Cobalt complexes and process for producing the same
    42.
    发明授权
    Cobalt complexes and process for producing the same 失效
    钴复合物及其制造方法

    公开(公告)号:US3567751A

    公开(公告)日:1971-03-02

    申请号:US3567751D

    申请日:1968-02-16

    Applicant: SNAM PROGETTI

    CPC classification number: C07F15/065

    Abstract: A PROCESS FOR PRODUCING AN ORGANOMETALLIC TETRADENTATE COMPLEX OF COBALT BY REACTING AN ORGANOMETALLIC TETRADENTATE COMPLEX OF COBALT OF THE FORMULA:

    -X1-CO(-R)(-X2(-))(-X3(-))-X4-

    WHEREIN X1, X2, X3 AND X4, WHICH FORM THE TETRADENTATE COMPLEX, MAY BE THE SAME OR DIFFERENT AND EACH REPRESENTS A NITROGEN, OXYGEN, SULPHUR OR PHOSPHORUS ATOM; AND R IS AN ALKYL, ARYL, ALKARYL OR CYCLOALKYL RADICAL WITH CARBON MONOXIDE OR NITROGEN MONOXIDE AND WITH A MOBILE HYDROGEN COMPOUND REPRESENTED BY THE FORMULA R''H, SAID R'' BEING AN OXYALKYL, OXYARYL, OXYCYCLOALKYL AMINO, HYDROXY OR MERCAPTAN RADICAL, IN THE PRESENCE OF VISIBLE OR ULTRAVIOLET RADIATION DISCLOSED. THE RESULTING PRODUCTS ARE ALSO DISCLOSED AND CLAIMED. THEY FIND PARTICULAR UTILITY AS CATALYSTS IN VARIOUS ORGANIC REACTIONS SUCH AS OXIDATIONS, OXO-REACTIONS AND NITROSATIONS.

    Process for the recovery of isoprene from mixtures containing the same
    50.
    发明授权
    Process for the recovery of isoprene from mixtures containing the same 失效
    从含有它的混合物中回收异丙苯的方法

    公开(公告)号:US3860496A

    公开(公告)日:1975-01-14

    申请号:US21354471

    申请日:1971-12-29

    Applicant: SNAM PROGETTI

    CPC classification number: C07C7/08 C07C11/18

    Abstract: A multi-stage method is disclosed whereby isoprene of high purity is recovered from mixtures of C5 hydrocarbons containing it, wherein the mixture is subjected to a first extractive distillation stage in the presence of a solvent, such as morpholine and N-formyl-morpholine, containing water and in which olefinic and saturated hydrocarbons are withdrawn as a top product; a second extractive distillation stage effects the withdrawal of the major part of the cyclopentadiene and acetylene compounds present in the bottom product of the first stage as a sidestream and said solvent constitutes a bottom product for recycling to said first and second stage; in a third extractive distillation stage the top product of the second stage is treated with solvent containing water, fed to the third stage from a stripper and then recycled as bottom product to said stripper; and, in a rectification stage, isoprene of desired purity is recovered from the overhead product of the third extractive distillation stage.

    Abstract translation: 公开了一种多级方法,其中从含有它的C5烃的混合物中回收高纯度的异戊二烯,其中混合物在溶剂例如吗啉和N-甲酰基吗啉存在下进行第一萃取蒸馏阶段, 含有水,其中烯属和饱和烃作为顶级产品被取出; 第二萃取蒸馏阶段使作为侧流的第一阶段的底部产物中存在的环戊二烯和乙炔化合物的主要部分退出,并且所述溶剂构成用于再循环到所述第一和第二阶段的底部产物; 在第三萃取蒸馏阶段中,第二阶段的顶部产物用含溶剂的水处理,从汽提塔进料至第三阶段,然后作为底部产物再循环至所述汽提塔; 并且在精馏阶段,从第三萃取蒸馏阶段的塔顶产物中回收所需纯度的异戊二烯。

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