbon.

    Polydentate organic ligand, preparation method and application thereof, metallo-supramolecular polymer and preparation method thereof

    公开(公告)号:US11969719B2

    公开(公告)日:2024-04-30

    申请号:US18086530

    申请日:2022-12-21

    申请人: Jilin University

    IPC分类号: B01J31/18 B01J37/04 C08G83/00

    摘要: A polydentate organic ligand, a preparation method and an application method thereof, a metallo-supramolecular polymer and a preparation method thereof are provided. A structure of triphenylamine is combined with a structure of phenanthroline to serve as the polydentate organic ligand, which takes advantages of a large-volume distortion structure and excellent electroactivity of the triphenylamine. The polydentate organic ligands have good solubility, which provides lower-cost and diversified methods for preparing the metallo-supramolecular polymers. Meanwhile, the phenanthroline has a rigid structure and a conjugated large π bond in its molecule, which facilitates chelating coordination with metal ions to form a stable compound. Therefore, the polydentate organic ligand enables the metallo-supramolecular polymer to have good transferability, stable electroactivity, and high conversion speed, i.e., fast response speed, excellent electrochromic cycling stability and long service lifetime.